MCAT Physical : Physical Chemistry

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #1 : Phase Changes

The strain on an object __________ when initial length is increased and __________ when final length is increased.

Possible Answers:

increases . . . decreases

decreases . . . increases

decreases . . . decreases

increases . . . increases

Correct answer:

decreases . . . increases

Explanation:

Strain of an object is defined as:

     

 is the final length and  is the initial length. The equation implies that increasing the initial length of an object () would decrease the strain. Similarly, the equation also implies that increasing the final length of an object () would increase the strain; therefore, increasing the initial length decreases strain, whereas increasing the final length increases strain.

Example Question #7 : Phase Changes

Which of the following will result in the greatest increase in length of a rubber band at its maximum stretch point, as compared to an unaltered control?

Assume the rubber band will experience the same constant force.

Possible Answers:

Using a rubber band that is twice as long and is twice as elastic

Using a rubber band that has half the length

Using a rubber band that has twice the cross-sectional area

Using a rubber band that is twice as elastic

Correct answer:

Using a rubber band that is twice as elastic

Explanation:

To answer this question, we need to know the equation for Young’s modulus, :

     

Recall the definitions of stress and strain:

     

Here,  is force,  is cross-sectional area,  is change in length, and  is initial length. Plugging these two equations into the definition of Young’s modulus gives us:

     

Rearranging this equation to solve for change in length gives us:

    

Since we want to increase  we look for answer choices that increase  and , or decrease  and . Among the answer choices, the greatest increase occurs when you double the elasticity of the rubber band. Recall that Young’s modulus is a measure of the stiffness of a material; therefore, a more elastic (flexible, or less stiff) material will lower Young’s modulus. Having a material twice as elastic will decrease  by one half and will give the greatest increase in the change in length of the rubber band. 

Using half the length () and using twice the cross-sectional area will decrease the change in length. Using a rubber band twice as long, but twice as elastic, will not alter the change in length.

Example Question #8 : Phase Changes

Which of the following is false regarding Young’s modulus?

Possible Answers:

Young’s modulus is defined as the slope of the stress vs. strain plot

Young’s modulus has the same units as stress

Young’s modulus is only valid for certain stresses

Young’s modulus increases as stress increases

Correct answer:

Young’s modulus increases as stress increases

Explanation:

Young’s modulus is a constant that is calculated by generating a stress vs. strain plot. The slope of the linear region of the stress vs. strain plot is defined as the Young’s modulus. Recall that the stress vs. strain plot is nonlinear past the elastic limit (stress at which the material starts to plastically deform). This means that we cannot calculate the slope past the elastic limit; Young’s modulus is invalid for stresses beyond the elastic limit.

Young’s modulus is defined as follows:

     

To calculate strain, you divide change in length by initial length. Since both change in length and initial length have the same units, the units cancel and strain becomes a dimensionless quantity. This means that the Young’s modulus will have the same units as stress alone. 

Young’s modulus is a material property. This means that the Young’s modulus is constant for a given type of material. It does not depend on the stress experienced by the material. Any changes to stress will be compensated for by a change in strain, which will allow Young’s modulus to be constant for the material. Similarly, Young’s modulus does not depend on strain or on the geometrical properties (length and area) of the material. It will only change if you change the type of material being used.

Example Question #1 : Thermochemistry And Energetics

Adenosine-triphosphate is formed by the following endothermic reaction.


If body temperature decreases, ADP production __________.

Possible Answers:

is unpredictable

 

increases

decreases

remains constant

Correct answer:

increases

Explanation:

Since heat can be considered a reactant (endothermic), if heat is decreased, ADP is increased according to Le Chatelier’s Principle. If a reactant is removed, the equilibrium will shift toward the reactants. In this reaction, ADP and heat are both reactants.

Example Question #1 : Energetics Of Biological Reactions And Atp

Which of the following is true, assuming the reaction goes to completion?

I. There is an increase in , entropy

II. 

III. At equilibrium, 

IV. Oxygen is the reducing agent

Possible Answers:

II and III

I and IV

I, II, and III

I and III

II only

Correct answer:

I, II, and III

Explanation:

This question ties together the reaction for oxidation of glucose with several thermodynamic principles.

The first option, stating that there is an increase of entropy, is true. When balanced, we see that there is an increase in total number of molecules when the reaction completes; thus, there will be an increase in entropy.

The second option states that enthalpy, or , is less than than zero. This is also true, as it implies that this is an exothermic (or heat generating) reaction. The oxidation of glucose is how our bodies generate heat and keep homeostasis.

The third option, stating that Gibb's free energy is zero at equilibrium, is also true. Any equation will have  at equilibrium.

The last option, stating that oxygen is the reducing agent, is false. Oxygen is actually the oxidizing agent and is itself reduced.

Example Question #3 : Energetics Of Biological Reactions And Atp

ATP stores energy through its ability to lose a phosphate group to form ADP in the following reaction



At body temperature, the thermodynamic values for ATP hydrolysis are as follow.




Glycolysis is an energy-liberating process (, ) that is coupled with the conversion of two ADP molecules into two ATP molecules according to the following reaction.

