All AP Chemistry Resources
Example Questions
Example Question #1 : Entropy
Which of the following does not represent an increase in entropy?
Melting of mercury
Boiling water
NaCl dissolving in water
Condensation of water on glass
Sublimation of CO2
Condensation of water on glass
Of phases, from greatest to least entropy is gas>liquid>solid. Dissolving a salt into solution is an increase in entropy because the salt has greater space to move. The only decrease in entropy is condensation of water on glass (gas to liquid)
Example Question #2 : Entropy
Which of the following reactions represents a negative change in entropy?
Water heating
Sublimation of dry ice
Ice melting
Salt dissolving
None of these represent a negative change in entropy
None of these represent a negative change in entropy
Entropy for phases are Gas>Liquid>Solid. A salt dissolving into solution has a positive entropy change (the solution becomes more chaotic). Therefore all of the listed reactions are a positive change in entropy, making E the correct answer.
Example Question #1 : Entropy
Which of the following scenarios describes a process with a negative entropy change?
A clean room becomes cluttered
Osmosis
Building a skyscraper
An igloo melting
Building a skyscraper
Entropy can be thought of as the tendency for a system to become disordered, or random. Osmosis, melting ice, and a clean room becoming dirty are all examples of entropy at work. Each of these processes will occur spontaneously without the input of outside energy or work.
If you make a skyscraper, you are incorporating a series of compounds and building products into a single, distinct formation. Think of it this way: what are the odds that mother nature would spontaneously build a building? This process is very ordered, which means that entropy of the universe has decreased.
Example Question #1 : Entropy
What is the change in entropy for the following reaction?
The change in entropy is calculated by:
When cannot be measured, it can be calculated from known entropies of formation.
It is important to first balance the reaction before performing calculations. The coefficients are important in determining the change in entropy of a reaction.
Example Question #71 : Thermochemistry And Kinetics
What is the change in entropy for the following reaction?
The change in entropy is calculated by:
When cannot be measured, it can be calculated from known entropies of formation.
It is important to first balance the reaction before performing calculations. The coefficients are important in determining the change in entropy of a reaction.
Example Question #6 : Entropy
What is the change in entropy for the following reaction?
The change in entropy is calculated by:
When cannot be measured, it can be calculated from known entropies of formation.
It is important to first balance the reaction before performing calculations. The coefficients are important in determining the change in entropy of a reaction.
Example Question #1 : Entropy
What is the change in entropy for the following reaction?
The change in entropy is calculated by:
When cannot be measured, it can be calculated from known entropies of formation.
It is important to first balance the reaction before performing calculations. The coefficients are important in determining the change in entropy of a reaction.
Example Question #1 : Entropy
What is the change in entropy for the following equation?
The change in entropy is calculated by:
When cannot be measured, it can be calculated from known entropies of formation.
It is important to first balance the reaction before performing calculations. The coefficients are important in determining the change in entropy of a reaction.
Example Question #1 : Entropy
What is the entropy for the following reaction?
The change in entropy is calculated by:
When cannot be measured, it can be calculated from known entropies of formation.
It is important to first balance the reaction before performing calculations. The coefficients are important in determining the change in entropy of a reaction.
Example Question #2 : Entropy
Which reaction will result in a negative entropy?
A reaction will have a positive change in entropy when the disorder of the system is increasing. This can happen when a liquid transitions to a gas, or more gas molecules are formed in the reaction.
Since two molecules of gaseous nitrogen dioxide can combine to form one molecule of dinitrogen tetroxide, the amount of gaseous molecules is halved. This increases order, which decreases the entropy of the system.