MCAT Physical : Solubility and Solution Equilibrium

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Example Question #11 : Solubility And Solution Equilibrium

Hypothetically, if calcium hydroxide, lithium hydroxide, and potassium hydroxide all had a  value of , which compound would have the greatest solubility?

Possible Answers:

The solubilities of all three compounds are equal

Correct answer:

Explanation:

Solubility is the ability of a solute to dissolve into a solvent. It is calculated by creating an equilibrium equation and solving for the concentration of dissolved ions.

For this question, we will need to set up equilibrium constant equations for each compound.

Note that the solid compounds are not included in the equilibrium expressions. Now we can work on finding the solubilities. For each mole of calcium hydroxide dissolved, one mole of calcium ions and two moles of hydroxide ions are released. For each mole of lithium hydroxide dissolved, one mole of lithium ions and one mole of hydroxide ions are released. For each mole of potassium hydroxide dissolved, one mole of potassium ions and one mole of hydroxide ions are released. Mathematically, we can equate these ratios to the ion concentrations in the equilibrium calculations.

In these calculations, is the solubility. Given the solubility constants, we can solve for .

Calcium hydroxide has the greatest solubility.

Example Question #12 : Solubility And Solution Equilibrium

The solubility product constant of   is . What is the solubility of this compound?

Possible Answers:

Correct answer:

Explanation:

Solubility is the ability of a solute to dissolve into a solvent. It is calculated by creating an equilibrium equation and solving for the concentration of dissolved ions.

For this question, we will need to set up the equilibrium constant equation for calcium hydroxide.

Note that the solid compound is not included in the equilibrium expression. Now we can work on finding the solubility. For each mole of calcium hydroxide dissolved, one mole of calcium ions and two moles of hydroxide ions are released. Mathematically, we can equate this ratio to the ion concentrations in the equilibrium calculation.

In this calculation, is the solubility. Given the solubility constant, we can solve for .

Example Question #13 : Solubility And Solution Equilibrium

How many moles of fluoride ions are present in  of a completely saturated solution of lead (II) fluoride?

Possible Answers:

Correct answer:

Explanation:

Recall that the solubility product constant is given by the equation below, for a reaction in the following format.

Using our balanced reaction, we can find the solubility product equation for the dissociation of lead (II) fluoride.

For each molecule of lead (II) fluoride that dissolves, it produces one lead ion and two fluoride ions. We can conclude that the concentration of fluoride ions in solution will be twice the concentration of lead ions.

Use these variables in the solubility product equation, along with the given value from the question.

Now we can solve for the value of .

Remember that this value is equal to the concentration of lead ions in solution and half the concentration of fluoride ions in solution.

Example Question #1 : Equilibrium Constant And Reaction Quotient

Which of the following is true regarding the solubility product constant, , for a reaction in the form:

Possible Answers:

 has units of moles per liter

The concentration of substance  strongly influences the value of 

 represents the ratio of reactants to products as the reaction progresses

As more of substance  dissolves in the given solution, increases

Correct answer:

Explanation:

To determine the solubility product constant, we only need the concentrations and coefficients of the ions. The effective concentration of any pure substance (solid, liquid, or gas) is equal to one by definition, so does not influence the value of . The equation for the solubility product constant of this reaction is:

The units of the solubility product constant will depend on the coefficients of the products. will be a constant for the reaction, and will not change as more solid dissolves or as the reaction progresses.

Example Question #11 : Solubility And Solution Equilibrium

Which of the following will not increase the solubility of a solution?

Possible Answers:

Increasing the temperature of a gas solute in a liquid solvent

All of these will increase solubility

Decreasing the temperature of a gas solute in a liquid solvent

Increasing the temperature of a solid solute in a liquid solvent

Increasing the pressure of a gas solute in a liquid solvent

Correct answer:

Increasing the temperature of a gas solute in a liquid solvent

Explanation:

Increasing the temperature of a gas solute in a liquid solvent will decrease solubility. While dissolved, the gas is in equilibrium with the liquid. Adding heat will push the equilibrium in favor of the gas, causing it to precipitate from solution in the form of bubbles.

Increasing the pressure of a gas solute in a liquid solvent, decreasing the temperature of a gas solute in a liquid solvent, and increasing the temperature of a solid solute in a liquid solvent will all increase the solubility. 

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