Glycolysis results in which of the following?

Possible Answers:

A decrease in entropy

An increase in entropy

A conservation of entropy

An increase in enthalpy

Correct answer:

An increase in entropy

Explanation:

Since glycolysis is an exothermic reaction (ΔH is negative), enthalpy does not increase. As for entropy, the reaction begins with a large molecule and ends with smaller molecules, therefore entropy increases.

Example Question #4 : Energetics Of Biological Reactions And Atp

ATP stores energy through its ability to lose a phosphate group to form ADP in the following reaction



At body temperature, the thermodynamic values for ATP hydrolysis are as follow.
ΔG = –30kJ/mol
ΔH = –20kJ/mol
ΔS = 34kJ/mol

Glycolysis is an energy-liberating process (ΔG = –218kJ/mol, ΔH = –20 kJ/mol) that is coupled with the conversion of two ADP molecules into two ATP molecules according to the following reaction.

Glycolysis is __________.

Possible Answers:

exergonic and exothermic

exergonic and endothermic

endergonic and endothermic

endergonic and exothermic

Correct answer:

exergonic and exothermic

Explanation:

ΔG and ΔH are both negative for glycolysis, meaning that the reaction is exergonic and exothermic.

Example Question #5 : Energetics Of Biological Reactions And Atp

ATP stores energy through its ability to lose a phosphate group to form ADP in the following reaction



At body temperature, the thermodynamic values for ATP hydrolysis are as follow.
ΔG = –30kJ/mol
ΔH = –20kJ/mol
ΔS = 34kJ/mol

Glycolysis is an energy-liberating process (ΔG = –218kJ/mol, ΔH = –20 kJ/mol) that is coupled with the conversion of two ADP molecules into two ATP molecules according to the following reaction.

The formation of peptide bonds requires 17kJ/mol of energy. It also requires the energy of three ATP molecules. How many ATP molecules are required to synthesize a protein containing 550 peptide bonds?

Possible Answers:

312

1,962

1,650

550

Correct answer:

1,962

Explanation:

Since we know that three ATP molecules per bond are required, 1,650 ATP molecules are needed. However, we also know that 17kJ/mol of additional energy is required for each bond. This energy must come from ATP molecules. The only choice that is greater than 1,650 is 1,962.

Example Question #6 : Energetics Of Biological Reactions And Atp

ATP stores energy through its ability to lose a phosphate group to form ADP in the following reaction



At body temperature, the thermodynamic values for ATP hydrolysis are as follow.
ΔG = –30kJ/mol
ΔH = –20kJ/mol
ΔS = 34kJ/mol

Glycolysis is an energy-liberating process (ΔG = –218kJ/mol, ΔH = –20 kJ/mol) that is coupled with the conversion of two ADP molecules into two ATP molecules according to the following reaction.

How much heat, in joules, is released when 4 * 1019 molecules of ATP are converted to ADP via ATP hydrolysis? 

Possible Answers:

45J

1.3 * 10-3J

1.3J

13,000J

Correct answer:

1.3J

Explanation:

To solve this problem, first convert molecules to moles with Avogadro’s number, then convert moles to kJ using the ΔH of ATP hydrolysis. Lastly convert kJ to J.

Example Question #1 : Gibbs Free Energy

A scientist prepares an experiment to demonstrate the second law of thermodynamics for a chemistry class. In order to conduct the experiment, the scientist brings the class outside in January and gathers a cup of water and a portable stove.

The temperature outside is –10 degrees Celsius. The scientist asks the students to consider the following when answering his questions:

Gibbs Free Energy Formula:

ΔG = ΔH – TΔS 

 

Liquid-Solid Water Phase Change Reaction:

H2O(l) ⇌ H2O(s) + X

The scientist prepares two scenarios. 

Scenario 1:

The scientist buries the cup of water outside in the snow, returns to the classroom with his class for one hour, and the class then checks on the cup. They find that the water has frozen in the cup.

Scenario 2: 

The scientist then places the frozen cup of water on the stove and starts the gas. The class finds that the water melts quickly.

After the water melts, the scientist asks the students to consider two hypothetical scenarios as a thought experiment. 

Scenario 3:

Once the liquid water at the end of scenario 2 melts completely, the scientist turns off the gas and monitors what happens to the water. Despite being in the cold air, the water never freezes.

Scenario 4:

The scientist takes the frozen water from the end of scenario 1, puts it on the active stove, and the water remains frozen.

In scenario 1, the reaction of water freezing has which of the following quantities for the Gibbs Free Energy Formula?

Possible Answers:

Enthalpy: Negative; Entropy: Positive

Enthalpy: Positive; Entropy: Negative

Enthalpy: Positive; Entropy:  Positive

Enthalpy: Negative; Entropy: Zero

Enthalpy: Negative; Entropy: Negative

Correct answer:

Enthalpy: Negative; Entropy: Negative

Explanation:

As water freezes, heat is released. The H value in the equation must therefore be negative.  Also as water freezes, there is a local decline in the amount of disorder. The S, or entropy, term in the Gibbs equation refers to entropy of the system. Thus, this term must be negative as well.

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