GRE Subject Test: Chemistry : Reaction Chemistry

Study concepts, example questions & explanations for GRE Subject Test: Chemistry

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Example Questions

Example Question #5 : Reactions With Inorganic Compounds

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Determine the theoretical yield in grams of  produced if 5.6 grams of  is reacted with excess .

Possible Answers:

Correct answer:

Explanation:

Convert the number of grams of  to moles:

Based on the chemical equation 1 mole of  is produced for every 2 mole of  reacted.

Therefore: 

Convert the moles of  to grams:

Example Question #6 : Reactions With Inorganic Compounds

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For the reaction given, identify the type of reaction taking place.

Possible Answers:

Synthesis reaction

Double displacement reaction

Combination reaction

Decomposition reaction

Correct answer:

Double displacement reaction

Explanation:

A displacement reaction is one in which an atom, ion or molecule moves from one compound to another to replace an atom, ion or molecule in another compound. In the reaction given,  ion moves from  to . Also, ion moves from  to .

Example Question #3 : Reactions With Inorganic Compounds

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Determine the percentage yield of the reaction given if 40.0 grams of  is heated to give 15.0 grams of .

Possible Answers:

Correct answer:

Explanation:

In chemistry, percentage yield is a term used to quantify the efficiency of a chemical reaction. In order to calculate this quantity, the value for the actual yield and theoretical yield is needed. The actual yield is the amount of product obtained during a chemical reaction. The theoretical yield is the maximum amount of product possible to be obtain by a chemical reaction which is based on the amount of reactants used. Below is the formula needed to calculate the percentage yield.

Convert the number of grams of  to moles:

Based on the chemical equation 1 mole of  is produced for every 1 mole of  reacted.

Convert the moles of  to grams:

Example Question #4 : Reactions With Inorganic Compounds

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For the reaction given, identify the type of reaction taking place.

Possible Answers:

Displacement reaction

Synthesis reaction

Decomposition reaction

Combination reaction

Correct answer:

Displacement reaction

Explanation:

A displacement reaction is one in which an atom, ion or molecule moves from one compound to another to replace an atom, ion or molecule in another compound. In the reaction given, 2  ions move from 2 moles of  to  to form .

Example Question #2 : Equilibrium

The initial concentrations of this reaction are listed below.

Based on these initial concentrations, which statement is true? 

Possible Answers:

The forward rate will be greater than the reverse rate

The reaction is in equilibrium

The ratio of products to reactants is greater than the equilibrium constant

The reaction will shift left

Correct answer:

The forward rate will be greater than the reverse rate

Explanation:

When given initial concentrations, we can determine the reaction quotient (Q) of the reaction. The reaction quotient is given by the same equation as the equilibrium constant (concentration of products divided by concentration of reactants), but its value will fluctuate as the system reacts, whereas the equilibrium constant is based on equilibrium concentrations.

By comparing the reaction quotient to the equilibrium constant, we can determine in which direction the reaction will proceed initially. 

The reaction quotient with the beginning concentrations is written below.

This shows that the ratio of products to reactants is less than the equilibrium constant. Since Q is less than Keq in the beginning, we conclude that the reaction will proceed forward until Q is equal to Keq. In this manner, the denominator (reactants) will decrease and the numerator (products) will increase, causing Q to become closer to Keq.

Example Question #1 : Le Chatelier's Principle And Common Ion Effect

Consider the reaction reaction below.

A student allows the system to reach equilibrium and then removes two moles of hydrogen gas. Which of the following will be a result?

Possible Answers:

The amount of N2 in the reaction vessel will increase

The reaction will first shift toward the products, then toward the reactants

The reaction will shift to the side with fewer total moles of gas

No change will occur

More NH3 will be produced

Correct answer:

The amount of N2 in the reaction vessel will increase

Explanation:

According to Le Chatelier's principle, when a system at equilibrium is disturbed, the system will react to restore equilibrium. In other words, it will seek to undo the stress. Here, if hydrogen gas is removed, the reaction will shift toward the reactants to re-form it. In the process, more nitrogen will be produced.

Example Question #32 : Equilibrium

A saturated solution of scandium hydroxide, which also contains solid scandium hydroxide, is treated with 0.1N HCl. The addition of acid will __________ the solubility of scandium hydroxide because of __________.

Possible Answers:

decrease . . . the common ion effect

decrease . . . Le Chatelier's principle

increase . . . the decreased pH

not affect . . . the common ion effect

increase . . . Le Chatelier's principle

Correct answer:

increase . . . Le Chatelier's principle

Explanation:

Scandium hydroxide dissociates according to this reaction.

As 0.1N HCl is added, it will quantitatively react with hydroxide anions to produce ScCl3 and water.

Hydroxide will be removed from the above equilibrium, and the system will compensate by shifting the equilibrium to the right, according Le Chatelier's principle. As the equilibrium shifts to the right, more solid scandium hydroxide is hydrolyzed, resulting in increased solubility.

Example Question #33 : Equilibrium

A system contains iodine atoms that are in equilibrium with respect to the reaction below:

The volume of the system is suddenly reduced, leading to an increase in pressure. What effect will this have on the reaction?

Possible Answers:

The reaction shifts to the right then to the left

The reaction shifts to the right

The reaction shifts to the left

The reaction will not be affected

Correct answer:

The reaction shifts to the right

Explanation:

Since the system is originally at equilibrium and a stress is applied, Le Chatelier's principle is to be considered. By increasing the total pressure, the reaction will move in the direction toward which there are less molecules of gas.

Looking at the original reaction there are two moles of gas on the left and only one on the right, indicating that the reaction will shift to the right if the pressure is increased.

Example Question #1 : Reaction Equilibrium

Consider the following saturated solution. Assume it is at equilibrium.  

What is the chromate ion concentration after 0.019 moles of lead nitrate is added to 1 L of the above solution?

Possible Answers:

Correct answer:

Explanation:

Us the solubility constant to calculate the answer to this question. We know that:

and

Since  is a very small number, we can assume that the concentration of chromate, , will be very small compared to the concentration of the added lead, 0.019 M. We can use the two known values ( and lead concentration) to solve for the unknown chromate concentration:

Example Question #1 : Reaction Equilibrium

Which method can be used to increase the activation energy of a reaction done in the lab?

Possible Answers:

Increasing the temperature

Increasing the pressure

Increasing the concentration of reactants

Decreasing the temperature

Shaking the reaction flask

Correct answer:

Decreasing the temperature

Explanation:

The activation energy is the minimum amount of energy required to start a chemical reaction. Based on the collision model, increasing the temperature, pressure, and concentration for a chemical reaction will decrease the activation energy. This is because increasing these factors increases the number of collisions of molecules, which is required for a reaction to occur. Therefore, decreasing the temperature would have the opposite effect causing the activation energy to increase, decreasing the likelihood of a reaction taking place.

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