MCAT Physical : Oxidation-Reduction

Study concepts, example questions & explanations for MCAT Physical

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Example Questions

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Example Question #1 : General Principles Of Oxidation Reduction

Which compound is oxidized in the following reaction?

Possible Answers:

Correct answer:

Explanation:

Oxidation is defined by a loss of electrons, generally resulting in a more positive charge on an atom. Reduction is defined by a gain of electrons, generally resulting in a more negative charge on an atom. To identify the compound being oxidized, we need to find which compound is becoming more positive.

Zinc is initially neutral, but gains a positive two charge as a product. Hydrogen initially has one positive charge, but becomes neutral in the product. The distinction becomes even clearer if we break the overall reaction into two half-reactions.

We can see that zinc is losing electrons and hydrogen is gaining electrons. Zinc is thus being oxidized.

Example Question #22 : Oxidation Reduction

Which of the following is an incorrect example of a combustion reaction?

Possible Answers:

Correct answer:

Explanation:

We often hear of combustion reactions producing carbon dioxide and water. This is true when the reactants contain all three elements (hydrogen, oxygen, and carbon) needed to make carbon dioxide and water. The trick here is to understand that although combustion is just an oxidation reaction (ie, creating more carbon-oxygen bonds), all reactions must still be balanced. One answer choice fails to balance hydrogen in the reaction.

Although we do see an oxidation reaction with the formation of carbon dioxide, the reaction is NOT balanced. This reaction cannot possibly take place as written.

Example Question #21 : Oxidation Reduction

Which of the following is the oxidizing agent in the following equation?

Possible Answers:

Cr(s)

Al(s)

Al3+

Cr3+

Correct answer:

Cr3+

Explanation:

An oxidizing agent is one that oxidizes another element and, becomes reduced in the process. Oxidizing and reducing agents are found in the reactants of the equation, eliminating Al3+ and Cr(s) as answer choices. Cr3+ gains three electrons to become Cr(s), which has an oxidation number of zero. Cr3+ becomes reduced, while Al(s) is oxidized, therefore, Cr3+ is the oxidizing agent. Remember "OIL RIG": Oxidation Is Loss of electrons and Reduction Is Gain of electrons.

Example Question #1 : General Principles Of Oxidation Reduction

In the above unbalanced redox reaction, which best describes the oxidation/reduction roles of iron and oxygen?

Possible Answers:

Iron is oxidized, oxygen is neither oxidized nor reduced

Iron is reduced, oxygen is oxidized 

Iron is reduced, oxygen is neither oxidized nor reduced

Iron is reduced, oxygen is reduced

Iron is oxidized, oxygen is reduced

Correct answer:

Iron is oxidized, oxygen is reduced

Explanation:

There are a couple options to solve this problem. First, we could simply remember that anything which combines with oxygen in a redox reaction is oxidized, and the associated oxygen is reduced.

Another option is to think about the oxidation numbers of each element (an element whose oxidation number increases is oxidized, and one whose oxidation number decreases is reduced). If we choose this method, recall that free elements (Fe and O2 in this case) have oxidation number 0. Also, oxygen in compounds has oxidation number -2. Oxygen's oxidation number decreases from 0 to -2, meaning that oxygen is reduced. Since oxidation and reduction occur at the same time in different elements of the redox reaction, iron's oxidation number must increase, so iron is oxidized.

Example Question #21 : Oxidation Reduction

Consider the following combustion reaction.

Which of the following statements correctly describes carbon in the reaction?

Possible Answers:

Carbon is oxidized in the reaction

Carbon is the oxidizing agent in the reaction

Carbon is neither oxidized nor reduced in the reaction

Carbon is reduced in the reaction

Correct answer:

Carbon is oxidized in the reaction

Explanation:

This problem requires us to determine the oxidation number of carbon as a reactant and as a product. The oxidation number of carbon as a reactant is –4, because it is attached to four hydrogens each with a charge of +1. The overall charge on the molecule is zero, the carbon must cancel out the charges contributed by hydrogen.

Carbon as a product has an oxidation number of +4, because it is attached to two oxygens, each with an oxidation number of –2. Again, we know that the molecule is neutral, and carbon must balance the charges from oxygen

Since the oxidation number of carbon went from –4 to +4, we conclude that carbon has been oxidized in the reaction. Any atom that loses electrons is oxidized, while any atom to gain electrons is reduced.

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