MCAT Physical : Atoms, Elements, and the Periodic Table

Study concepts, example questions & explanations for MCAT Physical

varsity tutors app store varsity tutors android store

Example Questions

Example Question #921 : Mcat Physical Sciences

An acid’s strength is related to the ease with which hydrogen atoms in the acid can dissociate into hydrogen ions. The weaker the bond between the hydrogen and the acid molecule, the stronger the acid. Based on this information, which halogen will form the strongest acid?

Possible Answers:

Fluorine because it has the highest electronegativity

Iodine because it has the lowest electronegativity

Iodine because it has the largest atomic radius

Fluorine because it has the smallest atomic radius

Correct answer:

Iodine because it has the lowest electronegativity

Explanation:

The question states that a stronger acid will possess a weaker bond between the hydrogen atom and the acid. To have a weak bond, it is essential to have a non-metal atom that will repel electrons from the hydrogen. This will enable the hydrogen atom to distance itself from the acid, which will make the bond weaker (it will make it easier to remove the hydrogen atom).

Recall that electronegativity of an atom is defined as the ability of the atom to pull electrons towards itself. An atom with a high electronegativity will have high attraction for electrons, whereas an atom with low electronegativity will have low attraction for electrons; therefore, to have a strong acid, the non-metal atom must have a low electronegativity. In the periodic table, the electronegativity decreases as you go from right to left and top to bottom. This means that iodine will have a lower electronegativity than fluorine and will form the strongest acid.

Remember that fluorine is the most electronegative atom in the entire periodic table. Every halogen, except fluorine, forms a strong acid. , , and  are all strong acids ( is the strongest), whereas  is a weak acid due to the strength of the bond between hydrogen and fluorine.

Example Question #922 : Mcat Physical Sciences

Which of the following is true of a neutral halogen?

Possible Answers:

It has more valence electrons than the noble gas in its period

Its electron configuration ends with 

It has an unpaired electron in one of its  orbitals

It has lower affinity for electrons than the alkali metal in its period

Correct answer:

It has an unpaired electron in one of its  orbitals

Explanation:

Neutral halogens are found in group 17 of the periodic table. These elements contain seven valence electrons and have electron configurations that end with , where  is the outermost shell number and corresponds with the period (row) of the halogen.

The outermost shell contains seven valence electrons (two in the  orbital and five in the  orbital). If the electron configuration ended in  then the halogen has an extra electron, has a complete octet, and is not neutral (has a charge of ).

Noble gases are found in group 18 of the periodic table. The key characteristic of noble gases is their eight valence electrons (complete octet) in the ground state; therefore, noble gases have one more valence electron than a neutral halogen in the same row. Alkali metals are found in group 1 of the periodic table. They only have one valence electron. The easiest way for them to complete an octet is to lose an electron. Halogens, on the other hand, have seven valence electrons and gain an electron to complete octet. This means that halogens have more attraction (affinity) for electrons than the alkali metals.

The electron configuration of a neutral halogen ends in . There are a total of three  orbitals in a shell, and each  orbital can contain two electrons. This means that  orbitals can contain a total of six electrons. In the nth shell of a neutral halogen, the  orbitals only contain five electrons. Two  orbitals will contain two paired electrons, and one  orbital will only contain one, unpaired electron; therefore, a neutral halogen will have a  orbital with an unpaired electron. 

 

Example Question #1 : Periodic Table Groupings

Which of the following is a characteristic of the halogens?

I. They are good oxidizing agents

II. They complete an octet by gaining two electrons

III. They have high electronegativities

Possible Answers:

I, II, and III

I and III

II only

II and III

I only

Correct answer:

I and III

Explanation:

Halogens are elements found in group 17 of the periodic table. They are characterized by their seven valence electrons. To complete an octet, halogens only need to gain a single electron. Since they gain electrons, halogens are usually reduced and serve as good oxidizing agents. Recall that when a substance is reduced it is also classified as an oxidizing agent because it can oxidize another atom (remove an electron from another atom). 

Halogens gain an electron to complete an octet because they have seven valence electrons. The elements in the oxygen group (group 16) gain two electrons to complete an octet because they have six valence electrons.

Halogens are highly electronegative. Electronegativity is defined as the ability of an atom to pull electrons towards itself. Since they need only one electron to complete an octet, halogens have high attraction towards electrons and, consequently, have high electronegativity values. Note that electronegativity increases as you go from left to right on the periodic table; therefore, halogens have the highest electronegativity of any group. Noble gases (group 18) are inert and do not have any attraction for electrons (low electronegativity).

Example Question #7 : Periodic Table Groupings

An unknown element has been studied in the lab. It has been shown to be malleable, ductile, and a good conductor of heat. Which element best fits this description?

Possible Answers:

Silicon

Cobalt

Boron

Sulfur

Correct answer:

Cobalt

Explanation:

The correct answer is cobalt, since it is the only metal among the answer choices. Metals have all the properties described (malleability, ductility, and conductivity). Sulfur, boron, and silicon do not exhibit these properties to the same extent.

