AP Chemistry : Solutions and States of Matter

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #11 : Other Solution Concepts

A solution was prepared by diluting 10mL of a 0.500M salt solution to 20mL. What would be the final concentration of this solution?

Possible Answers:

Correct answer:

Explanation:

Use the dilution formula:

Rearranging this equation gives:

Plugging in the values gives:

Therefore, after diluting the solution to 20mL, the solution concentration would be lowered from 0.50M to 0.25M.

Example Question #51 : Solutions

Which of the following is a weak electrolyte?

Possible Answers:

Correct answer:

Explanation:

Solutes that dissociate completely in a solution are called strong electrolytes. Weak electrolytes stay paired to some extent in solutions. As a result, strong electrolytes include ionic compounds and strong acid and bases.

Example Question #13 : Other Solution Concepts

Which of the following definitions is false?

Possible Answers:

Solubility product, , is the product of ion concentrations at equilibrium in a supersaturated solution of salt.

Ion-product constant of water, , is the product of equilibrium concentration of  and  ions in an aqueous solution at .

Molality is the number of moles of solute in a solution divided by the number of kilogram of solvent.

The van't Hoff factor, i, is the number of ions that a compound produces in a solution.

Correct answer:

Solubility product, , is the product of ion concentrations at equilibrium in a supersaturated solution of salt.

Explanation:

Solubility product, , is the product of ion concentrations at equilibrium in a saturated solution of salt. All other definitions are true.

Example Question #1 : Deviations From Ideal Gas Law

Under which conditions would you expect Ar to deviate the most from ideal behavior?

Possible Answers:

200 K and 1 atm

Ar always behaves ideally

200 K and 10 atm

300K and 5 atm

300K and 10 atm

Correct answer:

200 K and 10 atm

Explanation:

The ideal gas law assumes the gas particles are non-interacting and small relative to the size of their container.  At 200K (lowest temperature in the list, and the highest pressure).  This gives Ar the most time to interact due to molecular speeds and the high pressure implies the molecular size is not insignificant relative to the container.

Example Question #1 : Deviations From Ideal Gas Law

Would you expect a polar or non polar gas to deviate most from ideal gas behavior?

Possible Answers:

Polar gases because of hydrogen bonding

Polar gases, because of high dipole-dipole interactions

Non polar gases, because of high dispersion interactions

Both polar and non polar gases behave ideally

Non polar gases because of reduced overall intermolecular forces

Correct answer:

Polar gases, because of high dipole-dipole interactions

Explanation:

Polar gases would have increased interactions due to their dipoles that would lead to deviations from ideal gas behavior.

Example Question #1 : Deviations From Ideal Gas Law

Which of the following would behave most like an ideal gas?

Possible Answers:

All are ideal gases because they are non-polar

 in 10 L

 in 10 L

 in 10 L

 in 10 L

Correct answer:

 in 10 L

Explanation:

 is the smallest molecule in the list, and therefore the least size effects.

Example Question #622 : Ap Chemistry

Why do gases deviate from ideal behavior as the temperature is decreased?

Possible Answers:

As the temperature is decreased the molecules have more kinetic energy and break the intermolecular interactions keeping them together.

None of the above.

As the temperature is decreased the molecules have less kinetic energy and can’t maintain the intermolecular forces necessary for ideal gas behavior.

As the temperature is decreased the molecules have less kinetic energy and can’t break the intermolecular interactions between them.

As the temperatures is decreased the molecules become frozen in place.

Correct answer:

As the temperature is decreased the molecules have less kinetic energy and can’t break the intermolecular interactions between them.

Explanation:

The ideal gas law assumes the gas particles are non-interacting and small relative to the size of their container.  As the temperature is decreased the gas molecules are moving slower and allow for a greater degree of interaction.

Example Question #623 : Ap Chemistry

When does a gas behave most like an ideal gas?

Possible Answers:

At low temperatures, low volume, low intermolecular interactions

At high temperatures, high volume, low intermolecular interactions

At low volumes, high temperatures, and high intermolecular interactions

At low temperatures, high volume, and low intermolecular interactions

At high temperature, high volumes, and high intermolecular interactions

Correct answer:

At high temperatures, high volume, low intermolecular interactions

Explanation:

The ideal gas law assumes the gas particles are non-interacting and small relative to the size of their container.  At high temperatures the gas molecules are moving fast enough to shorten the time scale for any interactions.  At high volumes, the molecular size becomes small relative to the size of the container, and the low interactions mean the molecules act more independently.

Example Question #1 : Representations Of Solutions

Which of these solutions can be separated via chromatography?

Possible Answers:

B and C

Ethanol and water

None of the above

A homogeneous solution of organic solvents

Soil and water

Correct answer:

B and C

Explanation:

Chromatography is the physical separation of components of a mixture.  Answers b and c can be separated by chromatography due to their homogeneous nature.  The soil and water example would be separated by filtration.

Example Question #2 : Representations Of Solutions

Which of the following would most likely form a homogeneous solution?

Possible Answers:

NaNO3 and octanol (C8H18O)

Water and benzene (C6H6)

NH4Cl and water

A and B

All would form homogeneous solutions

Correct answer:

NH4Cl and water

Explanation:

Like dissolves like.  The NH4Cl and water mixture involves an ionic solid and a polar solvent. Examples a and b involve mixing polar/non-polar solvents and ionic and non-polar solvents.

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