MCAT Physical : MCAT Physical Sciences

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #6 : Power

Two students (student X and student Y) lift a boulder vertically from point A to point B. Student X directly lifts the boulder from point A to point B, whereas student Y uses a pulley to lift the boulder. This allows student Y to apply a force () that is three times smaller than the force applied by student X (). Both students apply force upwards and take the same amount of time to complete this task.

The vertical distance between point A and point B is .

The power exerted by student Y is __________.

Possible Answers:

equal to force exerted by student Y times two

less than the power exerted by student X

equal to the power exerted by student X

equal to the force exerted by student Y times five

Correct answer:

less than the power exerted by student X

Explanation:

To answer this question you need to know the definitions of work and power:

The units of work and power are Joules and watts, respectively. The passage states that the amount of time it takes to complete the task is same for both students; therefore, you can ignore the effects of time on power.

The passage also states that student Y applies less force. Since student Y applies less force, he has to expend less energy (work) than student X. This means that student Y also has to exert less power. A reduction in force will reduce work, and subsequently reduce power. We can thus conclude that student Y exerts less power than student X.

Example Question #7 : Power

Two students (student X and student Y) lift a boulder vertically from point A to point B. Student X directly lifts the boulder from point A to point B, whereas student Y uses a pulley to lift the boulder. This allows student Y to apply a force () that is three times smaller than the force applied by student X (). Both students apply force upwards and take the same amount of time to complete this task.

The vertical distance between point A and point B is .

If student Y exerts a force of and completes the task in . What is the power exerted by student X?

Possible Answers:

Correct answer:

Explanation:

The first step is to find the force exerted by student X. The passage states that student Y exerts three times less force than student X; therefore, student X exerts three times more than student Y:

The second step is to find the amount of work done by student X.

Remember that student X directly lifts the boulder from point A to point B. This means that the distance the boulder travels is the vertical distance between point A and B ().

The question states that time for the entire process is . Since the time is the same for both students, power exerted by student X is:

The correct answer is .

Example Question #1 : Mirrors And Lenses

The focal point for a mirror is 56cm behind the mirror. Is the mirror concave or convex, and what is its radius of curvature?

Possible Answers:

Concave with radius of curvature of 28cm

Concave with radius of curvature of 112cm

Convex with radius of curvature of 112cm

Convex with radius of curvature of 28cm

Correct answer:

Convex with radius of curvature of 112cm

Explanation:

Since the focal point falls behind the mirror it must be convex. The radius of curvature can be found using the focal length equation.
 



Example Question #2 : Mirrors And Lenses

A concave mirror has a radius of curvature of 0.85m. Where is the mirror's focal point?

Possible Answers:

The focal point cannot be found from the given information

Correct answer:

Explanation:

Since the mirror is concave, the focal point will be in front of the mirror. The focal length is equal to one half of the radius of curvature.



Rc is the radius of curvature. Plugging in 0.85m for Rc allows us to solve for the focal length.


0.43m is equal to 43cm.

Example Question #1 : Focal Length

A lens has a focal length of . What is the strength and type of lens?

Possible Answers:

, diverging lens

, converging lens

, diverging lens

, converging lens

Correct answer:

, diverging lens

Explanation:

Since the focal length is negative, the lens is diverging.

The diopter of a lens is found through the following formula:

Since the focal length of the lens is :

Example Question #12 : Compounds, Molecules, And Bonds

Carbon dioxide and water are the two products formed from the combustion of a hydrocarbon. What type of intermolecular forces are present for water?

Possible Answers:

Hydrogen bonding and dipole-dipole attraction

Hydrogen bonding, London dispersion forces, and dipole-dipole attraction

Hydrogen bonding

 

Dipole-dipole attraction

London dispersion forces

Correct answer:

Hydrogen bonding, London dispersion forces, and dipole-dipole attraction

Explanation:

Water exhibits hydrogen bonding. Each hydrogen atom is bond to a highly electronegative oxygen atom, resulting in a slight positive dipole on the hydrogen and a slight negative dipole on the oxygen. Within a solution of water, these dipoles can align, causing attractive forces between the hydrogens of one water molecule and the oxygen of another. Hydrogen bonding is a specialized form of dipole moment; since water has a permanent dipole moment, dipole-dipole attractions are present. Finally, like all molecules, water exhibits London dispersion intermolecular forces as well.

Example Question #11 : Compounds, Molecules, And Bonds

Boiling point is the temperature a liquid needs to achieve in order to begin its transformation into a gaseous state. Campers and hikers who prepare food during their trips have to account for differences in atmospheric pressure as they ascend in elevation. During the ascent, the decrease in atmospheric pressure changes the temperature at which water boils.

