AP Chemistry : AP Chemistry

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #13 : Gases

What is the osmotic pressure exerted by a solution of 2M CaCl2 at room temperature? (R=0.082 L*atm/K/mol)

Possible Answers:

147 atm


18 atm

6 atm

73 atm

250 atm

Correct answer:

147 atm

Explanation:

The van't Hoff factor for CaCl2 is 3 since the molecule dissociates in solution to 3 ions. T is in absolute temperature (25+273=298). This makes the osmotic pressure:

3*2M*0.082*298.

Example Question #331 : Ap Chemistry

At  the vapor pressure of pure water is . What is the minimum amount of liquid water we need to put in a  flask to achieve this vapor pressure.  

Possible Answers:

It does not matter the amount of water, the vapor pressure will always be reached

 which is equivalent to 

Correct answer:

 which is equivalent to 

Explanation:

We use the ideal gases equation to know the mol of water we need in the gas phase to generate a pressure of  in a  flask at .

And the mass is:

  

If we have less than that amount of water the liquid will evaporate completely but there will not be enough molecules to reach the vapor pressure. More than  of water will allow to reach the vapor pressure and there will be also a liquid leftover. Remember that the vapor pressure of a liquid at a fixed temperature is a constant.

Example Question #13 : Gases

 of  are introduced in a  flask. A vacuum is applied to the flask and its temperature raised to . At this temperature ammonium nitrate decomposes according to the reaction:

If the percent yield of this reaction is , which will be the total pressure of the flask after the reaction concludes.   

 

Possible Answers:

 

Correct answer:

 

Explanation:

Using the molecular mass we calculate the number of mol of  :

At this moment we could apply the percentage yield, however let's live it for the end. Each mole of  decomposed will generate  of gas. Then the total pressure assuming  yield will be:

Since only  of the  decomposes, the real total pressure will be:

Example Question #17 : Gases

It can be argued that one of the greatest innovations in automobile safety is the airbag. A typical driver's side airbag expands to a volume of between 50-60L. For this problem use . In older airbag models sodium azide is employed to produce nitrogen gas as shown in the following decomposition reaction:

Two more reactions are employed to remove the reactive sodium metal, shift the above reaction equilibrium to the right, and produce more nitrogen gas; however for this problem assume all gas is generated from the first reaction as shown above and that the reaction proceeds to completion.

The gauge pressure is . This is the pressure at which the airbag is deployed. Note: gauge pressure is defined as the additional pressure in the system relative to atmospheric pressure. In this case use STP pressure as atmospheric pressure.  

(It is worth noting that this pressure is the initial pressure to fill the airbag, which would provide a rock-hard cushion; therefore in the real world the air bag immediately begins to deflate so as to provide proper cushioning; that fact is not important for solving this problem). 

What is the minimum mass of  required to inflate the airbag given the above conditions?

Possible Answers:

Correct answer:

Explanation:

First, identify the necessary parameters.

We must use the ideal gas equation:

 and since the molar gas constant given uses Kelvin in it's definition, we must convert  to Kelvin as follows: 

Since the pressure given is gauge pressure, we must convert to the actual pressure as follow: 

So therefore the pressure we want to use is 

Now that we have listed the given quantities we can see that in order to get the mass of  needed, we must first find the number of moles of  needed to fill the volume of the airbag, then use the molar ratios from the above chemical equation to convert moles of  to moles of , after which we can use the molar mass of  to calculate the grams of  needed to inflate the airbag.

In order to calculate the number of moles of  we can employ the Ideal gas law: to find n (the number of moles of gas; which in this case the only gas involved is 

Plug in the given quantities that have been converted into the correct units and quantities:

Solve.

 

Now that we know the moles of  needed we can use stoichiometry, and the information in the following equation: 

To determine the number of moles of  required and then convert the moles of  to the grams of  using the molar mass of . The molar mass of  can be found by using a periodic table and adding the molar masses of the constituent elements as shown below:

 

Molar mass of

Given that we calculated the moles of  to fill the volume of the airbag to be:  , and the molar ratios from the chemical equation we can set up the final steps of the calculation as shown below:

  

Therefore in order to inflate this driver's side airbag it would need to contain at least 68.04g of 

Example Question #12 : Solutions And States Of Matter

Suppose that a container contains  of a gaseous sample of unknown hydrocarbon at STP. If this sample occupies a volume of , what is the identity of the hydrocarbon?

Possible Answers:

Correct answer:

Explanation:

In this question, we're given the mass and volume of an unknown hydrocarbon filling a container. We're asked to determine the identity of this compound.

To solve this problem, it's important to realize that for any ideal gas at STP (standard temperature and pressure),  of the gas will equate to  of that gas. For this question, we're told that there is  present. 

Now that we know how many moles of gas are in the container, we can use this information, together with the mass provided to us in the question stem, to determine the molecular mass of the unknown compound.

Looking at the answer choices, the only hydrocarbon that matches this molecular mass is ethane, .

Example Question #1 : Phase Changes

As condensation forms on a glass of ice water, the temperature of the air surrounding the glass __________.

Possible Answers:

increases

decreases

is impossible to determine

stays the same

Correct answer:

increases

Explanation:

As a substance condenses from the gas phase to the liquid phase, it loses energy in the form of heat loss. Heat is transferred from the water to the air, resulting in an increase in the temperature of the air. 

Example Question #2 : Phase Changes

How much energy is required to boil 9 moles of liquid water at its boiling point, and what is the temperature of the water vapor product?

Possible Answers:

Correct answer:

Explanation:

The enthalpy of vaporization gives the amount of energy required to evaporate a liquid at its boiling point, in units of energy per mole. The total energy requirement to heat a given amount of steam is found by mulitplying the the number of moles to be vaporized by the energy of vaporization per mole.

The temperature remains constant throughout a phase change, thus the final temperature would still be 100°C.

Example Question #1 : Phase Changes

How much heat must be added to raise a sample of 100g of water at 270K to 280K?

The specific heat capacity of water is , and water's heat of fusion is .

Possible Answers:

Correct answer:

Explanation:

The following fomula gives the heat needed to generate a given temperature change for a substance of known specific heat capacity:

where  is the heat input in Joules,  is the mass of the sample in grams, and  is the specific heat capacity in .

However, in the event of a phase change (water melts at 273K), the heat of fusion or vaporization must be added to the total energy cost. The formula becomes:

 

Example Question #1 : Phase Changes

Why does water boil at a lower temperature at high elevation?

Possible Answers:

Water has a higher vapor pressure at high elevation

The atmospheric pressure is lower at high elevations

There is a lower heat of fusion at higher elevation

Hydrogen bonds are easier to disrupt at high elevation

The higher the elevation, the denser water is. 

Correct answer:

The atmospheric pressure is lower at high elevations

Explanation:

Increasing temperature means that vapor pressure increases as well. When vapor pressure is equal to the atmospheric pressure, water boils. The atmospheric pressure is lower at high elevation, so water boils at a lower temperature. 

Example Question #2 : Energy Of Phase Changes

Heating curve

Using the heat curve, define the segment time(s) that the kinetic energy of the substance is increasing.

Possible Answers:

1, 2, and 5

2, 3, and 4

1, 3, and 5

2 and 4

Correct answer:

1, 3, and 5

Explanation:

Remember, temperature is a measure of the average kinetic energy of molecules. Therefore the kinetic energy increases whenever the temperature is increasing. So, the kinetic energy is increasing during segments 1, 3, and 5.

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