All High School Chemistry Resources
Example Questions
Example Question #1 : Thermochemistry And Energetics
Which condition is always true for an exothermic reaction?
Heat is being gained from the environment
is negative
There must be a catalyst involved
is positive
is negative
When a reaction is exothermic ("exo-" meaning out and "-thermic" having to do with heat), it means that the reaction is giving off heat into the environment. Therefore, the reactants have a net heat loss throughout the process of the reaction.
The change in enthalpy, , is a measure of the change in heat energy during a reaction. is always negative for an exothermic process because the products always have less heat energy than the reactants.
Example Question #521 : High School Chemistry
Which condition is always true for an exothermic reaction?
Heat is being gained from the environment
is positive
is negative
There must be a catalyst involved
is negative
When a reaction is exothermic ("exo-" meaning out and "-thermic" having to do with heat), it means that the reaction is giving off heat into the environment. Therefore, the reactants have a net heat loss throughout the process of the reaction.
The change in enthalpy, , is a measure of the change in heat energy during a reaction. is always negative for an exothermic process because the products always have less heat energy than the reactants.
Example Question #1 : Help With Endergonic And Exergonic Reactions
Which of the following is considered an exothermic reaction?
Synthesis reactions
Forming a bond
Decomposition reactions
Breaking a bond
Single-replacement reactions
Forming a bond
An exothermic reaction releases energy into the environment. In contrast, endothermic reactions require an input of energy to initiate the reaction.
Forming a bond is always an exothermic reaction because it releases energy. Breaking a bond always requires energy, and is thus an endothermic process. Synthesis, decomposition, and single-replacement reactions can be either exothermic or endothermic, and cannot be determined without more information.
Example Question #2 : Help With Endergonic And Exergonic Reactions
Which type of reaction will happen spontaneously?
Exothermic reactions
Reactions that increase entropy
Endergonic reactions
Endothermic reactions
Exergonic reactions
Exergonic reactions
Spontaneity is determined by Gibbs free energy. When Gibbs free energy is less than zero, the reaction is considered exergonic and will occur spontaneously. When Gibbs free energy is greater than zero, the reaction is considered endergonic and will not occur spontaneously.
Exothermic reactions cause a release of enthalpy (heat) from the system and endothermic reactions require and input of energy to initiate the reaction. Gibbs free energy is determined by enthalpy, entropy, and temperature. A negative enthalpy, high temperature, and high entropy will cause the reaction to be more spontaneous, but must all come together to contribute. Simply because a reaction is exothermic does not meant that is increases entropy enough to be spontaneous.
Example Question #1 : Help With Enthalpy
Consider the following balanced reaction:
What is the change in enthalpy if of solid carbon is used in the above reaction?
The enthalpy of describes the amount of heat when the amount of carbon in the balanced reaction (two moles) is used. Since only of carbon are used, we can find how much heat is released.
When two moles of carbon are used, are released. Two moles of carbon is equal to of carbon, based on carbon's atomic mass.
Knowing this, we can set up proportions in order to determine how much heat is released by of carbon.
So of carbon results in of heat being released to the surroundings.
Example Question #11 : Thermochemistry And Energetics
Consider these two half reactions:
Step 1.
Step 2.
Based on these half reactions, find the enthalpy for the following reaction:
Hess's law states that the enthalpy of the total reaction is equal to the enthalpy of the steps required to get to the total reaction, regardless of the path that is chosen. This means that we can combine the two half steps with known enthalpies in order to solve for the enthalpy of the main reaction.
Step 1.
Step 2.
Total:
Since step 1 results in two moles of liquid water, we need to use the second step twice in order to replace them with two moles of water vapor.
Combined:
Since the total reaction is created by step 1 occurring once and step 2 occurring twice, we can write the enthalpy as:
Use the given enthalpies of the steps to calculate the total change in enthalpy.
Example Question #2 : Help With Enthalpy
How much energy is required to heat of from to ?
Use the following formula:
Plug in values:
Example Question #521 : High School Chemistry
Which of the following phases and states has the highest entropy?
Gas
Aqueous solution
Liquid
Solid
Colloid
Gas
Entropy is defined as the amount of disorder in a system and is favored in biological and chemical systems. Any system will prefer to have higher entropy, and spontaneous reactions will generally increase entropy in the system.
Gas particles move at higher velocity and with greater range than particles in liquids and solids. This contributes to their high level of entropy. Aqueous solutions gain entropy with the number of ions in solution, but do not reach the same level of entropy of gases. Colloids are homogenized mixtures, such as milk, and follow relatively the same principles as aqueous solutions.
Example Question #2 : Help With Entropy
Which of the following results in a decrease in entropy?
Allowing a gas to diffuse
Melting ice
Building a road
Breaking a mirror
Building a road
Entropy can be thought of as the tendency for a system to favor disorder. This means that the least ordered scenario in a system is typically favored by probability. Entropy increases when disorder is increased. Examples include an ice cube melting into a puddle, a gas diffusing all throughout a room, and a mirror shattering. Each of these either increases the energy of the system or results in the creation of multiple pieces/particles from a single object.
When building a road, materials are placed in an ordered, specific manner. This gives it a negative entropy.
Example Question #3 : Help With Entropy
For any chemical reaction __________.
the entropy change of the universe is greater than or equal to zero
the system experiences an increase in entropy
the universe loses entropy
the entropy of the surroundings must decrease
the entropy change of the universe is greater than or equal to zero
Any reaction can be thought of as taking place in a system, while the surroundings are the rest of the universe. It helps to remember that the entropy of the universe is constantly increasing. This means that the entropy change in the universe increases following every reaction. A system can have a decrease in entropy, as long as the entropy of the surroundings increases by a greater value.