A student performed the following procedures to study various photosynthetic pigments (light-absorbing chemicals) in tree leaves and the wavelengths of light they absorb.

Experiment 1:

The student obtained samples of leaves from oaks, maples, ashes, sycamores, and poplars. Each leaf sample was ground separately with a mortar and pestle to release the pigments, and then each sample was suspended in water to make a colored solution of the pigment. The student then measured the absorption spectrum (a graph of how much light is absorbed by a pigment at varying wavelengths of light) of each solution in a device called a spectrophotometer. The setup of a spectrophotometer is shown below in Diagram 1.

The light source emits white light, which is split into its various wavelengths by the prism. Next, a slit, which can be moved up or down to select a particular wavelength, is used to transmit just a single wavelength to the sample. The sample absorbs a fraction of this light that is characteristic to the pigment in the sample, and the rest is transmitted to the detector for a readout. Using the spectrophotometer, the student found the λ_max (the wavelength of light in nanometers (nm) that the pigment absorbs most intensely, for each sample) and recorded the results in Table 1. Table 1 also shows the transmittance and absorbance values at λ_max. Transmittance, T, is defined as the fraction of light, expressed as a decimal, which passes through the sample. Absorbance, A, is given by:

                                    A = –log(T)   or  10^–A = T

Experiment 2:

A student is given a leaf from an unknown source. She crushes and extracts the pigment according to the procedure in Experiment 1. Measuring the absorbance spectrum in the spectrophotometer produces the following readout, shown in Diagram 2.

                                                     Diagram 2

A standardized sample of a pigment often found in plant leaves, called Chlorophyll A, was placed into the spectrophotometer and found to have a λ_maxof 425 nm. The leaves of which tree most likely have a high concentration of Chlorophyll A?

A student wanted to study the kinetics, or rates of a chemical reaction based on the concentrations of its reactants and products, of the reaction shown below.

This reaction is easy to monitor using a spectrophotometer, which measures how much light of a particular wavelength is absorbed by a solution. The deep purple potassium permanganate, or , absorbs light of a 550 nm wavelength in proportion to its concentration in the reaction solution. Manganese sulfate, or , is pale pink and absorbs light of a 500 nm wavelength in proportion to its concentration in the reaction solution. All other reactants and products are colorless and do not absorb visible light and thus cannot be monitored using the spectrophotometer.

Experiment 1:

The student constructed a standard curve, or a graph of the absorbance of solutions of varying concentrations of potassium permanganate, to quantify the relationship between concentration and absorbance. To prepare five sample of increasing concentration, he labeled five test tubes A, B, C, D, and E, weighed out 0.1, 0.2, 0.3, 0.4, and 0.5 grams of potassium permanganate into each, respectively, and added 1 milliliter (mL) of water to each test tube to dissolve. Then, he used the spectrophotometer to determine the absorbance at 550 nm of each sample. The data is graphed in Figure 1 below.

                                                        Figure 1

Experiment 2: 

The student then studied potassium permanganate in the presence of oxalic acid, , to observe the reaction. Monitoring both the absorbances of potassium permanganate and manganese sulfate, he was able to determine the reaction rate using a special setting on the spectrophotometer. The reaction rate at various concentrations of reactants is shown below in Table 1.

The rate constant, , for a chemical reaction involving two reactants is given by the following equation: 

What is the rate constant for the reaction studied in Experiment 2?

A student wanted to study the kinetics, or rates of a chemical reaction based on the concentrations of its reactants and products, of the reaction shown below.

This reaction is easy to monitor using a spectrophotometer, which measures how much light of a particular wavelength is absorbed by a solution. The deep purple potassium permanganate, or , absorbs light of a 550 nm wavelength in proportion to its concentration in the reaction solution. Manganese sulfate, or , is pale pink and absorbs light of a 500 nm wavelength in proportion to its concentration in the reaction solution. All other reactants and products are colorless and do not absorb visible light and thus cannot be monitored using the spectrophotometer.

Experiment 1:

The student constructed a standard curve, or a graph of the absorbance of solutions of varying concentrations of potassium permanganate, to quantify the relationship between concentration and absorbance. To prepare five sample of increasing concentration, he labeled five test tubes A, B, C, D, and E, weighed out 0.1, 0.2, 0.3, 0.4, and 0.5 grams of potassium permanganate into each, respectively, and added 1 milliliter (mL) of water to each test tube to dissolve. Then, he used the spectrophotometer to determine the absorbance at 550 nm of each sample. The data is graphed in Figure 1 below.

                                                        Figure 1

Experiment 2: 

The student then studied potassium permanganate in the presence of oxalic acid, , to observe the reaction. Monitoring both the absorbances of potassium permanganate and manganese sulfate, he was able to determine the reaction rate using a special setting on the spectrophotometer. The reaction rate at various concentrations of reactants is shown below in Table 1.

Reaction rate is given by the following equation:

Imagine that  for this particular reaction. If a student uses concentrations of 2.0 grams/mL for both of the reactants, what should he expect the rate to be?

The Ideal Gas Law is as follows:

 is pressure as measured in Pascals,  is volume as measured in cubic meters,  is the number of moles of the gas,  is the gas constant known as 8.314 Joules per mole times Kelvin, and  is the temperature measured in Kelvin.

A class of students began studying the Ideal Gas Law and how the Pressure and the Volume relate to one another.  They took 20 moles of a sample gas and kept the room at a temperature of 300 Kelvin.  They then used different sized containers of the gas to limit and expand the volume.  At each different volume, they measure the pressure of the gas on its container.  The table they made from their results is seen in table 1.

TABLE 1 

And they graph their findings in Figure 1.

FIGURE 1

If the Kelvin temperature were to rise, what would happen to the pressure?

The Ideal Gas Law is as follows:

 is pressure as measured in Pascals,  is volume as measured in cubic meters,  is the number of moles of the gas,  is the gas constant known as 8.314 Joules per mole times Kelvin, and  is the temperature measured in Kelvin.

A class of students began studying the Ideal Gas Law and how the Pressure and the Volume relate to one another. They took 20 moles of a sample gas and kept the room at a temperature of 300 Kelvin. They then used different sized containers of the gas to limit and expand the volume. At each different volume, they measure the pressure of the gas on its container. The table they made from their results is seen in table 1.

TABLE 1 

And they graph their findings in Figure 1.

FIGURE 1

Would Figure 1 be the same for 1 mole of hydrogen gas as it would be for 1 mole of oxygen gas?

The Ideal Gas Law is as follows:

 is pressure as measured in Pascals,  is volume as measured in cubic meters,  is the number of moles of the gas,  is the gas constant known as 8.314 Joules per mole times Kelvin, and  is the temperature measured in Kelvin.

A class of students began studying the Ideal Gas Law and how the Pressure and the Volume relate to one another. They took 20 moles of a sample gas and kept the room at a temperature of 300 Kelvin. They then used different sized containers of the gas to limit and expand the volume. At each different volume, they measure the pressure of the gas on its container. The table they made from their results is seen in table 1.

TABLE 1 

And they graph their findings in Figure 1.

FIGURE 1

What would the pressure be if the volume was 100 cubic meters?

The Ideal Gas Law is as follows:

 is pressure as measured in Pascals,  is volume as measured in cubic meters,  is the number of moles of the gas,  is the gas constant known as 8.314 Joules per mole times Kelvin, and  is the temperature measured in Kelvin.

A class of students began studying the Ideal Gas Law and how the Pressure and the Volume relate to one another.  They took 20 moles of a sample gas and kept the room at a temperature of 300 Kelvin.  They then used different sized containers of the gas to limit and expand the volume.  At each different volume, they measure the pressure of the gas on its container.  The table they made from their results is seen in table 1.

TABLE 1 

And they graph their findings in Figure 1.

FIGURE 1

If the same 20 moles of the same gas were taken to sea level (at a pressure of 100,000 Pascals) and heated to 300 Kelvin, how large would the volume of the container be to hold it at its new pressure?

During digestion, the energy in food is converted to energy the body can use. Scientists use calorimetry experiments to measure the calories, or energy, provided by food when it is digested or burned. 

The relationship used to find the heat transferred energy  is given by , where  is the mass of the material,  is the given specific heat capacity, and  is the change in temperature of the material. 

In this experiment, food was burned over a Bunsen burner under a can of 200 ml of water. The temperature change of the water and mass change of the food can be used to determine the calories in four different food items.

Table 1 shows the values of the change of mass of the food items, the change in temperature of the water and the energy. Table 2 shows the energy to mass ratio of three of those food items.

                                                    Table 1

                                  Roasted Peanut  Peanut    Cracker    Cheese Puff

Water Temp. Initial         23.9 °C           33.2 °C     40.3 °C      53.9 °C

Water Temp. Final           30.0 °C           40.9 °C     55.9 °C      62.8 °C

Food Mass Initial             0.69 g             0.61 g       3.21 g        1.22 g

Food Mass Final               0.38 g             0.21 g       0.91 g        0.48 g

Energy                            1.22 Cal          1.54 Cal     3.12 Cal     1.78 Cal

                           Table 2

Sample         Energy to Mass Ratio (Cal/g)

     1                                 1.36

     2                                 3.93

     3                                 2.40

Based on the results shown in Table 1 from the experiment, what is the relationship between the mass change of the food sample and the calories in the food?

Two students are studying hydrocarbon combustion, or the burning of compounds containing carbon and hydrogen in the presence of oxygen gas. Both students express their views on this phenomenon. 

Student 1: Hydrocarbons are high in energy and therefore naturally burn in order to release that energy. That energy is released in the form of light and heat. If water is thrown onto a fire, it will extinguish it because it cuts the combustion from the oxygen gas required for it to burn.

Student 2: Hydrocarbons are compounds at a greater energy state than the compounds produced when they burn. This excess energy changes to heat when hydrocarbons burn. Lastly, hydrocarbons require a spark to initiate the combustion. 

Which of the following statements would both students be most likely to agree?

Two students are studying hydrocarbon combustion, or the burning of compounds containing carbon and hydrogen in the presence of oxygen gas. Both scientists express their views on this phenomenon.

Student 1: Hydrocarbons are high in energy and therefore naturally burn in order to release that energy. That energy is released in the form of light and heat. If water is thrown onto a fire, it will extinguish it because it cuts the combustion from the oxygen gas required for it to burn. 

Student 2: Hydrocarbons are compounds at a greater energy state than the compounds produced when they burn. This excess energy changes to heat when hydrocarbons burn. Lastly, hydrocarbons require a spark to initiate the combustion. 

Which of the following statements would Student 2 be most likely to agree with and not Student 1?