ACT Science : Chemistry

Study concepts, example questions & explanations for ACT Science

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Example Questions

Example Question #171 : Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

Given that all of the following are true, which of the following, if found, provides the strongest evidence against Scientist 2's hypothesis?

Possible Answers:

When a rusted piece of iron is immersed in lemon juice (citric acid), it becomes shiny again.

When immersed in a solution of water and acid, a galvanized piece of iron does not rust.

When an iron nail is immersed in water in an open container, rust forms on the nail even in the absence of added acid.

When oxygen is prevented from dissolving into a solution which contains a piece of iron, the iron does not rust.

When two iron nails are immersed in identical solutions of acid and water, they rust at different rates.

Correct answer:

When a rusted piece of iron is immersed in lemon juice (citric acid), it becomes shiny again.

Explanation:

Scientist 2 states that acid is required for rust to form. Because acid releases H+ ions—which, according to Scientist 2, are involved in the production of rust—we should expect that adding more acid to a solution will speed up the formation of rust. If, however, adding citric acid actually reverses rusting or removes rust (causing a piece of iron to become shiny again), this would suggest that Scientist 2's explanation is wrong.

Scientist 2 also states that acid may be formed in a solution because of atmospheric carbon dioxide dissolving in the water or because of impurities in a piece of iron. So, rust may form even when no acid is directly added to water. It is also possible that different amounts of impurities in different pieces of iron cause them to rust at different rates. This is why some of the other answers are not correct.

Example Question #11 : How To Find Conflicting Viewpoints In Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

Lye (sodium hydroxide) is a base that neutralizes acids. Suppose that lye is added to water in which an iron pipe has been immersed. According to Scientist 2, the pipe's rate of rusting will most likely __________.

Possible Answers:

decrease, because the solution will become less acidic

increase, because more Fe2+ ions will be produced

increase, because rust requires hydroxide ions to form

increase, because the concentration of H+ ions in the solution will increase

decrease, because the solution will become more acidic

Correct answer:

decrease, because the solution will become less acidic

Explanation:

According to Scientist 2, acid is needed for rust to form. However, the question tells us that lye neutralizes acids. So, if lye is added to the solution, the solution will become less acidic, and rust will not form, or form at a slower rate.

Example Question #173 : Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

An iron nail is placed in an unsealed test tube filled with water. No other substances are added to the water. When the nail is removed after an extended period of time, it is covered by rust. According the Scientist 2, the nail most likely rusted because __________.

Possible Answers:

the iron nail contained impurities, which reacted with water to form iron oxide

the iron nail contained impurities, with reacted with water to form OH- ions

carbon dioxide from the air dissolved in the water and reacted to form carbonic acid

the iron nail contained impurities, which reacted with water to form carbonic acid

oxygen from the air dissolved in the water and reacted to form OH- ions

Correct answer:

carbon dioxide from the air dissolved in the water and reacted to form carbonic acid

Explanation:

According to Scientist 2, acid is needed for rust to form. However, Scientist 2 also tells us that acid may form spontaneously when carbon dioxide from the air dissolves in water and reacts to form carbonic acid. In this experiment, because it was observed that the iron nail did rust, some acid must have been in the water. This acid might have been carbonic acid produced from carbon dioxide, or other acids produced from impurities contained in the iron nail. Out of these two options, the only one listed as a possible answer choice is the situation involving carbon dioxide and carbonic acid.

Example Question #171 : Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

Sodium hydroxide (NaOH) is a compound which dissociates into Na+ and OH- ions in solution. Suppose that sodium hydroxide is added to water in which a piece of iron has been immersed. It is then observed that the rate at which rust forms on the iron increases. Scientist 1 would most likely explain this result by saying that __________.

Possible Answers:

sodium hydroxide neutralized the acid in the water, slowing the formation of iron hydroxide

sodium hydroxide increased the concentration of oxygen in the water, facilitating the formation of iron hydroxide

sodium hydroxide increased the concentration of hydroxide ions in the water, slowing the formation of iron hydroxide

sodium hydroxide neutralized the acid in the water, facilitating the formation of iron hydroxide

sodium hydroxide increased the concentration of hydroxide irons in the water, facilitating the formation of iron hydroxide

Correct answer:

sodium hydroxide increased the concentration of hydroxide irons in the water, facilitating the formation of iron hydroxide

Explanation:

According to Scientist 1, hydroxide (OH-) ions are one of the precursors involved in the formation of rust. Since sodium hydroxide dissociates into Na+ and OH- ions, adding sodium hydroxide to a solution would increase the concentration of OH- ions. If Scientist 1 is right, this should also speed up or facilitate the formation of iron hydroxide, which should then turn into rust.

Example Question #175 : Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

According to Scientist 1, which of the following conditions will result in the least rapid formation of rust?

