All AP Chemistry Resources
Example Questions
Example Question #13 : Gases
What is the osmotic pressure exerted by a solution of 2M CaCl2 at room temperature? (R=0.082 L*atm/K/mol)
147 atm
18 atm
6 atm
73 atm
250 atm
147 atm
The van't Hoff factor for CaCl2 is 3 since the molecule dissociates in solution to 3 ions. T is in absolute temperature (25+273=298). This makes the osmotic pressure:
3*2M*0.082*298.
Example Question #331 : Ap Chemistry
At the vapor pressure of pure water is . What is the minimum amount of liquid water we need to put in a flask to achieve this vapor pressure.
It does not matter the amount of water, the vapor pressure will always be reached
which is equivalent to
which is equivalent to
We use the ideal gases equation to know the mol of water we need in the gas phase to generate a pressure of in a flask at .
And the mass is:
If we have less than that amount of water the liquid will evaporate completely but there will not be enough molecules to reach the vapor pressure. More than of water will allow to reach the vapor pressure and there will be also a liquid leftover. Remember that the vapor pressure of a liquid at a fixed temperature is a constant.
Example Question #13 : Gases
of are introduced in a flask. A vacuum is applied to the flask and its temperature raised to . At this temperature ammonium nitrate decomposes according to the reaction:
If the percent yield of this reaction is , which will be the total pressure of the flask after the reaction concludes.
Using the molecular mass we calculate the number of mol of :
At this moment we could apply the percentage yield, however let's live it for the end. Each mole of decomposed will generate of gas. Then the total pressure assuming yield will be:
Since only of the decomposes, the real total pressure will be:
Example Question #17 : Gases
It can be argued that one of the greatest innovations in automobile safety is the airbag. A typical driver's side airbag expands to a volume of between 50-60L. For this problem use . In older airbag models sodium azide is employed to produce nitrogen gas as shown in the following decomposition reaction:
Two more reactions are employed to remove the reactive sodium metal, shift the above reaction equilibrium to the right, and produce more nitrogen gas; however for this problem assume all gas is generated from the first reaction as shown above and that the reaction proceeds to completion.
The gauge pressure is . This is the pressure at which the airbag is deployed. Note: gauge pressure is defined as the additional pressure in the system relative to atmospheric pressure. In this case use STP pressure as atmospheric pressure.
(It is worth noting that this pressure is the initial pressure to fill the airbag, which would provide a rock-hard cushion; therefore in the real world the air bag immediately begins to deflate so as to provide proper cushioning; that fact is not important for solving this problem).
What is the minimum mass of required to inflate the airbag given the above conditions?
First, identify the necessary parameters.
We must use the ideal gas equation:
and since the molar gas constant given uses Kelvin in it's definition, we must convert to Kelvin as follows:
Since the pressure given is gauge pressure, we must convert to the actual pressure as follow:
So therefore the pressure we want to use is
Now that we have listed the given quantities we can see that in order to get the mass of needed, we must first find the number of moles of needed to fill the volume of the airbag, then use the molar ratios from the above chemical equation to convert moles of to moles of , after which we can use the molar mass of to calculate the grams of needed to inflate the airbag.
In order to calculate the number of moles of we can employ the Ideal gas law: to find n (the number of moles of gas; which in this case the only gas involved is
Plug in the given quantities that have been converted into the correct units and quantities:
Solve.
Now that we know the moles of needed we can use stoichiometry, and the information in the following equation:
To determine the number of moles of required and then convert the moles of to the grams of using the molar mass of . The molar mass of can be found by using a periodic table and adding the molar masses of the constituent elements as shown below:
Given that we calculated the moles of to fill the volume of the airbag to be: , and the molar ratios from the chemical equation we can set up the final steps of the calculation as shown below:
Therefore in order to inflate this driver's side airbag it would need to contain at least 68.04g of
Example Question #12 : Solutions And States Of Matter
Suppose that a container contains of a gaseous sample of unknown hydrocarbon at STP. If this sample occupies a volume of , what is the identity of the hydrocarbon?
In this question, we're given the mass and volume of an unknown hydrocarbon filling a container. We're asked to determine the identity of this compound.
To solve this problem, it's important to realize that for any ideal gas at STP (standard temperature and pressure), of the gas will equate to of that gas. For this question, we're told that there is present.
Now that we know how many moles of gas are in the container, we can use this information, together with the mass provided to us in the question stem, to determine the molecular mass of the unknown compound.
Looking at the answer choices, the only hydrocarbon that matches this molecular mass is ethane, .
Example Question #1 : Phase Changes
As condensation forms on a glass of ice water, the temperature of the air surrounding the glass __________.
increases
decreases
is impossible to determine
stays the same
increases
As a substance condenses from the gas phase to the liquid phase, it loses energy in the form of heat loss. Heat is transferred from the water to the air, resulting in an increase in the temperature of the air.
Example Question #2 : Phase Changes
How much energy is required to boil 9 moles of liquid water at its boiling point, and what is the temperature of the water vapor product?
The enthalpy of vaporization gives the amount of energy required to evaporate a liquid at its boiling point, in units of energy per mole. The total energy requirement to heat a given amount of steam is found by mulitplying the the number of moles to be vaporized by the energy of vaporization per mole.
The temperature remains constant throughout a phase change, thus the final temperature would still be 100°C.
Example Question #1 : Phase Changes
How much heat must be added to raise a sample of 100g of water at 270K to 280K?
The specific heat capacity of water is , and water's heat of fusion is .
The following fomula gives the heat needed to generate a given temperature change for a substance of known specific heat capacity:
where is the heat input in Joules, is the mass of the sample in grams, and is the specific heat capacity in .
However, in the event of a phase change (water melts at 273K), the heat of fusion or vaporization must be added to the total energy cost. The formula becomes:
Example Question #1 : Phase Changes
Why does water boil at a lower temperature at high elevation?
Water has a higher vapor pressure at high elevation
The atmospheric pressure is lower at high elevations
There is a lower heat of fusion at higher elevation
Hydrogen bonds are easier to disrupt at high elevation
The higher the elevation, the denser water is.
The atmospheric pressure is lower at high elevations
Increasing temperature means that vapor pressure increases as well. When vapor pressure is equal to the atmospheric pressure, water boils. The atmospheric pressure is lower at high elevation, so water boils at a lower temperature.
Example Question #2 : Energy Of Phase Changes
Using the heat curve, define the segment time(s) that the kinetic energy of the substance is increasing.
1, 2, and 5
2, 3, and 4
1, 3, and 5
2 and 4
1, 3, and 5
Remember, temperature is a measure of the average kinetic energy of molecules. Therefore the kinetic energy increases whenever the temperature is increasing. So, the kinetic energy is increasing during segments 1, 3, and 5.