AP Chemistry : Limiting Reagent

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

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Example Question #21 : Stoichiometry

How is a limiting reagent problem recognized?

Possible Answers:

The amount of product is always given

One of the reactants is always present in excess

The initial quantities of at least two reactants are given

The initial quantities of one reactant and one product are given

The initial quantities of at least two reactants are given

Correct answer:

The initial quantities of at least two reactants are given

Explanation:

When two or more reactants of a chemical equation's quantities are given, the first step is to determine the limiting reagent of the reaction. The reaction will only proceed and produce as much product as the limiting reagent allows. For example if there are 5 moles of oxygen gas and excess hydrogen gas, only 10 moles of water can be produced regardless of how much hydrogen gas is present. 

Example Question #11 : Limiting Reagent

The following reaction is used to obtain small amounts of chlorine gas in the laboratory:

If  of  are allowed to react with  of , the limiting reactant will be:

 

Possible Answers:

There is no limiting reactant

Correct answer:

Explanation:

First of all, a product cannot be the limiting reactant. This problem can be solved in many different ways. Keep in mind that to solve a stoichiometry problem a good practice is to convert mass to mol. Let's find if the amount of  we have is enough to react with  of :

We have only  of   and  are needed. Then  is the limiting reactant.

Example Question #13 : Limiting Reagent

When grilling out, many people utilize the combustion of propane to provide the heat energy needed to cook their food.  The chemical equation for this reaction is shown below:

 

You notice that your gas grill is producing a large amount of soot, which is negatively impacting the taste of your food. Please select the best explanation of this phenomenon, and it's corresponding solution.

Possible Answers:

The limiting reactant is oxygen; therefore the best way to reduce the soot is to add an oxygen source such as , which releases oxygen by thermal decomposition.

Oxygen is in excess; therefore the best way to reduce the soot is to close the grill hood and close any vent holes preventing atmospheric oxygen from entering the system.

The soot production is due to a dirty grill and therefore your grill must be thoroughly cleaned.

The limiting reactant is propane; therefore the best way to reduce the soot is to increase the input of propane.

The limiting reactant is oxygen; therefore the best way to reduce the soot is to decrease the input of propane, which is in excess.

Correct answer:

The limiting reactant is oxygen; therefore the best way to reduce the soot is to decrease the input of propane, which is in excess.

Explanation:

Soot is a mixture incompletely combusted hydrocarbons. Therefore the production of soot occurs most when the hydrocarbon is in excess and the oxidizer (in this case oxygen) is the limiting reactant.

Incorrect answers and explanations:

The limiting reactant is propane, therefore the best way to reduce the soot is to increase the input of propane.  

This is incorrect because propane is in excess when soot production is maximized. Therefore adding more propane will only result in more soot.

The limiting reactant is oxygen; therefore the best way to reduce the soot is to add an oxygen source such as , which releases oxygen by thermal decomposition.

The limiting reactant is indeed oxygen and  does undergo thermal decomposition to produce oxygen. However it is also one of the primary ingredients for gunpowder (the other two ingredients have a high probability of being present in a device that processes tissue from living organisms), therefore the safety factor of this answer leads it to be incorrect. Not to mention that this method would not be the simplest solution.

Oxygen is in excess; therefore the best way to reduce the soot is to close the grill hood and close any vent holes preventing atmospheric oxygen from entering the system.

Oxygen is the limiting reactant; therefore cutting off the supply of oxygen would only create more soot or depending upon the degree to which the oxygen supply is cut off, this could stop the reaction altogether.

The soot production is due to a dirty grill and therefore your grill must be thoughly cleaned.  

A dirty grill may have soot in it, but unless the dirtiness is blocking off the supply of oxygen, the soot currently being produced is not caused by the dirt. In any case the root cause of any soot production is that oxygen is limiting and this answer does not address that fact.

Correct Answer and explanation:

The limiting reactant is oxygen; therefore the best way to reduce the soot is to decrease the input of propane, which is in excess.

The limiting reactant when soot is produced is oxygen. In most propane grills, the oxygen supply is maxed out at the level of atmospheric oxygen. Therefore the only reactant under your direct control is the propane. By reducing the quantity of propane, you can make it no longer in excess.

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