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GRE Subject Test: Chemistry : Analytical Chemistry

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Example Questions

Example Question #1 : Limiting Reagent

Given the unbalanced equation below, how many grams of carbon dioxide will be produced from one mole of glucose and three moles of oxygen?

$C_6H_{12}O_6+O_2\rightarrow CO_2+H_2O$

Possible Answers:

148g

132g

72g

4.98g

224g

Correct answer:

132g

Explanation:

The first step to solve will be to balance the chemical reaction:

$C_6H_{12}O_6+6O_2\rightarrow 6CO_2+6H_2O$

We see that we see that for every one mole of glucose used, six moles of carbon dioxide will be made. Similarly, for every six moles of oxygen used, six moles of carbon dioxide will be formed. For the reaction to carry out to completion, however, there must exist six moles of oxygen for every one mole of glucose. In the problem's circumstances, one of these compounds becomes the limiting reactant, in this case it is oxygen.

$1mol\ C_6H_{12}O_6*\frac{6mol\ O_2}{1mol\ C_6H_{12}O_6}=6mol\ O_2$

We only have three moles of oxygen, but we would need six to react all the given glucose, making oxygen the limiting reagent. We need to find the carbon dioxide produced from the limited amount of oxygen present. Use the molar ratio between oxygen and carbon dioxide and the molar mass of carbon dioxide to solve.

$3mol\ O_2*\frac{6mol\ CO_2}{6mol\ O_2}*\frac{44g\ CO_2}{1mol\ CO_2}=132g\ CO_2$

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Example Question #1 : Gravimetric Analysis

Household vinegar contains the organic compound acetic acid with chemical formula, $CH_{3}COOH$ . If a 10.00 g vinegar sample contains $0.1024\ moles$ of acetic acid, calculate the percent (mass/mass) of the $CH_{3}COOH$ in the vinegar sample.

Density of vinegar is the following:

$CH_{3}COOH=1.05\frac{g}{mL}$

Possible Answers:

$3.3\%$

$75\%$

$61.5\%$

$12.8\%$

Correct answer:

$61.5\%$

Explanation:

Convert the moles of $CH_{3}COOH$ to grams:

$0.1024\ moles \times \frac{60.05g}{mole}=6.1491g\ CH_{3}COOH$

To calculate the percentage of $CH_{3}COOH$ in the vinegar we need to use the following formula:

$\%CH_{3}COOH=\frac{grams\ of\ CH_{3}COOH}{grams\ of\ vinegar}$

Therefore,

$\frac{6.15g}{10.00g}\times 100=61.5\%\ CH_{3}COOH$

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Example Question #1 : Analyzing Solids

Consider the following balanced equation for the solubility of barium hydroxide in an aqueous solution.

$\small Ba(OH)_{2}_{(s)} \rightleftharpoons Ba^{2+}_{(aq)} + 2OH^{-}_{(aq)}$

$\small K_{sp} = 5*10^{-3}$

What is the solubility of barium hydroxide?

Possible Answers:

$\small 0.05M$

$\small 0.035M$

$\small 0.108M$

$\small 0.071M$

Correct answer:

$\small 0.108M$

Explanation:

In order to solve for the solubility of barium hydroxide, we need to establish an ICE table for the reaction.

I. Initially, there are no barium ions or hydroxide ions in the solution, so we can call their concentrations zero at the beginning of the reaction.

C. For every molecule of dissolved barium hydroxide, there will be one ion of barium and two ions of hydroxide. As a result, the increases in each ion can be designated $\small +x$ and $\small +2x$ , respectively.

E. Finally, we plug these values into the equilibrium expression and set it equal to the solubility product constant.

$\begin{matrix} Ba(OH)_2 & Ba^{2+} &OH^- \\ /& 0 & 0\\ / & x & 2x \end{matrix}$

$K_{sp}=[Ba^{2+}][OH^-]^2$

$\small 5*10^{-3} = [x][2x]^{2}$

$\small x = 0.108M$

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Example Question #1 : Solubility And Precipitation

Write the solubility product, $K_{sp}$ , for $BaSO_4_{(s)}$ .

