A student wanted to study the kinetics, or rates of a chemical reaction based on the concentrations of its reactants and products, of the reaction shown below.

This reaction is easy to monitor using a spectrophotometer, which measures how much light of a particular wavelength is absorbed by a solution. The deep purple potassium permanganate, or , absorbs light of a 550 nm wavelength in proportion to its concentration in the reaction solution. Manganese sulfate, or , is pale pink and absorbs light of a 500 nm wavelength in proportion to its concentration in the reaction solution. All other reactants and products are colorless and do not absorb visible light and thus cannot be monitored using the spectrophotometer.

Experiment 1:

The student constructed a standard curve, or a graph of the absorbance of solutions of varying concentrations of potassium permanganate, to quantify the relationship between concentration and absorbance. To prepare five sample of increasing concentration, he labeled five test tubes A, B, C, D, and E, weighed out 0.1, 0.2, 0.3, 0.4, and 0.5 grams of potassium permanganate into each, respectively, and added 1 milliliter (mL) of water to each test tube to dissolve. Then, he used the spectrophotometer to determine the absorbance at 550 nm of each sample. The data is graphed in Figure 1 below.

                                                        Figure 1

Experiment 2: 

The student then studied potassium permanganate in the presence of oxalic acid, , to observe the reaction. Monitoring both the absorbances of potassium permanganate and manganese sulfate, he was able to determine the reaction rate using a special setting on the spectrophotometer. The reaction rate at various concentrations of reactants is shown below in Table 1.

A scientific relationship, known as Beer's Law, mathematically correlates absorbance to concentration via the following equation:

where  is the absorbance,  is the concentration of the sample, and  is a constant specific for the chemical in the sample. According to Figure 1, what is the value of , in mL/g, for potassium permanganate?

A student wanted to study the kinetics, or rates of a chemical reaction based on the concentrations of its reactants and products, of the reaction shown below.

This reaction is easy to monitor using a spectrophotometer, which measures how much light of a particular wavelength is absorbed by a solution. The deep purple potassium permanganate, or , absorbs light of a 550 nm wavelength in proportion to its concentration in the reaction solution. Manganese sulfate, or , is pale pink and absorbs light of a 500 nm wavelength in proportion to its concentration in the reaction solution. All other reactants and products are colorless and do not absorb visible light and thus cannot be monitored using the spectrophotometer.

Experiment 1:

The student constructed a standard curve, or a graph of the absorbance of solutions of varying concentrations of potassium permanganate, to quantify the relationship between concentration and absorbance. To prepare five sample of increasing concentration, he labeled five test tubes A, B, C, D, and E, weighed out 0.1, 0.2, 0.3, 0.4, and 0.5 grams of potassium permanganate into each, respectively, and added 1 milliliter (mL) of water to each test tube to dissolve. Then, he used the spectrophotometer to determine the absorbance at 550 nm of each sample. The data is graphed in Figure 1 below.

                                                        Figure 1

Experiment 2: 

The student then studied potassium permanganate in the presence of oxalic acid, , to observe the reaction. Monitoring both the absorbances of potassium permanganate and manganese sulfate, he was able to determine the reaction rate using a special setting on the spectrophotometer. The reaction rate at various concentrations of reactants is shown below in Table 1.

The "special setting" on the spectrophotometer underlined in the description of Experiment 2 likely involves what?

The rate of a reversible chemical reaction depends on many factors, including concentrations of the reactants and products, temperature, and presence of enzymes called catalysts. In the forward reaction, two reactants combine to form one product. However, in a reverse reaction, the product is broken down into the two reactants.

In order for a forward reaction to occur, the reactants moving around in the test tube must physically interact with each other. The more often reactants interact with each other, the more produce is formed in the same amount of time. The speed at which reactants combine into products (the rate of the reaction) can be calculated by dividing the amount of a chemical produced in a reaction (often measured in moles) by the time it takes to produce that amount.

In order to determine the effects of reactant and product concentration, temperature, and presence of catalysts on the rate of a reaction, a scientist studied the following reaction:

The scientist varied the conditions of the experiment and measured the rate of the reaction. The results are outlined in Table 1. The units of concentration are moles per liter.

