AP Chemistry : AP Chemistry

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #2 : Polarity And Dipole

Which of the following has the greatest dipole moment?

Possible Answers:

PCl4

H2O

HCN

SO2

Correct answer:

HCN

Explanation:

HCN has the largest difference in electronegativity, and the atoms are in a linear configuration. There is a strong dipole moment in the direction of nitrogen, without anything else canceling it out. Water has a dipole moment from each H, and the molecule is bent, so the dipoles partially cancel themselves out. SO2 also has a bent configuration, so its dipoles partially cancel each other out as well. PCl4 is tetrahedral, and all the dipoles cancel out.

Example Question #71 : Ap Chemistry

Why is oil not soluble in water?

Possible Answers:

Oil has stronger attraction between its molecules than water does

Water and oil are both nonpolar

Water is polar and oil is nonpolar

Oil has larger molecules than water

Correct answer:

Water is polar and oil is nonpolar

Explanation:

Water is a polar molecule and oil a nonpolar molecule. Polar and nonpolar molecules do not readily mix. Like tends to dissolve like; polar solutes will dissolve in polar solvents, while nonpolar solutes will dissolve in nonpolar solvents.

Water has stronger attraction between molecules, but this does not play a role in solubility.

Example Question #72 : Ap Chemistry

Which of the following molecules is the most polar?

Possible Answers:

CCl4

BF3

NH4

CH4

H2O

Correct answer:

H2O

Explanation:

To determine the overall polarity of a molecule it is important to note any differences in electronegativity that occur between the molecule's constituent atoms, but it is also important to consider the overall shape of the molecule. BF3 and CCl4 may seem like tempting answers because these atoms contain very electronegative elements.  However in both molecules the shapes, BF3 being trigonal planar and CCl4 being tetrahedral, cause each dipole within the polar bonds to cancel eachother out making these molecules overall non-polar.  The answer is then H2O because oxygen is bonded to two hydrogen molecules, and it also has two lone pairs casuing it to assume a bent conformation that is overall polar.  

 

Example Question #4 : Polarity And Dipole

Which of the following compounds will have the most ionic bond character?

Possible Answers:

Correct answer:

Explanation:

Ionic bonds arise from a large difference in electronegativities between two atoms. This is most common between metal and non-metal compounds, since these are generally located on opposite sides of the periodic table.

Of the given compounds, only two contain ionic bonds. , , and are composed solely of non-metal atoms. Even though nitrate and phosphate ions are charged, they are still composed only of covalent bonds.

and are both ionic compounds. Barium and lithium are metals with very low electronegativities, while fluorine and oxygen are non-metals with very high electronegativities. By looking at the periodic table, however, we can see that the distance between lithium and fluorine is greater than the distance between oxygen and barium. This tells us that there will be a greater difference in electronegativity between lithium and fluorine, meaning that lithium fluoride will have the most ionic character.

The electronegativity values support this conclusion, showing that lithium fluoride has the greater difference.

Example Question #2 : Polarity And Dipole

Which of the following substances would be least soluble in water?

Possible Answers:

Correct answer:

Explanation:

Water is a polar solvent, which makes it an excellent solvent for dissolving polar substances. Pentane  is a nonpolar molecule, which means it will be insoluble in water.

The other compounds will all dissolve according to the below reactions.

Example Question #6 : Polarity And Dipole

Which of the following is amphoteric? 

Possible Answers:

HF

H2O

NH3

CH2COOH

Correct answer:

H2O

Explanation:

Amphoteric compounds can act as both acids and bases. Water, H2O, is the most commonly cited amphoteric compound. It can act as an acid to give H+ molecules, or act as a base to give OH– molecules. 

Example Question #4 : Nomenclature And Functional Groups

What is the oxidation state of manganese () in the polyatomic permanganate anion ()?

Possible Answers:

Correct answer:

Explanation:

When assigning oxidation states to elements of a given compound, non-transition metal elements are assigned specific oxidation states corresponding to their group number and valence relative to a complete octet.

Group 1 elements have 1 valence electron and an oxidation state of +1.

Group 2 elements have 2 valence electrons and an oxidation state of +2. 

Group 8 elements (the noble gases) have a complete octet, thus their assigned oxidation state is 0.

Group 7 elements (halogens) have 7 valence electrons and an oxidation state of -1.

Group 6 elements such as oxygen have 6 valence electrons and an oxidation state of -2.

Permanganate has 4 oxygen atoms and an overall charge of -1. The oxidation state of the  atom may be found by first calculating the combined oxidation state of the oxygen atoms:

 

and finding the difference between their combined oxidation state and the overall charge of the ion (-1):

Example Question #5 : Nomenclature And Functional Groups

According to VSEPR theory, for the ammonium ion (), the electron-pair geometry is __________ and the molecular geometry is __________.

Possible Answers:

trigonal pyramidal . . . tetrahedral

trigonal pyramidal . . . trigonal pyramidal

tetrahedral . . . tetrahedral

tetrahedral . . . trigonal pyramidal

Correct answer:

tetrahedral . . . tetrahedral

Explanation:

Both the electron-pair and molecular geometries of ammonium are tetrahedral, as opposed to ammonia (), in which the electron-pair geometry is tetrahedral, but the molecular geometry is trigonal pyramidal. As evidenced below:

Ammonia:

Screen shot 2015 06 22 at 5.12.58 pm

Note that the difference in geometry arises in the presence of the lone pair on nitrogen in ammonia. The lone pair only contributes to molecular geometry, but does not contribute to electron-pair geometry. Bonding electrons, however, contribute to both electron and molecular geometries.

Ammonium:

Screen shot 2015 06 22 at 5.15.59 pm

In ammonium, the lone pair seen in ammonia is shared in a bond with an additional hydrogen atom. 

Example Question #41 : Molecules And Compounds

What are the mass percents of C, H, and O, respectively, in a molecule of glucose monomer ()?

Possible Answers:

Correct answer:

Explanation:

On average, the molar masses of carbon, hydrogen, and oxygen are approximately ,  , and , respectively.

The molar mass of a molecule of glucose is:

 

Each term added in the previous step is the mass of each element present in a mole of glucose, so the mass percent of its components are found by dividing their respective contributions to the molar mass by the molar mass:

Example Question #11 : Compounds

What is the name for the following polyatomic ion:  (also written )?

Possible Answers:

Acetate

Oxalate

Dichromate

Dicarbon trihydrogen dioxide

Carbon trihydrogen monocarbon dioxide

Correct answer:

Acetate

Explanation:

 (also written as ) is the formula for the acetate ion. Most polyatomic ions tend to follow certain naming trends, but acetate is one of the ions that does not follow those naming trends, so memorize this one since it shows up frequently in chemistry.

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