College Chemistry : Reactions

Study concepts, example questions & explanations for College Chemistry

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Example Questions

Example Question #2 : Stoichiometric Calculations And Dimensional Analysis

Use the equation shown to determine how many grams of water form when  of  reacts completely with  at .

Possible Answers:

 of water

 of water

 of water

 of water

Correct answer:

 of water

Explanation:

Use the relations , molar mass , and

Example Question #1 : Empirical And Molecular Formulas

What is the correct molecular formula for phosphoric acid?

Possible Answers:

Correct answer:

Explanation:

Phosphoric acid combines a single phosphate ion with three hydrogen ions. The correct molecular formula is . is the molecular formula for hydrophosphoric acid, is the molecular formula for phosphorous acid, and is just a charged phosphate ion, which has biochemical significance with regards to DNA structure and energy molecules like ATP. Phosphorus is not a diatomic atom.

Example Question #31 : Reactions

A molecule with the empirical formula  has a molar mass of . Find its molecular formula.

Possible Answers:

Correct answer:

Explanation:

Start by finding the molar mass of of  by adding up the molar masses of its constituent atoms.

Now, divide the molar mass of the molecule by the molar mass of its empirical formula.

In order to find the molecular formula, you will need to multiply the empirical formula by . Thus, the molecular formula is .

Example Question #1 : Empirical And Molecular Formulas

What is the empirical formula for a compound that contains  carbon and  hydrogen?

Possible Answers:

Correct answer:

Explanation:

We're given the percent composition of the elements carbon and hydrogen in a given compound, and we're asked to determine the empirical formula.

The first thing we have to do is determine the relative molar ratios of each element. In this case, because we are given the percent composition, we can assume that we're starting off with  of the starting material. That way, we can convert each percentage directly into grams.

Following that, we need to use the molar mass of each element in order to convert it from grams to moles.

In other words, what we have found is that in our compound, for every  of carbon, there will also be  of hydrogen.

But remember, the empirical formula for any given compound tells us the lowest whole number ratio of the compound's constituent elements. Therefore, we'll need to divide each value by the lowest number out of all the values available.

What this tells us is that for every  of carbon in this compound, there will be  of hydrogen as well. This is equivalent to the previous ratio, but now it has been reduced to the lowest possible whole numbers.

Example Question #1 : Chemical Equilibrium, Equilibrium Constant, And Reaction Quotient

Consider the following reaction:

Give the expression for the equilibrium constant for this reaction.

Possible Answers:

Correct answer:

Explanation:

Recall how to find the expression of the equilibrium constant for the simplified equation:

Since the given equation has gases, we will only consider the partial pressures of each gas in the expression for the equilibrium constant. Remember that only molecules in aqueous and gas forms are included in this expression. Pure solids and pure liquids are excluded.

Thus, we can then write the following equilibrium constant for the given equation:

Example Question #34 : Reactions

Consider the following reaction:

The reaction mixture at  initially contains  and . At equilibrium, . What is the equilibrium constant for the reaction?

Possible Answers:

Correct answer:

Explanation:

Start by writing the equilibrium expression:

Now, create a chart like the following to keep track of the changes in concentration.

 
Initial 0.750 2.00 0.00
Change -0.100 -0.025 0.200
Equilibrium 0.650 19.75 0.200

Since we know that the concentration of HCl decreased by , we can use the stoichiometric ratios to deduce the amount of change for the oxygen gas and the chlorine gas.

Plug in the equilibrium concentrations into the expression for the equilibrium constant.

Example Question #1 : Chemical Equilibrium, Equilibrium Constant, And Reaction Quotient

Calculate the equilibrium constant at  for the reaction by using free energies of formation.

Possible Answers:

Correct answer:

Explanation:

Start by using the free energies of formation to find .

 

Recall the equation that links together  with the equilibrium constant, .

Plug in the given information and solve for .

Example Question #1 : Equilibrium

Consider a reaction mixture using the equation shown. At equilibrium the partial pressure of  is  and the partial pressure of  is . What is the partial pressure of  in this mixture if  at ?

Possible Answers:

 or

 or  

 or  

 or

Correct answer:

 or

Explanation:

Use algebra to solve for the partial pressure of .

 

Example Question #2 : Equilibrium

Considering the reaction shown, if the partial pressures of , and  are  each, is the mixture at equilibrium? If not which direction will the reaction proceed to reach equilibrium if ?

Possible Answers:

No, the reaction will proceed left towards the reactants. 

Yes, the reaction will move towards the products.

No, reaction will proceed right towards the products.

Yes

Correct answer:

No, reaction will proceed right towards the products.

Explanation:

Since  the reaction is not at equilibrium. This means that at equilibrium, the ratio of products to reactants is greater than at the given conditions. Thus, the reaction will move right towards the products to reach equilibrium.

Example Question #3 : Chemical Equilibrium, Equilibrium Constant, And Reaction Quotient

In the laboratory  of  and  of  are reacted in a  beaker. At equilibrium  of  remain. Using the equation shown calculate the equilibrium constant.

Possible Answers:

Correct answer:

Explanation:

Use an ice table and the  equation to solve.                      

                                                                

Initial                                                       

Change                               

Equilibrium                                        

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