In order to display the relationship between the number of moles of H+ and the rate of the reaction in Experiments 1 and 4, the scientist could:

The rate of a reversible chemical reaction depends on many factors, including concentrations of the reactants and products, temperature, and presence of enzymes called catalysts. In the forward reaction, two reactants combine to form one product. However, in a reverse reaction, the product is broken down into the two reactants.

In order for a forward reaction to occur, the reactants moving around in the test tube must physically interact with each other. The more often reactants interact with each other, the more produce is formed in the same amount of time. The speed at which reactants combine into products (the rate of the reaction) can be calculated by dividing the amount of a chemical produced in a reaction (often measured in moles) by the time it takes to produce that amount.

In order to determine the effects of reactant and product concentration, temperature, and presence of catalysts on the rate of a reaction, a scientist studied the following reaction:

The scientist varied the conditions of the experiment and measured the rate of the reaction. The results are outlined in Table 1. The units of concentration are moles per liter.

The effect of temperature on the rate of reaction is best demonstrated by comparing which two trials?

The rate of a reversible chemical reaction depends on many factors, including concentrations of the reactants and products, temperature, and presence of enzymes called catalysts. In the forward reaction, two reactants combine to form one product. However, in a reverse reaction, the product is broken down into the two reactants.

In order for a forward reaction to occur, the reactants moving around in the test tube must physically interact with each other. The more often reactants interact with each other, the more produce is formed in the same amount of time. The speed at which reactants combine into products (the rate of the reaction) can be calculated by dividing the amount of a chemical produced in a reaction (often measured in moles) by the time it takes to produce that amount.

In order to determine the effects of reactant and product concentration, temperature, and presence of catalysts on the rate of a reaction, a scientist studied the following reaction:

The scientist varied the conditions of the experiment and measured the rate of the reaction. The results are outlined in Table 1. The units of concentration are moles per liter.

If a scientist desired to produce the most HCl possible in a reaction, the scientist could:

The rate of a reversible chemical reaction depends on many factors, including concentrations of the reactants and products, temperature, and presence of enzymes called catalysts. In the forward reaction, two reactants combine to form one product. However, in a reverse reaction, the product is broken down into the two reactants.

In order for a forward reaction to occur, the reactants moving around in the test tube must physically interact with each other. The more often reactants interact with each other, the more produce is formed in the same amount of time. The speed at which reactants combine into products (the rate of the reaction) can be calculated by dividing the amount of a chemical produced in a reaction (often measured in moles) by the time it takes to produce that amount.

In order to determine the effects of reactant and product concentration, temperature, and presence of catalysts on the rate of a reaction, a scientist studied the following reaction:

The scientist varied the conditions of the experiment and measured the rate of the reaction. The results are outlined in Table 1. The units of concentration are moles per liter.

In Experiment 8, if the moles of H+ were doubled, the expected rate of the reaction would be:

The rate of a reversible chemical reaction depends on many factors, including concentrations of the reactants and products, temperature, and presence of enzymes called catalysts. In the forward reaction, two reactants combine to form one product. However, in a reverse reaction, the product is broken down into the two reactants.

In order for a forward reaction to occur, the reactants moving around in the test tube must physically interact with each other. The more often reactants interact with each other, the more produce is formed in the same amount of time. The speed at which reactants combine into products (the rate of the reaction) can be calculated by dividing the amount of a chemical produced in a reaction (often measured in moles) by the time it takes to produce that amount.

In order to determine the effects of reactant and product concentration, temperature, and presence of catalysts on the rate of a reaction, a scientist studied the following reaction:

The scientist varied the conditions of the experiment and measured the rate of the reaction. The results are outlined in Table 1. The units of concentration are moles per liter.

The direction of the reaction most likely depends on:

Both gases and liquids are considered to be fluids that have individual molecules that move around with kinetic and potential energy. Kinetic energy, defined as the energy related to motion, takes three forms: translational energy that occurs as a molecule moves from position A to position B, rotational energy that occurs as a molecule spins around an imaginary axis at its center of mass, and vibrational energy that occurs as individual atoms in a molecular bond move towards and away from each other. Usually, molecules possess varying combinations of kinetic energy forms. In contrast, potential energy is defined as stored energy that could be released to become kinetic energy. The total energy of a molecule is fixed, meaning that a molecule has some combination of kinetic and potential energies.

