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Example Questions
Example Question #1 : Concentration And Units
How many liters of 10M HCl are needed to make 4L of 0.4M solution?
A simple calculation can be done to perform any solution dilution problem. We know our equation .
We can rewrite this as .
Using this formula, we take the old solution and set it equal to the new solution.
We need 0.16 liters of our 10 molar solution.
Example Question #2 : Titrations
Which solution has the highest molarity?
This question requires us to calculate molarity for each answer choice. It is important to add everything correctly and be careful with more complex compounds.
Molarity is simply moles of solute over liters of solution. The correct answer, after trying each, is the answer with lead (II) nitrate, as it gets us a molarity of 2.
Example Question #3 : Concentration And Units
Which of the following is equivalent to molarity?
Kilograms of solute per mole of solution
Moles of solute per liter of solvent
Moles of solute per liter of solution
Moles of solute per kilogram of solvent
Moles of solute per liter of solution
Molarity, molality, and normality are the three principle ways to measure concentration. Molarity is a measure of moles of solute per liter of solution. Molality is a measure of moles of solute per kilogram of solvent. Normality expressly relates to acids and bases, and is the measure of moles of solute divided by the number of hydrogen equivalents per mole, all divided by liters of solution. Normality is also referred to as "equivalents (of acid) per liter."
Example Question #6 : Concentration And Units
Given that 50 mL of 3M HI was present, what volume would be needed to change the concentration to 0.75M?
150mL
50mL
200mL
180mL
150mL
Use the equation M1V1 = M2V2, and plug in the corresponding values to solve for V2:
V2 = (3)(50)/(0.75) = 200mL
We started out 50mL of the solution, so you have to add 150mL to get a final volume of 200mL.
Example Question #3 : Concentration And Units
What is the concentration of Ca in a solution of 1 mol CaCl2 in 1 L of distilled water? (M = molarity, m= molality)
The definition of molality is moles of solute in 1 kg of the solvent, whereas molarity is the number of moles of solute per 1 L of solutioin. Since 1 mol of CaCl2 is added to 1 L of water, this means that the volume of the final solution is greater than 1 L. Thus, molality is the more accurate concentration determinant, since the solution is probably close to 1 L.
Example Question #1 : Titrations
Which of the following aqueous solutions is the most concentrated?
All of these solutions have the same concentration.
In order to answer this question, it helps to know that 1 kilogram of water is equal to 1 liter of water, due to its density. Two of the above options refer to a 1m solution of hydrochloric acid. The other is a 1M solution.
All three of the options have the same amount of hydrochloric acid (one mole). For molarity, the hydrochloric acid is diluted with water until one liter of solution is created. For molality, one mole of HCl is added to one kilogram of water. Since one kilogram of water is one liter, this becomes the same concentration.
One a very small level, the 1M HCl solution will be slightly more concentrated. Creating a molal solution does not take into account the volume of the solute. If, for example, 100 cubic centimeters of HCl were added to one kilogram of water, the resulting volume would be more than one liter, making the concentration slightly less than 1M. This discrepancy is usually not accounted for in basic chemistry, but you should be familiar with the concept.
Example Question #3 : Titrations
What is the molality of a solution created by mixing 4.3g into 43g of water?
Cannot be determined
Molality can be defined:
It is slightly different from Molarity and has different uses.
Example Question #2 : Titrations
How much solid NaOH must be dissolved to make 740mL of a 0.32M solution?
9.47g
4.26g
The sodium hydroxide will boil off with the water
9.47 * 102g
12.8g
9.47g
This problem can be solved by stoichiometry. Remember that 0.32M gives us the moles of NaOH per liter, and solve for the number of moles per 0.740L.
Example Question #2 : Identifying Unknown Concentration
Find the mass of in 10L of water if it is a 2m solution.
Molality is grams of solute per kilogram of solvent.
Water has a density of one gram per mililiter, so one liter of water equal to one kilogram. If we have a 2m solution, that means we have two moles of per kilogram of water.
has a molecular weight of .
This gives us of .
Example Question #81 : Acid Base Chemistry
A chemist has a bottle containing a 2M aqueous solution of hydrochloric acid. He needs to create a 50mL solution of hydrochloric acid that has a concentration of 0.5M. What is the volume of 2M hydrochloric acid that he should dilute in order to achieve the desired concentration?
In order to dilute the concentrated acid, we need to find the amount of concentrated acid that will be diluted to 50mL of total solution. We can find the volume of concentrated acid necessary by setting the final volume and concentration equal to the initial concentration and unknown volume.
The initial concentration is 2M, the final concentration is 0.5M, and the final volume is 50mL
This means that 12.5mL of concentrated acid needs to be diluted to 50mL of solution. This will result in a solution with a concentration of 0.5M.
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