MCAT Physical : Electron Configuration

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

Example Question #49 : Nuclear Chemistry And Electrons

An electron in which of the following orbitals is closest to the nucleus?

Possible Answers:

Correct answer:

Explanation:

Nuclear orbitals will always fill from the innermost to the outermost subshells. Using the  rule, we can approximate the order in which these orbitals will fill. Because electrons fill starting with the centermost orbitals, the electron that is closest to the nucleus will belong to the orbital that fills first.

corresponds to the principle quantum number, the first number in the given orbital location. is the azimuthal quantum number, and dictates the shape of the orbital.

        

5s and 3d produce the same number from the  equation, but in the event of a tie we always pick the orbital with the lowest letter (s < p < d < f). The innermost orbital will be 5s.

Example Question #831 : Mcat Physical Sciences

What is the electron configuration of Fe+?

Possible Answers:

Correct answer:

Explanation:

When an element loses an electron it is generally taken away from the highest electron shell. The electron configuration of iron (Fe) is . The 4s orbital is farther away from the nucleus than the 3d orbital, therefore the electron configuration of Fe+ will be .

Example Question #841 : Mcat Physical Sciences

Which of the following is the correct electronic configuration for vanadium?

Possible Answers:

[Ar]3d34s2

[Ar]3d24s2

[Ar]4s24p3

[Ar]3d44s1

Correct answer:

[Ar]3d34s2

Explanation:

When determining electronic configuration, the answer is made much easier by starting with the next smallest noble gas in brackets. As a result, [Ar] is an appropriate way to incorporate every previous electron before argon.

After argon, vanadium has five other electrons to distribute, and because vanadium is a transitional element, it will fill its 3d subshells before filling the 4p subshells. The 4s subshell is filled first, and the last three electrons are placed into the 3d subshells.

[Ar]3d34s2

Example Question #14 : Electron Configuration

Which of the following is the correct notation for a sodium ion?

Possible Answers:



Correct answer:


Explanation:

A neutral atom of sodium would contain eleven electrons to balance out the charge of the eleven protons in the nucleus. We are asked, however, for the configuration of a sodium ion. Sodium is an alkali metal, meaning that it will ionize by losing only one electron, gaining a charge of . By losing one electron, sodium drops from having eleven electrons to ten. We will need to select the answer that shows an electron removed form the outermost shell.

Neutral sodium:

Sodium ion:

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