Possible Answers:

Placing powdered iron in water at 30°C and adding table salt

Placing a strip of iron in water at 5°C

Placing powdered iron in water at 5°C

Placing a strip of iron in water at 30°C

Placing powdered iron in water at 30°C

Correct answer:

Placing a strip of iron in water at 5°C

Explanation:

Scientist 1 states that increasing the surface area of iron and increasing the ambient temperature both speed up the formation of rust. Additionally, she says that salt acts as a catalyst for rust formation, meaning that adding salt to a solution also speeds up the formation of rust. Because this question asks us for the situation under which rust will form least rapidly, the correct answer is the one in which iron has a smaller surface area (the iron strip) and is placed in cooler (5°C)water.

Example Question #176 : Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

Given that the explanation of Scientist 2 is correct, which of the following conditions, if any, will result in the formation of rust?

Possible Answers:

An iron pot is placed in a sealed chamber containing oxygen gas.

An iron pot is immersed in water in an unsealed container.

Rust will not form in any of the situations listed.

An iron pot is coated with zinc, then immersed in water in an unsealed container.

An iron pot is placed in a sealed chamber containing carbon dioxide gas.

Correct answer:

An iron pot is immersed in water in an unsealed container.

Explanation:

According to Scientist 2, water must contain oxygen and acid in order for rust to form. However, Scientist 2 says that even when no acid is directly added to water, carbon dioxide from the air can react with water to form carbonic acid. Oxygen can also dissolve from the air into the water. So, if an iron pot is placed in an unsealed container of water, both oxygen and carbon dioxide from the atmosphere can enter the water. This creates conditions under which rust can form.

Example Question #851 : Act Science

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

Bromothymol blue is a pH indicator that is yellow in acidic solutions and blue in basic solutions. When bromothymol blue is added to a solution, it remains blue. A piece of iron is then immersed in this solution. Given that the explanation of Scientist 2 is correct, which of the following is most likely to occur?

Possible Answers:

Iron oxide will be produced because the solution is acidic.

Iron oxide will be produced because the solution is basic.

Iron oxide will not be produced because the solution is basic.

Iron oxide will not be produced because the solution is acidic.

Correct answer:

Iron oxide will not be produced because the solution is basic.

Explanation:

Scientist 2 states that rusting is caused by attack by an acid. If he is right, rust can form in acidic solutions, but will not form in basic solutions. This question tells us that the blue color of bromothymol blue shows that a solution is basic. Since the bromothymol blue keeps its blue color, we know that the solution in the question is basic. So, rust will most likely not be formed.

Example Question #178 : Chemistry

In its refined form, iron is a shiny, silver-gray metal; however, when refined iron is exposed to atmospheric conditions for an extended period of time, its surface becomes flaky, pitted, and red- or orange-colored. This process is known as "rusting," and the new flaky, orange or red substance is called "rust."

Below, two scientists discuss how rust forms and the composition of rust.

 

Scientist 1:

Both water and oxygen are needed for rust to form. Water is an electrolyte, meaning that it allows ions to move within it. When iron comes into contact with water, some iron naturally dissociates into iron ions (Fe2+) and free electrons. Additionally, when atmospheric oxygen (O2) dissolves in water, some oxygen reacts with water to form hydroxide ions (OH-). Because water allows ions to move freely, iron ions and hydroxide ions combine to form a new compound: iron hydroxide. However, iron hydroxide is not a stable compound. Over time, as water evaporates, it changes into a hydrated form of iron oxide. This is rust.

Salts can act as catalysts for rust formation, meaning that they speed up the rate at which rust forms. However, rust can form in pure water, in the absence of added salts.

Increasing the ambient temperature increases the rate of rust formation. Additionally, increasing the amount of iron's surface area that is exposed to water also increases the rate at which rust forms. However, because a layer of rust is porous to water and oxygen, water and oxygen will continue to cause the interior of a piece of iron to rust even after the iron's surface has been rusted.

 

Scientist 2:

Attack by acids causes rust to form. In water, acids ionize to create positively-charged hydronium (H+) ions and negatively-charged anions. Hydronium ions are electron-deficient; because of this, they attract electrons from iron. This creates iron ions (Fe2+), which are soluble in water. Once dissolved in water, iron ions react with dissolved atmospheric oxygen (O2) to create iron oxide, or rust.

Acids can come from a variety of sources. For example, when carbon dioxide in the atmosphere dissolves in water, carbonic acid (H2CO3) is created. Carbonic acid is the most common cause of rusting. However, other environmental sources of acids exist. Rainwater is normally slightly acidic because it has come into contact with molecules in the atmosphere, like sulfur dioxide and nitrogen oxides. These molecules also dissolve in water to form acids. Additionally, iron itself may contain impurities such as phosphorous and sulfur, which react with water to produce acids. Both acidic environments and impurities within iron itself create the conditions under which iron rusts.