Further complicating the matter is the observation that addition of a solute to a pure liquid also changes the boiling point. Raoult’s Law can be used to understand the changes in boiling point if a non-volatile solute is present, as expressed here.

In this law,  is the mole fraction of the solvent, is the vapor pressure of the pure solvent, and  is the vapor pressure of the solution. When this vapor pressure is equal to the local atmospheric pressure, the solution boils.

Of the following types of forces, which is most likely responsible for explaining the high vapor pressure of a very volatile chemical species?

Possible Answers:

Coordinate covalent bonds

Van der Waals forces

Dipole-dipole bonds

Polar covalent bonds

Hydrogen bonds

Correct answer:

Van der Waals forces

Explanation:

Phase phenomena, such as vapor pressure, are best explained as a product of intermolecular forces. Strong intermolecular forces, like hydrogen bonds or dipole interactions, would make us expect weak vapor pressure, increasing attraction between molecules in the same phase and preventing transition. Large vapor pressures are more likely due to weak van der Waals intermolecular interactions, rather than stronger forces.

Example Question #12 : Compounds, Molecules, And Bonds

Which is not true of London dispersion forces?

Possible Answers:

They are the weakest intermolecular force

They only exist between polar molecules

They result from an asymmetrical distribution of electrons

They are caused by temporary dipoles

They occur more frequently between larger atoms

Correct answer:

They only exist between polar molecules

Explanation:

London dispersion forces are weak, temporary attracting forces caused when electrons in adjacent atoms move into asymmetrical arrangements about their nuclei, forming temporary dipoles. Since electrons are constantly moving in any atom, both polar and nonpolar substances can develop temporary dipoles and experience London dispersion forces. These forces occur randomly as electrons form spontaneous polarized distributions, before immediately dissipating as the electrons move to new positions.

Example Question #14 : Compounds, Molecules, And Bonds

A student mislabels three jars containing three different molecules. The student frantically tries to find the identity of the molecules in each jar. He knows that the three possible molecules are methanol (), dichloromethane (), and propane (). At room temperature, he observes that one of the jars contains a gas, whereas the other two jars contain liquids. He then finds the boiling point of each jar. The molecule from jar A has a boiling point of , jar B has a boiling point of , and jar C has a boiling point of . Based on his findings he is able to determine the identity of the molecules in each jar.

What is the identity of jar B?

Possible Answers:

Dicholormethane, because it only contains dipole-dipole interactions, the strongest intermolecular force

Propane, because it only contains London dispersion forces, the weakest intermolecular force

Propane, because it only contains London dispersion forces, the strongest intermolecular force

Dichloromethane, because it only contains dipole-dipole interactions, the weakest intermolecular force

Correct answer:

Propane, because it only contains London dispersion forces, the weakest intermolecular force

Explanation:

The passage states that jar B has a boiling point of , the lowest of all three molecules; therefore, jar B contains molecules that have the weakest intermolecular forces. Of all the intermolecular forces, London dispersion forces (or van der Waals forces) are the weakest. These forces occur in all molecules because the movement of electrons inside molecules causes brief polarities that can be used to form intermolecular forces. Since they are so brief, London dispersion forces are very weak and easy to break.

Many nonpolar molecules, such as propane, only contain London dispersion forces and lack all forms of dipole interaction. This results in very weak intermolecular interactions for these compounds, and will affect physical properties like vapor pressure, boiling point, and surface tension. Weak intermolecular forces will increase vapor pressure, decrease boiling point, and decrease surface tension.

Remember that polar molecules, such as methanol and dichloromethane, also contain London dispersion forces. They just contain much stronger forces (hydrogen bonding and dipole-dipole interactions) that make the London dispersion forces negligible.

Example Question #91 : Mcat Physical Sciences

Halogens start out as gases (fluorine and chlorine), but transition to liquid (bromine) and then to solid (iodine) when moving down group 17 of the periodic table. This is because __________.

Possible Answers:

the atoms become heavier

the atoms lose their valence electrons more easily

London dispersion forces increase as the molecules become larger

the larger molecules have larger electronegativities, making them cluster closer together with one another

Correct answer:

London dispersion forces increase as the molecules become larger

Explanation:

The effects of London dispersion forces are best demonstrated by viewing the halogen group. The lighter halogens are gaseous at room temperature, but transition to liquid and then to solid when moving down the group (bromine is a liquid, and iodine is a solid). When moving down the group, the halogens become much larger. Larger atoms experience greater London dispersion forces due to increased surface contact and greater polarizability. These increased London dispersion forces are enough to raise the boiling points of the larger atoms, causing them to exist as liquids of gases at room temperature.

While it is true that the larger atoms are heavier and will lose their valence electrons more readily, these factors do not impact the phase of the compound.

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