College Chemistry : Solutions, States of Matter, and Thermochemistry

Study concepts, example questions & explanations for College Chemistry

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Example Questions

Example Question #6 : Gas Laws

An ideal gas with a pressure of  is compressed to  of its original volume, what is the new pressure?

Possible Answers:

Correct answer:

Explanation:

An ideal gas with a pressure of  is is compressed to  of its original volume, what is the new pressure?

Use Boyle’s law:

 

You want to solve for the new pressure so isolate :

It compresses to  its original volume so, 

Plug in everything we know:

Cancel  from the numerator and denominator

Example Question #2 : Gas Laws

An ideal gas with a pressure of  is expanded to  times its original volume, what is the new pressure?

Possible Answers:

Correct answer:

Explanation:

Use Boyle’s law:

You want to solve for the new pressure so isolate :

It expands to  its original volume, so 

Plug in everything we know:

Cancel  from both the numerator and denominator

Example Question #51 : Solutions, States Of Matter, And Thermochemistry

A gas fills a  container, where heat is added raising its temperature from  to  and it increases its pressure from  to . What is the gas’ new volume?

Possible Answers:

Correct answer:

Explanation:

Use the combined gas law:

 

Solve for  since that is the new volume for which we need to solve:

Example Question #1 : Partial Pressure

 mixture of helium, nitrogen, and neon has a total pressure of  at a temperature of . If the partial pressure of helium is  and the partial pressure of nitrogen is , what mass of neon is present in the mixture?

Possible Answers:

Correct answer:

Explanation:

Since we have the total pressure and the pressures of helium and nitrogen, we can find the pressure of neon in this container.

Next, convert this pressure into atmospheres.

Now, recall the Ideal Gas Law:

Rearrange the equation to solve for moles of gas:

Using the pressure of neon, find the moles of neon that is present in the container.

Finally, convert the moles of neon into grams of neon using the molar mass.

Make sure your answer has  significant digits.

Example Question #1 : Partial Pressure

Suppose that hydrochloric acid and aluminum are reacted to produce hydrogen gas. This hydrogen gas is collected by displacement of water at  and a total pressure of . If the volume of the gas collected is , then how many moles of hydrogen were collected?

Note: The vapor pressure of water at  is .

Possible Answers:

Correct answer:

Explanation:

For this question, we're told that a chemical reaction is producing hydrogen gas. In doing so, the gas is displacing a certain amount of water vapor. We're asked to determine the number of moles of gas produced in this process.

The amount of water displaced by the production of hydrogen gas will be the amount (volume) of hydrogen gas produced. To measure its pressure, we take the reading of the total pressure and then subtract from it the pressure of water vapor (since it contributes to the total pressure). Using this information, we can use the ideal gas equation to determine the number of moles of hydrogen gas.

Next, we can use the ideal gas equation to solve for our answer.

Example Question #1 : Partial Pressure

A 4.0 L container at 25 C is filled with 2.0 g neon and 8.0 g helium. What is the total pressure of the mixture?

Possible Answers:

Correct answer:

Explanation:

To start, first recognize that this is an ideal gas law problem

Rearranging the equation to solve for P gives us

To solve the problem, we now need to find the total number of moles in the gaseous mixture ntot. To do this, convert the values for Ne and He to moles and add them together

Now that we have ntot, plug known values into the ideal gas law equation. Remember to convert from Celsius to Kelvin!

 

Example Question #1 : Partial Pressure

A 2.0 L container at 20 oC contains a gaseous mixture of  and He with a total pressure of 4 atm. The partial pressure exerted by He is 2.4 atm. How many moles of  are in the container?

Possible Answers:

Correct answer:

Explanation:

This is another ideal gas law problem, but this time dealing with partial pressures. Total pressure of a mixture is the sum of the partial pressures of each component. So first calculate the partial pressure exerted by 

Now that we have solved for the partial pressure of , we can solve for moles of  by using the ideal gas law equation

Rearrange to solve for moles of 

Example Question #1 : Effusion

Per Graham's law of effusion, how does the molar mass relate to both the rate and time of effusion? 

Possible Answers:

The molar mass relates inversely to the rate of effusion and directly to the time of effusion

None of these

The molar mass relates directly to both the rate and time of effusion

The molar mass relates inversely to both the rate and time of effusion

The molar mass relates directly to the rate of effusion and inversely to the time of effusion

Correct answer:

The molar mass relates inversely to the rate of effusion and directly to the time of effusion

Explanation:

This equation explicitly shows how the rate of effusion is inversely proportional to the molar mass of a gas in a gaseous solution. 

Because , time relates to molar mass by: 

Simplifying this equation, we see that: 

 

As a result, time relates directly to molar mass

Example Question #1 : Effusion

At the same temperature, an unknown gas effuses at a rate that is  times that of oxygen. Find the molar mass, in grams per mole, of the unknown gas.

Possible Answers:

Correct answer:

Explanation:

Recall Graham's Law of Effusion for two gases, A and B:

From the equation, we know the following:

Thus, we can solve for the molar mass of the unknown gas. Let  be the molar mass of the unknown gas.

Make sure that your answer has  significant figures.

Example Question #2 : Effusion

Which of the following is a true statement with regards to the relative effusion rates of oxygen and carbon dioxide?

Possible Answers:

Cannot be determined from the given information.

Oxygen will effuse  faster than carbon dioxide

Carbon dioxide will effuse  faster than oxygen

Carbon dioxide will effuse  faster than oxygen

Oxygen will effuse  faster than carbon dioxide

Correct answer:

Oxygen will effuse  faster than carbon dioxide

Explanation:

We're being asked to compare the effusion rates of oxygen and carbon dioxide.

Remember that effusion is the spontaneous movement of a gas through a small hole from one area to another. It's worth noting that at a given temperature, the average speed of all gas molecules in a system is used to calculate the average kinetic energy of the gas particles. This dependence of kinetic energy on temperature means that at a given temperature, any gas particle will have the same kinetic energy.

In this case, we can say that the kinetic energy of oxygen molecules in one system is equal to the kinetic energy of carbon dioxide molecules in another system. Furthermore, since mass is inversely proportional to velocity, identical kinetic energies would mean that as the mass of the gas particles in a system decreases, their velocity (and thus, effusion rates) would increase.

We can use this information to solve for the relative effusion rates between oxygen and carbon dioxide. By setting their kinetic energies equal to each other, we can derive an expression that relates their relative speeds to their relative masses.

Generally speaking, this expression shows how the velocity of any two gasses depends on their mass. In this case, the gasses are oxygen and carbon dioxide.

We can use the periodic table of the elements to find out the mass of each gas, and use that information to calculate the relative effusion rates.

This shows that oxygen will effuse at a rate that is about  faster than carbon dioxide.

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