Possible Answers:

$K_{sp} = [Ba][SO_{4}]^{2-}$

$K_{sp} = [Ba]^{2+}[SO_{4}]^{2-}$

$K_{sp} = [Ba^{2+}][SO_{4^}^{}^{2-}]$

$K_{sp} = [Ba][SO_{4}]$

$K_{sp} = [Ba]^{4+}[SO_{4}]^{2-}$

Correct answer:

$K_{sp} = [Ba^{2+}][SO_{4^}^{}^{2-}]$

Explanation:

The solubility product constant ( $K_{sp}$ ) is an expression that describes the extent to which a compound is soluble in an aqueous solution. It describes the equilibrium between a solid and its constituent ions in a solution. The equilibrium constant for $BaSO_4_{(s)}$ can be written as:

$K_{eq} = \frac{[Ba^{2+}][SO_{4^}^{}^{2-}]}{[BaSO_{4}(s)]}$

The denominator represents solid barium sulfate which is considered a constant. When the equation is rearranged, it becomes:

$K_{eq}*[BaSO_{4}]=[Ba^{2+}][SO_{4^}^{}^{2-}]$

The product, $K_{eq}*[BaSO_{4}]$ , can be considered a constant expression called the solubility product constant ( $K_{sp}$ ) and the equation can be written in the form:

$K_{sp} = [Ba^{2+}][SO_{4^}^{}^{2-}]$

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Example Question #1 : Solubility And Precipitation

Write the solubility product, $K_{sp}$ , for $AgCN_{(s)}$ .

Possible Answers:

$K_{sp} = [Ag][CN]$

$K_{sp} = [Ag]^{+}[CN]^{-}$

$K_{sp} = [Ag^{2+}][CN^{2-}]$

$K_{sp} = [Ag][CN^{-}]$

$K_{sp} = [Ag^{+}][CN^{-}]$

Correct answer:

$K_{sp} = [Ag^{+}][CN^{-}]$

Explanation:

$K_{eq} = \frac{[Ag^{+}][CN^{-}]}{[AgCN(s)]}$

The denominator represents solid barium sulfate which is considered a constant. When the equation is rearranged, it becomes:

$K_{eq}*[AgCN(s)]=[Ag^{+}][CN^{-}]$

The product, $K_{eq}*[AgCN]$ , can be considered a constant expression called the solubility product constant ( $K_{sp}$ ) and the equation can be written in the form:

$K_{sp} = [Ag^{+}][CN^{-}]$

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Example Question #2 : Solubility And Precipitation

Write the $K_{sp}$ expression for the following equilibria:

$Mg(OH)_{2(s)} \leftrightarrow Mg^{2+(aq)} + 2 OH^{-}_{(aq)}$

Possible Answers:

$K_{sp} = [Mg^{+}]2[OH^{-}]$

$Ksp = [Mg^{2+}][OH^{-}]^{2}$

$K_{sp} = [Mg]^{+}[OH]^{-}$

$K_{sp} = [Mg^{+}][OH^{-}]$

None of these

Correct answer:

$Ksp = [Mg^{2+}][OH^{-}]^{2}$

Explanation:

The solubility product constant ( $K_{sp}$ ) is an expression that describes the extent to which a compound is soluble in an aqueous solution. It describes the equilibrium between a solid and its constituent ions in a solution.The equilibrium between undissolved $Mg(OH)_{2(s)}$ and its ions dissolved in solution is:

$Mg(OH)_{2(s)} \leftrightarrow Mg^{2+(aq)} + 2 OH^{-}_{(aq)}$

The equilibrium constant for $Mg(OH)_{2(s)}$ can be written as:

$K_{eq} = \frac{[Mg^{2+}][OH^{-}]^{2}}{[Mg(OH)_{2}(s)]}$

The denominator represents solid barium sulfate which is considered a constant. When the equation is rearranged, it becomes:

$K_{eq}[Mg(OH)_{2}](s)=[Mg^{2+}][OH^{-}]^{2}$

The product, $K_{eq}[Mg(OH)_{2}]$ , can be considered a constant expression called the solubility product constant ( $K_{sp}$ ) and the equation can be written in the form:

$K_{sp} = [Mg^{2+}][OH^{-}]^{2}$

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Example Question #45 : Analytical Chemistry

Considering that $K_{sp} = 1.8 * 10^{-11}$ for the equilibrium reaction:

$Mg(OH)_{2(s)} \leftrightarrow Mg^{2+(aq)} + 2 OH^{-}_{(aq)}$

What would be the $Mg^{2+}$ concentration for a solution buffered at a pH of 8.5?