Varying amount of kinetic and potential energies define how molecules in a fluid interact with each other. For example, when the kinetic energy of a molecule is high (greater than 1000J), it can no longer interact with neighboring molecules strongly enough to remain a liquid. However, if the potential energies are too high (greater than 1000 J), molecules cannot escape a liquid to become a gas. If the kinetic energy is high and the potential energy is low, molecules tend to become a gas and can be modeled by an equation known as the Ideal Gas Law:

Where P is the pressure of a gas, V is the volume, n is the number of moles of a gas, R is a constant, and T is temperature in degrees Kelvin.

The Ideal Gas Law perfectly applies to particles with no mass, no intermolecular interactions, and no true volume. However, real molecules do not adhere perfectly to the Ideal Gas Law.

If the kinetic and potential energies of a liter of oxygen molecule are 1500 J and 100 J, respectfully, the liter is most likely to be in what phase according to the passage? 

Both gases and liquids are considered to be fluids that have individual molecules that move around with kinetic and potential energy. Kinetic energy, defined as the energy related to motion, takes three forms: translational energy that occurs as a molecule moves from position A to position B, rotational energy that occurs as a molecule spins around an imaginary axis at its center of mass, and vibrational energy that occurs as individual atoms in a molecular bond move towards and away from each other. Usually, molecules possess varying combinations of kinetic energy forms. In contrast, potential energy is defined as stored energy that could be released to become kinetic energy. The total energy of a molecule is fixed, meaning that a molecule has some combination of kinetic and potential energies.

Varying amount of kinetic and potential energies define how molecules in a fluid interact with each other. For example, when the kinetic energy of a molecule is high (greater than 1000J), it can no longer interact with neighboring molecules strongly enough to remain a liquid. However, if the potential energies are too high (greater than 1000 J), molecules cannot escape a liquid to become a gas. If the kinetic energy is high and the potential energy is low, molecules tend to become a gas and can be modeled by an equation known as the Ideal Gas Law:

Where P is the pressure of a gas, V is the volume, n is the number of moles of a gas, R is a constant, and T is temperature in degrees Kelvin.

The Ideal Gas Law perfectly applies to particles with no mass, no intermolecular interactions, and no true volume. However, real molecules do not adhere perfectly to the Ideal Gas Law.

If the kinetic and potential energies of a liter of oxygen molecules are 250 J and 1200 J, respectfully, the liter is most likely to be in what phase according to the passage?

Both gases and liquids are considered to be fluids that have individual molecules that move around with kinetic and potential energy. Kinetic energy, defined as the energy related to motion, takes three forms: translational energy that occurs as a molecule moves from position A to position B, rotational energy that occurs as a molecule spins around an imaginary axis at its center of mass, and vibrational energy that occurs as individual atoms in a molecular bond move towards and away from each other. Usually, molecules possess varying combinations of kinetic energy forms. In contrast, potential energy is defined as stored energy that could be released to become kinetic energy. The total energy of a molecule is fixed, meaning that a molecule has some combination of kinetic and potential energies.

Varying amount of kinetic and potential energies define how molecules in a fluid interact with each other. For example, when the kinetic energy of a molecule is high (greater than 1000J), it can no longer interact with neighboring molecules strongly enough to remain a liquid. However, if the potential energies are too high (greater than 1000 J), molecules cannot escape a liquid to become a gas. If the kinetic energy is high and the potential energy is low, molecules tend to become a gas and can be modeled by an equation known as the Ideal Gas Law:

Where P is the pressure of a gas, V is the volume, n is the number of moles of a gas, R is a constant, and T is temperature in degrees Kelvin.

The Ideal Gas Law perfectly applies to particles with no mass, no intermolecular interactions, and no true volume. However, real molecules do not adhere perfectly to the Ideal Gas Law.

At a constant volume, the relationship between pressure and temperature as presented in the passage may best be depicted as: