MCAT Physical : Electrochemistry

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #1 : Voltaic/Galvanic Cells

When a galvanic cell contains two different solutions, a salt bridge is often required. The salt bridge allows the two solutions to remain isolated by providing ionic interactions for both solutions, without severely reducing the potential difference. The salt bridge is commonly composed of a potassium chloride solution.

In what direction would you expect the potassium ions to travel in a galvanic cell?

Possible Answers:

The ions will distribute evenly in the salt bridge

The potassium will remain bound to chlorine, and will not ionize

Toward the anode

Toward the cathode

Correct answer:

Toward the cathode

Explanation:

Potassium ions (K+) will be positively charged, which means they will travel towards the side of the cell that is more negative. Reduction takes place at the cathode, because electrons flow from the anode to the cathode. Since negative charge accumulates at the cathode, the cations will travel in that direction, while the anions will travel towards the anode.

Example Question #171 : Physical Chemistry

Imagine a galvanic cell which uses solid zinc and aqueous iron ions to produce a voltage.

 

    

     

The cell above resulted in a transfer of 0.05mol of electrons. The cell ran for four minutes at a constant voltage. What is the current of the cell?

Possible Answers:

Correct answer:

Explanation:

This problem requires us to use dimensional analysis in order to compare what we know, and arrive at the current of the cell. First, we start by noting that the unit for current is Coulombs per second, or . Next, we combine the details of the galvanic cell in order to arrive at the appropriate units, and determine the current.

Example Question #2 : Batteries

You are charging your cell phone battery with your cell phone charger. What can you conclude about this process?

Possible Answers:

The cell phone battery is acting as a galvanic cell because it is releasing voltage

The cell phone battery is acting as a galvanic cell because it is acquiring voltage

The cell phone battery is acting as an electrolytic cell because it is releasing voltage

The cell phone battery is acting as an electrolytic cell because it is acquiring voltage

Correct answer:

The cell phone battery is acting as an electrolytic cell because it is acquiring voltage

Explanation:

A single battery can act as both a galvanic and an electrolytic cell. When a battery is discharging it is considered to be a galvanic cell because it is undergoing a spontaneous redox reaction and is losing voltage. On the other hand, when a battery is charging, it is acquiring voltage (from the phone charger that is connected to an outlet) and is considered an electrolytic cell.

Recall that electrolytic cells facilitate nonspontaneous reactions and require energy to carry out these unfavorable reactions. Charging a battery is a nonspontaneous process (because the reaction involved is the reverse of the reaction that occurs when the battery is discharging) and requires energy in the form of voltage input.

Example Question #1 : Other Electrochemical Principles

A researcher is analyzing an electrolytic cell. In trial 1, he applies  of current for two hours to the cell and observes that the cathode produces  of zinc metal. In trial 2, he applies the same amount of current but only for one hour. What will the researcher observe in the cathode during trial 2?

Possible Answers:

Smaller amount of zinc than trial 1 because the applied charge decreases

Same amount of zinc as trial 1 because the current stays the same

Same amount of zinc as trial 1 because the applied charge stays the same

Larger amount of zinc than trial 1 because the charge decreases

Correct answer:

Smaller amount of zinc than trial 1 because the applied charge decreases

Explanation:

Faraday’s Law states that the amount of substance produced in a half-cell is dependent on the charge applied to the system; therefore, the more charge applied the more substance produced. The question states that the researcher applies the same amount of current, but for a shorter time, in trial 2. Recall the definition of current:

This means that charge equals:

Trial 1 and Trial 2 have the same current; however, trial 2 has a smaller time. This means that the charge applied in trial 2 is smaller than the charge applied in trial 1; therefore, according to Faraday’s law, the researcher must observe a smaller mass of zinc metal in trial 2.

Example Question #21 : Electrochemistry

Faraday’s Law states that the amount of product in a cell __________ as the __________ increases.

Possible Answers:

increases . . . charge

decreases . . . time

decreases . . . charge

increases . . . time

Correct answer:

increases . . . charge

Explanation:

Faraday’s Law states that the amount of product in a half cell is proportional to the charge applied to the cell; therefore, the amount of product in a cell increases as the charge increases. Faraday’s Law states nothing about the relationship between the amount of product and time.

Example Question #2 : Other Electrochemical Principles

Which of the following substances cannot conduct electricity in water?

I. Sodium chloride

II. Iron (II) carbonate

III. Glucose

Possible Answers:

I only

I and II

II only

II and III

Correct answer:

II and III

Explanation:

The question asks you to pick substances that cannot conduct electricity. Recall that molecules that conduct electricity in solution are called electrolytes. In a chemical solution, a substance will conduct electricity if it can dissociate into ions; therefore, you are looking for molecules that will not dissociate into ions in water.

Sodium chloride, or , is an ionic compound that will dissociate into sodium ions and chlorine ions; therefore, sodium chloride will conduct electricity in water.

Iron (II) carbonate  is an insoluble compound in water. This means that it will not dissociate into ions and will not conduct electricity. Remember that most carbonates are insoluble in water.

Glucose is soluble in water because of its polar hydroxyl groups; however, it does not dissociate into ions. This means that glucose does not conduct electricity.

Example Question #4 : Other Electrochemical Principles

Listed below are three substances that dissolve in water.

I. Acetic acid

II. Acetone

III. Hydrochloric acid

Which of the following correctly lists the substances in decreasing order of electrical conductivity?

Possible Answers:

Correct answer:

Explanation:

Electrical conductivity is a measure of the ability of a substance to conduct electricity. A substance with a high electrical conductivity will easily conduct electricity, and a substance with low electrical conductivity will not conduct electricity.

In solution, a substance can conduct electricity if it can dissociate into ions. Of the three substances listed, hydrochloric acid is likely to have the highest electrical conductivity. Recall that hydrochloric acid () is a strong acid; therefore, it will completely dissociate into hydrogen and chlorine ions in water.

The substance with the second highest electrical conductivity is acetic acid. Although acetic acid is an acid, it is a weak acid. This means that the acetic acid will not completely dissociate into ions in water. If you have the same concentration of hydrochloric acid and acetic acid, hydrochloric acid will produce more ions in water and will be able to conduct more electricity; therefore, hydrochloric acid has a higher electrical conductivity than acetic acid.

Acetone is soluble in water; however, it does not dissociate into ions and will have the lowest electrical conductivity.

The correct order of electrical conductivity is: .

Example Question #1 : Oxidation Reduction In Electrochemistry

Imagine a galvanic cell that uses solid zinc and aqueous iron ions to produce a voltage.

 

    

     

Based on the above reaction, which of the following statements is correct?

Possible Answers:

 is oxidized at the anode, and  is reduced at the cathode

 is reduced at the cathode, and  is oxidized at the anode

 is oxidized at the cathode, and  is reduced at the anode

is reduced at the cathode, and is oxidized at the anode

 is reduced at the anode, and  is oxidized at the cathode

Correct answer:

 is oxidized at the anode, and  is reduced at the cathode

Explanation:

For the MCAT, remember "ANOX REDCAT." This will remind you that oxidation occurs at the anode, and reduction occurs at the cathode.

Since solid zinc (Zn) is giving up two electrons in the reaction, it is being oxidized. The iron ion (Fe2+) is accepting the two electrons, so it is being reduced.

Example Question #2 : Oxidation Reduction In Electrochemistry

Which of the following is false about anodes and cathodes?

     I. In a galvanic cell only, reduction occurs at the anode whereas oxidation occurs at the cathode

     II. Electron flows from anode to cathode in both galvanic and electrolytic cells

     III. Cathodes are only found in galvanic cells

Possible Answers:

I and III

II and III

I, II, and III

III

Correct answer:

I and III

Explanation:

An electrochemical cell undergoes two half-cell reactions (one oxidation reaction and one reduction reaction). Each half-cell reaction occurs either in a cathode or an anode; therefore, an electrochemical cell always has a cathode and an anode. Recall that there are two types of electrochemical cells: a galvanic cell and an electrolytic cell. Regardless of the type of the electrochemical cell, the reduction half-cell reaction always occurs in the cathode and the oxidation half-cell reaction always occurs in the anode; therefore, both galvanic and electrolytic cells have reduction occurring in the cathode and oxidation occurring in the anode. 

In both galvanic and electrolytic cells, electrons flow from the anode to the cathode. Anodes have free electrons because electrons are products of an oxidation reaction whereas cathodes require electrons because electrons are reactants of a reduction reaction; therefore, the free electrons flow from the anode to the cathode where they are used up in the reduction reaction. 

Cathodes are found in both galvanic and electrolytic cells. Recall the cathodes are the site of reduction half-reaction and anodes are the site of oxidation half-reaction.

Example Question #1 : Oxidation Reduction In Electrochemistry

Electrons are __________ in cathodes and __________ in anodes.

Possible Answers:

products . . . reactants

products . . . products

reactants . . . products

reactants . . . reactants

Correct answer:

reactants . . . products

Explanation:

The cathode is the site of reduction half-reaction, whereas the anode is the site of the oxidation half-reaction. In a reduction reaction molecules acquire electrons, whereas in an oxidation reaction molecules lose electrons. Electrons act as reactants during reduction reactions in the cathode, whereas they serve as products during oxidation reactions in the anode.

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