Possible Answers:

16 M

11 M

5 M

1.8 M

Correct answer:

1.8 M

Explanation:

The pH of the solution is 8.5 , therefore the pOH would be 5.5 considering the relationship:

14 = pH + pOH

Therefore $[OH]=3.2x10^{-6}$ based on the equation $[OH] = 10^{-pOH}$

The solubility product expression for $Mg(OH)_{2(s)}$ is : $K_{sp} = [Mg^{2+}][OH^{-}]^{2}$

By inserting the knowns in to the expression, gives:

$1.8 * 10^{-11} = [Mg^{2+}][3.2 * 10^{-6}]^{2}$

Rearrange this equation

$[Mg^{2+}] = \frac{1.8 * 10^{-11}}{(3.2 * 10^{-6})^{2}} = 1.8M$

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Example Question #43 : Analytical Chemistry

The K_sp of BaSO_4 is $5.0*10^{-9}$ . What is the molar solubility of BaSO_4 in water?

Possible Answers:

$5.3*10^{-8}$

$2.3*10^{-3}$

$3*10^{-3}$

$7.1*10^{-5}$

$8.5*10^{-6}$

Correct answer:

$7.1*10^{-5}$

Explanation:

The equation for the dissolution of BaSO_4 in water is below:

$BaSO_{4}(s)\rightleftharpoons Ba^{2+}(aq)\ +\ SO_{4}^{2-}(aq)$

The K_spfor the above equation is:

$Ksp=[Ba^{2+}][SO_{4}^{2-}]=5.0*10^{-9}$

Due to the solubility of BaSO_4 of in water, the concentration of $Ba^{2+}$ and $SO_4^{2-}$ ^- should be equal:

$[Ba^{2+}]\ =\ [SO_{4}^{2-}]=X$

Plug into the K_sp equation:

$Ksp=X*X=X^{2}=5.0*10^{-9}$

Therefore:

$X=\sqrt{5.0\ *10^{-9}}=7.1*10^{-5}$

The solubility of BaSO_4 in water is $7.1*10^{-5}$

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Example Question #44 : Analytical Chemistry

The K_sp of CuBr is $5.3*10^{-9}$ . What is the molar solubility of CuBr inwater?

Possible Answers:

$3.4*10^{-5}$

$5.6*10^{-9}$

$2.2*10^{-3}$

$7.3*10^{-5}$

$7.7*10^{-3}$

Correct answer:

$7.3*10^{-5}$

Explanation:

The equation for the dissolution of CuBr in water is below:

$CuBr(s)\rightleftharpoons Cu^{+}(aq)\ +\ Br^{-}(aq)$

The K_sp for the above equation is:

$Ksp=[Cu^{+}][Br^{-}]=5.3*10^{-9}$

Due to the solubility of CuBr of in water, the concentration of Cu^+ and Br^- should be equal:

$[Cu^{+}]\ =\ [Br^{-}]=X$

Plugging X into the K_sp equation gives:

$Ksp=X*X=X^{2}=5.3*10^{-9}$

Therefore:

$X=\sqrt{5.3\ *10^{-9}}=7.3*10^{-5}$

The solubility of CuBr in water is $7.3*10^{-5}$

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Example Question #2 : Solubility And Precipitation

Which salt is insoluble in water?

Possible Answers:

$CuSO_{4}$

$Al(OH)_{3}$

AgCl

$NaNO_{3}$

$CuCl_{2}$

Correct answer:

AgCl

Explanation:

Solubility rules must be followed for substances in aqueous media. Below are some of the solubility rules and they must be followed in the order given. For example, rule 1 should have precedence over rule 2.

1. All alkali metal $(Li, Na, K, Rb, \text{and}\ Cs)$ and NH_4^+ compounds are soluble.

2. Nitrate (NO_3^-) , perchlorate (ClO_4^-) , chlorate, (ClO_3^3) , and acetate (CH_3COO^-) salts are soluble.

3. Silver, lead, and mercury salts are insoluble.

Thus, we see that silver chloride is insoluble due to rule 3.

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GRE Subject Test: Chemistry : Analytical Chemistry

Study concepts, example questions & explanations for GRE Subject Test: Chemistry

All GRE Subject Test: Chemistry Resources

Example Questions

Example Question #1 : Limiting Reagent

Example Question #1 : Gravimetric Analysis

Example Question #1 : Analyzing Solids

Example Question #1 : Solubility And Precipitation

Example Question #1 : Solubility And Precipitation

Example Question #2 : Solubility And Precipitation

Example Question #45 : Analytical Chemistry

Example Question #43 : Analytical Chemistry

Example Question #44 : Analytical Chemistry

Example Question #2 : Solubility And Precipitation

All GRE Subject Test: Chemistry Resources

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