Example Question #1 : Metals

There is a unknown element in a jar. It is a solid at room temperature and conducts electricity. Which of the following could be true about this element?

Possible Answers:

The identity of the element is silicon and it can be stretched to create a thin wire

The identity of the element is silicon and it is a good oxidizing agent

The identity of the element is sodium and it can be stretched to create a thin wire

The identity of the element is sodium and it is a good oxidizing agent

Correct answer:

The identity of the element is sodium and it can be stretched to create a thin wire

Explanation:

The question states that the element is a solid at room temperature and conducts electricity. These are characteristics of a metal; therefore, the element is likely a metal. Recall that metals are usually found on the left side of the periodic table. The groups that are classified as metals include the alkali metals (group 1), alkaline earth metals (group 2), the aluminum family (group 3), and the transition metals (D block).

The answer choices state that it could be either sodium or silicon. Silicon is in group 14 and is considered a non-metal; therefore, the element has to be sodium. Metals are good electrical conductors and solid at room temperature. They are also ductile, which means that a metal can be stretched to create thin wires. 

Metals are good reducing agents, not oxidizing agents. Recall that metals usually have one, two, or three valence electrons. Since they only have a few valence electrons, metals prefer to lose their valence electrons to complete an octet. When an element loses electrons it is considered to be oxidized and can act as a reducing agent; therefore, sodium is not an oxidizing agent.

Example Question #1 : Periodic Table Groupings

Metals usually have __________ valence electrons and __________ electronegativities than non-metals.

Possible Answers:

fewer . . . lower

more . . . lower

fewer . . . higher

more . . . higher

Correct answer:

fewer . . . lower

Explanation:

Metals are found on groups on the left side of the period table (groups 1, 2, and 3, and transition metals). The groups on the left side have fewer valence electrons than the groups on the right side. Groups 1, 2, and 3 have one, two, and three valence electrons, respectively. Metals thus have fewer valence electrons than non-metals.

Electronegativity is a chemical property that is defined as the ability of an element to attract electrons towards itself. Since they have fewer valence electrons, metals find it easier to lose electrons to generate a complete octet (have eight valence electrons). Rather than attract electrons to fill octet, metals give them away. On the other hand, it is easier for non-metals to gain electrons to complete octet because they have larger amounts of valence electrons in their ground state. This means that non-metals have higher attraction for electrons and, consequently, have higher electronegativities.

Example Question #11 : Periodic Table Groupings

A mystery element is found in nature. It is very conductive and is able to be hammered into a thin layer without breaking. Based on these properties, where would you least expect to find this element on the periodic table?

Possible Answers:

The right side of the table

The left side of the table

The lanthanide period

This element could be found anywhere on the periodic table

The middle of the table

Correct answer:

The right side of the table

Explanation:

First off, it is important to know that the ability to be hammered into a sheet and conduct electricity are characterisitcs typically reserved for metals. With this in mind, we can check the periodic table, and see where on the table metals reside. Metallic character generally decreases as you go from left to right on the table, which results in nonmetals being found on the right side of the table. As a result, we would not expect to find this element and its metallic characteristics on the right side.

Example Question #12 : Periodic Table Groupings

What class of element is krypton?

Possible Answers:

Lanthanide

Metalloid

Halide

Noble gas

Correct answer:

Noble gas

Explanation:

The non-metals in group 8 are called noble gases because they tend to resist reactions with other atoms. Noble gases are the only elements to have valence octets in their ground states ().

Halides are the gases in group 7, which are most stable as negative ions to reflect the octet configurations of the noble gases. Lanthanides are the elements in period 6 that have an incomplete f shell. The metalloids are arranged along the diagonal between boron and polonium and divide the periodic table between the metals (to the left) and nonmetals (to the right).

Example Question #13 : Periodic Table Groupings

An unknown element has been shown to be unreactive. It has a low boiling point and an extremely high ionization energy. Which group does the element most likely belong to?

Possible Answers:

Noble gases

Alkali metals

Halogens

Alkaline earth metals

Correct answer:

Noble gases

Explanation:

The properties described fit well with the noble gases. Alkali and alkaline earth elements are solid at room temperature, meaning that they have a high boiling point. Halogens can be gaseous at room temperature, but are very reactive. Noble gases have low boiling points and rarely act in spontaneous reactions. Their properties are due to their full valence shell, which is the source of their stability. Changes to their electron configuration (such as removing an electron) require large amounts of energy.

Example Question #14 : Periodic Table Groupings

Which of the following groups has the highest number of valence electrons?

Possible Answers:

Alkali metals

Halogens

Noble gases

Alkaline earth metals

Correct answer:

Noble gases

Explanation:

The amount of valence electrons increases as you go from left to right on the periodic table. The lowest number of valence electrons is found in the alkali metals (group 1), which have only one valence electron per atom. The largest amount is found in the noble gases (group 18), which have a total of eight valence electrons. Noble gases have a complete octet; therefore, they are inert molecules that do not readily participate in chemical reactions.

Alkaline earth metals have two valence electrons, and halogens have seven.

Learning Tools by Varsity Tutors