The typical double replacement reaction is as follows:

The anions are the chemical species being exchanged (both sulfur and chloride). Hence, the name double replacement is given to this particular reaction.

Use the following steps to balance the equation:

1.) Check for diatomic molecules: in this case there are none so move on to step 2

2.) Balance the metals (hydrogen is not considered a metal in this application): There are 2 iron atoms on the left hand side and 1 iron atom on the right hand side so we add a 2 in front of the Fe on the right hand side to give:

3.) Balance the nonmetals (not including oxygen). There is one carbon on both sides so move on to step 4

4.) Balance oxygen. There are 3 oxygens on the left hand side and only 1 on the right hand side, so we can add a 3 in front of carbon monoxide on the right hand side to give:

5.) Balance hydrogen. No hydrogens, so we move on.

6.) Recount all atoms to make sure you have balanced correctly. There are 2 iron atoms on both sides and 3 oxygen on both sides.  However our carbons are no longer balanced so we can add a 3 in front of the elemental carbon on the left hand side to give:

If this problem had involved ionic species you would also want to make certain that the charges are balanced on both sides of the equation.

The charges on both sides add up to zero so your equation is balanced:

Single v.s Double Replacement Reaction:

Single replacement Reaction:

A single replacement reaction is defined as a type of reduction-oxidation reaction in which a more active element replaces a less active element in a compound. These reactions produce a new compound and an element as the products.  

General chemical equation:

Double Replacement Reaction:

A double replacement reaction is a type of reaction in which two reacting chemical species exchange bonds (ionic or covalent) resulting in the creation of two new products.  

General chemical equation:

 is also important in steel manufacturing and is a single replacement reaction. However, the equation given was so the difference being carbon monoxide production rather than carbon dioxide production. In reality both reactions occur simultaneously.

For double displacement, the solubility rules determine the phase labels. Make sure the correct set of rules/guidelines for the type of reaction that is being written/balanced are used. The octet rule refers to the stability atoms achieve by filling their outer shell of electrons. Huckel number is 4n+2 where n is any integer, and is involved in assigning aromaticity. 

When writing/balancing a single replacement reaction, make sure to consult the activity series, because that will tell us if a reaction will actually take place. Remember to look at the cations (metals and hydrogen) and where they are in relation to each other on the activity series. The higher one on the activity series is the most reactive; so if the cation by itself is the most reactive, it will replace the other cation and a reaction will occur. Boyle's law explains the inverse relationship between volume and pressure with respect to certain amount of an ideal gas at constant temperature.