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Example Questions
Example Question #1 : Orbitals And Hybridization
What is true when comparing the electron configuration of elemental sodium and sodium cation ?
The sodium ion has more electrons in orbitals
The outermost shell of the sodium ion has one electron
Elemental sodium is paramagnetic
The sodium ion has one additional electron in an orbital
Elemental sodium is paramagnetic
To answer this question, we need to find the electron configuration of both elemental sodium and sodium cation. If we look at the periodic table we can see that sodium is found on the first column. Since it is found in the first column, sodium has one valence electron. To complete octet, sodium will readily lose an electron and become a positively charged sodium ion. The electron configuration for sodium is . The electron configuration for sodium ion is (because it lost its electron in the orbital). This means that elemental sodium has an unpaired electron in its orbital; the sodium ion has no unpaired electrons. Recall that an unpaired electron can generate its own magnetic field and is called paramagnetic; therefore, solid sodium is paramagnetic. The number of electrons in the orbitals for both sodium and sodium ion is the same (6 electrons total in the orbital). The outermost shell of sodium is the third shell (because sodium is located on the third row of periodic table). Elemental sodium contains one electron in the orbital in the outermost shell whereas the sodium ion contains 6 electrons in its outermost shell.
Example Question #1 : Orbitals And Hybridization
It is observed that a molecule has three hybridized orbitals in its outermost shell. What can you conclude about this molecule?
None of these
It has four single bonds
It has a lone pair electron
It has a double bond
It has a double bond
Hybridization is a process involving the fusion, or hybridization, of and orbitals to form a unique orbital. It is possible for various combinations of and hybridization. Recall that there is one orbital and three orbitals in each shell. This means that the one orbital can hybridize with 1, 2, or all 3 orbitals. Since there are three total combinations, there are three types of hybridized orbitals. These are , , and . orbital has one and one orbital hybridized. This means that the orbital and the first orbital become a new orbital. A molecule with hybridization will have two orbitals and two orbitals. Similarly, an orbital is made from the hybridization of one and two orbitals. In hybridization, there are three orbitals and one orbital. Finally, an orbital has one and all three orbitals; therefore, an hybridized molecule will have four orbitals and no orbitals. The question states that there are three hybridized orbitals in this molecule; therefore, this molecule must be hybridized. The single orbital is unhybridized because the molecule probably has a double bond. Electrons in bonds in double and triple bonds cannot be found in hybridized orbitals; therefore, they need their own orbital. If a molecule has one bond (double bond), then it will need one orbital and will be hybridized (because this will give three hybridized orbitals and one orbital). If it has two bonds (triple bond), then it will need two orbitals and will be hybridized. If a molecule has all bonds (single bonds), then the molecule will require no empty orbitals for the delocalized electrons, and will be hybridized.
Example Question #1 : Orbitals And Hybridization
Which of the following is true regarding carbon tetrachloride?
Hybridization in this molecule involves two times as many orbitals as orbitals
More than one of these are true
The carbon in this molecule has similar hybridization as the carbon in carbon dioxide
Hybridization in this molecule involves three times as many orbitals as orbitals
Hybridization in this molecule involves three times as many orbitals as orbitals
Carbon tetrachloride, , has a central carbon atom attached to four chlorine atoms. The bonds between the carbon atom and chlorine atoms are single covalent bonds. The electrons in a single bond ( bond) can be found in hybridized orbitals. Since carbon tetrachloride only has single bonds, the carbon atom can hybridize all of its orbitals (one and three ) in the outermost shell and form a hybridization; therefore, three orbitals and one orbital participate in hybridization leading us to the correct answer. Carbon dioxide, , has a central carbon atom bonded to two oxygen atoms. To complete octet, carbon and oxygen atoms have double bonds. This means that carbon dioxide has two bonds (two double bonds). Recall that electrons in bonds cannot reside in hybridized orbitals; therefore, to accommodate the two bonds we need two empty, unhybridized orbitals. This means that carbon dioxide will have hybridization of one and one orbital, giving it an hybridization.
Example Question #1 : Valence Electrons
How many valence electrons are in an atom of phosphorus?
Three
Eight
Thirteen
Five
Five
When determining the number of valence electrons for an atom, simply count the number of electrons present in the outermost shell's s and p orbitals. Phosphorus has two electrons in the 3s subshell, and three more in the 3p subshell, making a total of five valence electrons.
Example Question #1 : Valence Electrons
What is the complete electron configuration for the sulfur atom?
1s42p63s23p4
1s22s22p63s23p2
1s42p63s23p4
1s22s22p63s23p2
1s22s22p63s23p4
1s22s22p63s23p4
The types of subshells, from smallest to largest, are as follows: s, p, d, and f. These four subshells correspond respectively to the following quantum numbers: 0, 1, 2, and 3. From the periodic table, it is known that sulfur has 16 electrons. Additionally, the maximum number of electrons the s sublevel can hold is 2. The maximum number of electrons that the p subshell can hold is 6, and electrons fill orbitals from lowest to highest energy. 1s22s22p63s23p4 is the only choice that meets the criteria.
Example Question #1 : Valence Electrons
Arrange the following ions in order of decreasing ionic radius: nitride ion, oxide ion, sodium ion, aluminum ion.
The ions have the same ionic radius.
Notice that all the ions have the same electron configuration as neon: 1s22s22p6. Substances with the same number of electrons and the same electron configuration are isoelectronic, meaning the number of electrons is the same but the number of protons is not. In an isoelectronic series, the ion with the most protons is smallest because the nucleus exerts a stronger force of attraction and the electrons are pulled closer to the nucleus. Consequently, the ion with the fewest protons is largest. has the most protons, therefore it has the smallest ionic radius. Continuing with this inverse relationship, the correct answer is: .
Example Question #1 : Periodic Table Trends
Which of the following trends decreases as you move from left to right on the periodic table?
Ionization energy
Electron affinity
Atomic radius
Electronegativity
Atomic radius
Although it may seem counterintuitive, atomic radius does decrease from left to right on the periodic table. The reason for this is because the added positive charge in the nucleus causes the elctrons to be pulled more strongly towards the center, which decreases the atomic radius.
Example Question #1 : Periodic Table Trends
Which of the following atoms has the greatest electronegativity?
Arsenic
Sulfur
Phosphorus
Selenium
Sulfur
Electronegativity values become greater as you move up and to the right on the periodic table. Of the four atoms listed, sulfur is the highest up and farthest to the right, giving it the greatest electronegativity.
Example Question #11 : Atoms And Elements
Which of these is in order of increasing ionization energy?
Ionization energy is the amount of energy that an atom in the ground state must absorb to emit an electron. Upon ionization, a cation is formed. Ionization energy increases from bottom to top within a group, and from left to right within a row of the periodic table which is the opposite trend that atomic radius follows. Referring to the periodic table, we can see that of these group VII elements, fluorine has the highest ionization energy.
Example Question #12 : Atoms And Elements
Which of the following lists is arranged in order of increasing atomic radius?
All of these atoms are in group VII. Within a group, atomic radii increase from top to bottom due to the increased number of electron shells.
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