AP Chemistry : Chemical Equilibrium

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #60 : Reactions And Equilibrium

Consider the following (arbitrary) reaction:

A_2O_{4\hspace{1 mm}(aq)}\leftrightharpoons 2AO_{2\hspace{1 mm}(aq)}

At equilibrium, [A_2O_4]=0.25\hspace{1 mm}M and [AO_2]=0.04\hspace{1 mm}M.

What is the value for the equilibrium constant, K_{eq}?

Possible Answers:

156.25

Correct answer:

Explanation:

First, consider the formula for the equilibrium constant of arbitrary reaction:

aA+bB \leftrightharpoons cC+dD

K_{eq}=\frac{[C]^c[D]^d}{[A]^a[B]^b}

The formula for the equilibrium constant for this reaction is:

K_{eq}=\frac{[AO_2]^2}{[A_2O_4]}=\frac{[0.04]^2}{[0.25]}=6.4\times10^{-3}

Example Question #11 : Equilibrium Constant And Reaction Quotient

Which of the following is true when the reaction quotient (Q) equals the equilibrium constant (K)?

Possible Answers:

The change in free energy is greater than zero.

Change in free energy = 0.

The change in free energy is less than zero.

The reaction stops completely.

Correct answer:

Change in free energy = 0.

Explanation:

When Q = K, the reaction has reached equilibrium and is in a state of dynamic equilibrium, where the forward and reverse reactions are occurring at the same rate. Since there is no net change in concentration, the free energy is zero. 

Example Question #12 : Equilibrium Constant And Reaction Quotient

If delta G for a certain reaction is found to be -4955 J/mol, what is the equilibrium constant (Keq) for this reaction?

Possible Answers:

100

5.9

7.4

55.6

80.9

Correct answer:

7.4

Explanation:

Given the equation delta G = -RTln(Keq), plugging in the correct values for the variables will lead us to the correct answer. Using e = 2.7, R = 8.314 J/molK, T= 298 K, and G = -4955 J, we can calculate that K = 7.4.

Example Question #13 : Equilibrium Constant And Reaction Quotient

If cesium metal spontaneously combusts when it comes in contact with room temperature water, which of the following must be true of the equilibrium constant of the reaction at 298 K?

Possible Answers:
K = 1
All of the above
K > 1
Not enough information
K < 1
Correct answer: K > 1
Explanation:

When K is greater than 1, the products are favored and the reaction proceeds forward spontaneously. This must be true of the reaction, since it spontaneously occurs when the metal comes into contact with the water.

Example Question #7 : Chemical Reactions

For the following reaction, what would be the correct equilibrium expression?

Possible Answers:

Correct answer:

Explanation:

For any equilibrium expression, solids and liquids are excluded because their concentrations are presumed to be constant during the reaction. The equilibrium expression is defined as the ratio of the concentration of products divided by the concentration of the reactants. Each reactant or product is raised to the power corresponding to its coefficient in the balanced chemical equation.

Using an arbitrary example:

Compare this to our question. Remember to exclude the solid magnesium!

Example Question #8 : Chemical Reactions

Determine the equation for the equilibrium constant of the following unbalanced reaction:

Possible Answers:

Correct answer:

Explanation:

The equilibrium constant, , is the ratio of the concentration of products raised to their coefficients, over the concentration of reactants raised to their coefficients. To find its value, we first need to balance the equation and then consider only the products and reactants that actually have concentrations (i.e. aqueous and gaseous species). Liquids and solids can be omitted from the calculation.

We note that chlorine only appears once on the right, so we add a 2 coefficient to balance the equation: 

Since is a solid (most hydroxides precipitate, unless they are paired with alkali metals, barium, or calcium) it will not be included in the equilibrium constant calculation.

The chloride ion concentration is raised to the second power because of the 2 coefficient that we added. So, putting products (species on the right side, other than the solid) on the top and reactants (species on the left) on bottom, we get: 

Example Question #1 : Identifying Reaction Equilibrium

Consider the following generic reaction:

If the equilibrium concentration of  is 1M, what is the equilibrium concentration of ?

Possible Answers:

Correct answer:

Explanation:

We can set up the equilibrium expression by placing the products, raised to the power of their coefficients, in the numerator and reactants, raised to the power of their coefficients, in the denominator:

We are given the value of the equilibrium constant and the equilibrium concentration of . Using stoichiometric coefficients, we can determine that a variable concentration, , of  will be present at equilibrium, and  of  will be present at equilibrium. Plugging in:

Simplify:

Now we can solve for  (which is the equilibrium concentration of , as we assigned) by dividing both sides by 4 and then taking the cube root.

Rounding to 2 sig figs (to match the two numbers we were given by the problem), we get:

Example Question #1 : Le Chatelier's Principle

Which of the following will cause an equilibrium shift in an exothermic reaction towards the products?

I. Decreasing the temperature

II. Evaporating the product

III. Adding a catalyst

Possible Answers:

I, II, and III only

I and II only

I only

III only

I and III only

Correct answer:

I and II only

Explanation:

I) Decreasing the temperature would take away heat from the system (a product), driving the reaction towards the products. II) Evaporating product would take a product away from the system, driving the reaction towards the products. III) Adding a catalyst only affects the rate of the reaction and does not effect equilibrium.

Example Question #1 : Le Chatelier's Principle

According to Le Chatelier's principle, which of the following occurs when you compress a system containing at least one gas species?

Possible Answers:

not enough information to determine

remains at equilibrium

shifts to favor the side with less moles of gas

shifts to favor the side with more moles of gas

Correct answer:

shifts to favor the side with less moles of gas

Explanation:

According to Le Chatelier's principle, when you compress a system, its volume decreases, so partial pressure of the all the gases in the system increases. The system will act to try to decrease the pressure by decreasing the moles of gas. 

Example Question #1 : Le Chatelier's Principle

If heat is added to an endothermic reaction, in which direction will the equilibrium shift according to Le Chatelier's principle?

Possible Answers:

to the left

equilibrium does not shift

cannot be determined 

to the right

Correct answer:

to the right

Explanation:

In an endothermic reaction, heat can be treated as a reactant. Thus, if you add more reactant (heat), the system will shift to get rid of the extra reactant and shift to the right to form more products.

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