Rusting can be prevented by painting the surface of iron, thus preventing it from coming into contact with water, oxygen, and acids. Iron can also be protected in a process called "galvanizing," which involves coating iron in a thin layer of zinc. Because zinc is more reactive than iron, it is corroded while the iron is protected.

In an experiment, oxygen is removed from water by boiling the water. This water is then poured into a flask, and a piece of iron is immersed in the water. Excess air is pumped out from the flask and replaced with helium (He). Then the flask is sealed. After an extended period of time, a reddish-orange substance is observed on the surface of the iron.

Given that Scientist 2 is correct, which of the following most likely describes the identity of the reddish-orange substance?

Possible Answers:

The substance is not rust, because rust requires carbonic acid to form.

The substance is not rust, because rust requires oxygen to form.

The substance is rust, because rust forms in the presence of oxygen.

The substance is rust, because rust forms in the presence of carbonic acid.

Correct answer:

The substance is not rust, because rust requires oxygen to form.

Explanation:

The explanation of Scientist 2 requires that oxygen be dissolved in water in order for rust to form. According to Scientist 2, free iron (Fe2+) ions react with dissolved atmospheric oxygen to form iron oxide. However, in this question, dissolved oxygen is removed from the water by boiling, and no additional oxygen is allowed to diffuse into the water, because the air is replaced with helium. Because no oxygen can get into the water, it would be impossible for rust to form. So, the reddish-orange substance must be another compound instead of rust.

Example Question #179 : Chemistry

In studying the effects of adding heat to different substances on each substance's temperature, a researcher conducted the following experiment. The researcher added 1,000 Joules of energy by a controlled heat lamp to four different substances. The temperature change in each substance that was caused by the heat was then measured and recorded. The results of this experiment are shown below.

Table3

The researcher is aware of a concept called specific heat and knows that lead has a lower specific heat than wood, which has a lower specific heat than cardboard, which has a lower specific heat than styrofoam. Therefore, the researcher has ordered the objects in the table from lowest specific heat (lead) to highest (styrofoam).

According to the data in the table, what is the apparent relationship between specific heat and the amount that an object's temperature changes when a given amount of heat is added?

Possible Answers:

There is no apparent relationship.

A positive correlation.

The data for different amounts of heat added is needed to discern a relationship.

The data for specific heat is needed to discern a relationship.

A negative correlation

Correct answer:

A negative correlation

Explanation:

Since the objects are ordered from lowest specific heat to highest and we see that the degree to which an object's temperature changes decreases as we go down the chart, we see a clear negative correlation. No more information is needed to discern this.

Example Question #171 : Chemistry

When describing their behavior, gases are typically treated as "ideal gases" in what is known as the ideal gas law. Two science students describe the ideal gas law in their own terms:

Student 1: The ideal gas law is based on the assumptions that a gas consists of a large number of molecules and that gas molecules take up negligible space in a gas due to their minuscule size in comparison to the space between each gas molecule. Also important is the assumption that all of the forces acting on gas molecules are from collisions with other gas molecules or a container and not from anything else. According to the ideal gas law, all gases behave the same so long as those assumptions hold true. Therefore, if you measure the volume of helium gas at a certain temperature and pressure, an equivalent amount of radon gas (a much heavier gas) at the same conditions will have the same volume.

Student 2: The ideal gas law's primary assumption is that a gas consists of a very large number of particles. For example, even within a single bacteria there can be billions of gas molecules despite the bacteria's very small size. Therefore, in a room full of gas, there are so many particles that their random behavior is, on average, uniform. There are exceptions to the ideal gas law and those are gases with very high inter-molecular forces of attraction (IMFAs). A gas with high IMFA will behave very differently than a gas with a low IMFA. As one could imagine, because a gas with a high IMFA will have molecules that tend to attract each other, that gas will display a lower volume than that which would be predicted by the ideal gas law.

Based on the passage, which of the following statements best describes where Student 1 and Student 2 disagree?

Possible Answers:

Student 2 would not consider molecule size to be important in the ideal gas law.

Student 1 would not consider molecule size to be important in the ideal gas law.

Student 1 would not consider IMFAs to be important in the ideal gas law.

The students do not disagree. 

Student 2 would not consider IMFAs to be important in the ideal gas law.

Correct answer:

Student 2 would not consider molecule size to be important in the ideal gas law.

Explanation:

This is a very tricky question because it is very tempting to answer that Student 1 did not recognize the possible influence of IMFAs on gas behavior since Student 1 did not mention IMFAs directly. This is why it is so important to read a passage very carefully. Although Student 1 does not specifically mention IMFAs, one can conclude from the passage that an IMFA is a force that acts on gas molecules that Student 1 points out would violate an important assumption of the ideal gas law. Therefore, student 1, while not using the term "IMFA," would likely agree that IMFAs would have an effect on ideal gas behavior. Instead, the answer is that Student 2 would not consider molecule size to be important. This we can assume because Student 2 did not mention molecule size whatsoever.

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