All AP Chemistry Resources
Example Questions
Example Question #81 : Ap Chemistry
Which of the following is the alcohol functional group?
-COOH
-COH
-NH2
-OH
-OR
-OH
The alcohol functional group is -OH
Example Question #82 : Ap Chemistry
What is the most acidic functional group on the amino acid cysteine? Cysteine has the chemical formula .
Thiol
Amine
Hydrochloric acid
Alcohol
Carboxylic acid
Carboxylic acid
We know that by definition, all amino acids contain a carboxylic acid functional group (), and an amino functional group (). Therefore the additional functional group can only contain sulfur and hydrogen.
The amino functional group is slightly basic, and the carboylic acid functional group is slightly acidic. The -SH functional group will also be acidic, but because sulfur and oxygen are in the same group on the periodic table, the -SH group will have similar acidic properties to an -OH group, and alcohols are less acidic than carboxylic acids.
Example Question #83 : Ap Chemistry
Which of the following functional groups is an amide?
Amides contain both oxygen and nitrogen in the functional group. The oxygen forms a double bond with a carbon, and the carbon bonds to a nitrogen. This forms the structure , where the nitrogen is also bound to the carbon.
is an alcohol functional group.
is an amine functional group.
is a carboxylic acid functional group.
is an aldehyde functional group.
Example Question #84 : Ap Chemistry
Which one of the following organic functional groups does not contain a carbon-oxygen double bond?
Aldehyde
Nitrile
Carboxylic acid
Ketone
Ester
Nitrile
A nitrile group contains a carbon-nitrogen triple bond, while all of the other groups contain a carbon-oxygen double bond.
Nitrile:
Ester:
Ketone:
Carboxylic acid:
Aldehyde:
Example Question #85 : Ap Chemistry
Which of the following is an organic compound?
Water
Magnesium fluoride
Sodium chloride
Oxygen
Glucose
Glucose
An organic compound is typically defined as one that contains carbon. Though there some small exceptions to this rule (for example, cyanide is not considered organic), in general most compounds follow it.
Though water, oxygen, and sodium chloride, may seem organic, they are not for they do not contain any covalent bonds to carbon. The only gievn compound that contains carbon is glucose, a sugar.
Example Question #4 : Organic Compounds
A chemist is trying to find the identity of a compound. She knows that the compound has a molecular weight of , and also that it consists of carbon, hydrogen, and oxygen by mass. What are the empirical and molecular formulas, respectively, for this compound?
It is impossible to tell without more information
The simplest way to begin these types of problems is to assume that we are starting out with 100 grams of the sample compound. This allows us to simplify things, since we know the mass percentages of the elements that make up out unknown compound.
Next, we must convert amount of each element from grams into moles.
This gives us a formula of
Now, we need to simplify this formula by dividing each of the terms by the greatest common denominator, 3.33, which gives us:
This is our empirical formula. To obtain the molecular formula, we must first find the mass of our empirical formula, which is .
Next, we need to divide the molecular weight of the compound by the empirical weight to obtain an integer of . Finally, we multiply the empirical formula by this integer in order to obtain the molecular formula, which is:
Example Question #86 : Ap Chemistry
How many lone pairs of electrons exist on the following molecule?
BF3
1
10
0
11
9
9
.. ..
:F — B — F: Boron can have a violated octet (6 e-) and each F has 3 lone pairs
.. | .. for a total of 9 pairs of unpaired electrons
:F:
..
Example Question #87 : Ap Chemistry
Which of the following compounds contains an atom that does NOT satisfy the octet rule?
I.
II.
III.
IV.
II and III
I, II, and IV
I and II
IV only
I and IV
I and IV
BCl3 only has six electrons around boron, while NO2 (with an odd number of electrons) would have only 7 electrons around the central nitrogen.
Example Question #88 : Ap Chemistry
Which of the following elements will have two unpaired valence electrons?
Carbon
Neon
Nitrogen
Beryllium
Fluorine
Carbon
Lewis dot diagrams can help us keep track on how the valence electrons will disperse themselves among orbitals in the atom. When drawing these diagrams, it is important to keep two things in mind.
1. The s orbital will be filled before the p orbital begins to be filled.
2. Electrons will never pair in the same orbital if an orbital of equal energy is unoccupied.
Knowing these two facts, we can predict which of the following elements will have two unpaired electrons.
Fluorine will have seven valence electrons, meaning that only one orbital will not be completely filled.
Beryllium only has two valence electrons, but they will both be found in the 2s orbital, because it must be filled before the p orbitals can receive electrons.
Nitrogen will have five valence electrons, so two will be found in the 2s orbital. The other three will be present in their own p orbitals, meaning nitrogen has three unpaired electrons.
Neon will have eight valence electrons, fully filling the 2s and 2p orbitals. It will have no unpaires electrons.
Carbon has one less valence electron than nitrogen, meaning that it will have two unpaired electrons in the p orbitals.
Example Question #1 : Lewis Diagrams
Which of the following is isoelectric with the cation ?
Isoelectronic means having the same electron configuration (i.e. the same number of electrons). and both have the same number of electrons (18), while sulfur has 16, phosphorous has 15, neon has 10, and the sodium cation has 10.
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