College Chemistry : Rate Laws

Study concepts, example questions & explanations for College Chemistry

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Example Questions

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Example Question #22 : Thermodynamics And Kinetics

What are the units for the rate constant  of a third order reaction?

Possible Answers:

Correct answer:

Explanation:

Because the rate of a chemical reaction is always in . The  value must always cancel with other units to produce these units. In a third order reaction the rate equation is 

If we replace the variables above with their units, the equation will look like this:

Therefore, in order to match,  must be have the units .

Example Question #11 : Rate Laws

If the reaction:

Follows the mechanism:

 (Slow)

 (Fast)

What is the rate order with respect to ?

Possible Answers:

Correct answer:

Explanation:

Because B is in the rate determining step (the slow step) then we know that it is not zero order with respect to the concentration of B.

However, because there is only one molecule of B reacting in the rate determining step, we know that this reaction is first order with respect to the concentration of B.

Example Question #11 : Kinetics

If the reaction:

Follows the mechanism:

 (Slow)

 (Fast)

What is the rate order with respect to ?

Possible Answers:

Correct answer:

Explanation:

The rate law is determined by the slowest step in a reaction mechanism. Because B is not a reactant in the slow step, then it will not appear in the reaction mechanism.

Therefore, the reaction is zeroth order in relation to the concentration of B.

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