AP Chemistry : AP Chemistry

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #22 : P H And Poh Of Strong Acids And Bases

A 1M solution of a monoprotic acid has a pH of 4.6. What is the  value for the conjugate base of the acid?

Possible Answers:

Correct answer:

Explanation:

In order to find the base dissociation constant for the conjugate base, we can start by finding the acid dissociation constant for the acid. Since a 1M solution of the acid has a pH of 4.6, we can find the proton concentration of the solution.

Since the acid is monoprotic, we can set the following equilibrium expression equal to its acid dissociation constant.

We can see that, since the acid is monoprotic, the concntration of protons will be equal to the concentration of the acid anion. The final concentration of the acid molecule will be equal to the initial concentration, minus the amount of protons formed. Using these values, we can solve for the equilibrium constant for the acid.

Now that we have the acid dissociation constant, we can find the conjugate base's dissociation constant by setting the product of the two values equal to the autoionization of water.

Example Question #981 : Ap Chemistry

Would H2SO4 or HNO3 produce a more acidic solution?

Possible Answers:

H2SO4 since it has a higher pKa

HNO3 since it has a higher pKa

HNO3 since it has a lower pKa

H2SO4 since it has a lower pKa

Correct answer:

H2SO4 since it has a lower pKa

Explanation:

Both are strong acids, but H2SO4 is bivalent, realeasing 2 protons for each molecule dissolved in solution. Further, a more acidic solution would have a lower pKa.

Example Question #982 : Ap Chemistry

Which of the following species will not be present in an aqueous solution of ?

Possible Answers:

All of these will be present in the solution

Correct answer:

Explanation:

The hydroxide ion (OH–) is a strong base and therefore would not be present in an acidic solution. Protons, the hydronium ion, and water will all be present in relatively large amounts within the solution. 

Example Question #24 : P H And Poh Of Strong Acids And Bases

Which of the following anions is the strongest base?

Possible Answers:

Correct answer:

Explanation:

Weaker acids dissociate less in water and therefore, reverse reaction is favored in 

. This indicates that the weaker the acid, the stronger its conjugate base.

, and  are all strong acids. Their conjugates are weak bases.

 has the weakest conjugate acid among the all the choices, so it is the strongest base.

Example Question #1 : Galvanic (Voltai) And Elecrolytic Cells

Consider the following electrolytic cell:

      

What happens at the anode in the electrolytic cell?

Possible Answers:

Iron is reduced

Nickel is reduced

Nickel is oxidized

Iron is oxidized

Correct answer:

Nickel is oxidized

Explanation:

It does not matter if the cell is galvanic or electrolytic; oxidation will always take place at the anode. This means that the nickel loses two electrons and is oxidized at the anode to generate nickel ions.

Nickel ions and iron are products, and are neither oxidized nor reduced during the reaction. Iron ions are reduced at the cathode to generate the iron product.

Example Question #2 : Galvanic (Voltai) And Elecrolytic Cells

Consider the following reaction in a galvanic cell:

 

Which of the following takes place at the anode?

Possible Answers:

Zinc is reduced

Zinc is oxidized

Copper is reduced

No reaction takes place at the anode

Copper is oxidized

Correct answer:

Zinc is oxidized

Explanation:

Oxidation takes place at the anode and reduction takes place at the cathode. You can remember this with the pneumonic "An Ox, Red Cat."

In the equation, zinc loses electrons. It goes from a neutral, elemental charge to a charge of . Since electrons are negative, a loss of electrons will cause an increase in charge. Because zinc loses electrons, it is oxidized. This will take place at the anode.

Example Question #2 : Galvanic (Voltai) And Elecrolytic Cells

Toward which pole do electrons travel in a galvanic cell?

Possible Answers:

More information is needed

Electrons do not travel; only the protons travel

Towards the cathode

Towards the anode

Towards the negative pole

Correct answer:

Towards the cathode

Explanation:

Reduction always occurs at the cathode, and oxidation always occurs at the anode. Since reduction is the addition of electrons, the electrons must flow toward the site of reduction.

In a galvanic cell the positive charge is on the cathode, while the negative charge is on the anode. Since a galvanic cell has a positive potential and is spontaneous, electrons freely flow down their potential gradient. The electrons, which are negatively charged, are traveling towards the cathode, which is positive charged, since opposites attract.

Example Question #2 : Electrochemistry

Toward which pole do the electrons travel in an electrolytic cell?

Possible Answers:

More information is needed

Towards the cathode

Towards the anode

Towards the positive pole

The electrons do not travel; only the protons travel

Correct answer:

Towards the cathode

Explanation:

Reduction always occurs at the cathode, and oxidation always occurs at the anode. Since reduction is the addition of electrons, electrons must travel toward the site of reduction.

In an electrolytic cell the negative charge is on the cathode, while the positive charge is on the anode. Since an electrolytic cell requires energy to perpetuate the reaction, we are pushing the electrons against their potential gradient. The electrons, which are negatively charged, are traveling towards the cathode, which is also negatively charged.

Example Question #1 : Help With Galvanic Cells

Which of the following differences between galvanic cells and electrolytic cells is false?

Possible Answers:

Electrolytic cells have a positive Gibb's free energy

Electrolytic cells have oxidation take place at the cathode

Electrolytic cells have negative voltages

Electrolytic cells are non-spontaneous

Correct answer:

Electrolytic cells have oxidation take place at the cathode

Explanation:

Electrolytic cells use non-spontaneous reactions that require an external power source in order to proceed. The values between galvanic and electrolytic cells are opposite of one another. Galvanic cells have positive voltage potentials, while electrolytic voltage potentials are negative. Both types of cell, however, have oxidation occur at the cathode and reduction occur at the anode.

Example Question #3 : Galvanic (Voltai) And Elecrolytic Cells

What is true about the current flow in a galvanic cell?

Possible Answers:

Galvanic cells do not have a current

It travels from cathode to anode

It travels from anode to cathode

It flows in the direction of electron flow

Correct answer:

It travels from cathode to anode

Explanation:

In a galvanic cell, the electrons will flow from the anode to the cathode; however, current travels in the opposite direction of the electrons by convention. In chemical cells, current is defined by the direction in which protons would flow. As a result, current flows from the cathode to the anode.

Keep in mind that reduction occurs at the cathode and oxidation occurs at the anode. Electrons are thus constantly moving from the anode to the cathode. Since the current will be opposite to the flow of electrons, we can conclude that it must flow from cathode to anode.

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