GRE Subject Test: Biochemistry, Cell, and Molecular Biology : Chemical Reactions

Study concepts, example questions & explanations for GRE Subject Test: Biochemistry, Cell, and Molecular Biology

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All GRE Subject Test: Biochemistry, Cell, and Molecular Biology Resources

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Example Questions

Example Question #4 : Help With Acid Base Chemistry And P H

A buffer can be created by adding equal amounts of weak acid and its conjugate base. What additional information is needed to determine the pKa of a buffer made in this manner?

Possible Answers:

pH

None of these are needed

Concentration of acid and conjugate base

Both of these are needed

Correct answer:

pH

Explanation:

The buffer is made by using weak acid and its conjugate base. The relationship between the concentration of the components (acid and conjugate base), pKa, and pH can be determined by using the Henderson-Hasselbalch equation.

where  is weak acid and  is the conjugate base. We know that equal amounts of  and  are added; therefore,  for buffer solutions made in this manner. To calculate the pKa of the solution we need the pH.

Example Question #4 : Help With Acid Base Chemistry And P H

A researcher adds   acid to  . The concentration of hydrogen ions is __________ as the concentration of hydroxide ions.

Possible Answers:

the same

half as much

three times as much

twice as much

Correct answer:

the same

Explanation:

Hydrochloric acid () and sodium hydroxide () are both strong reagents. Adding equal amounts of strong acid to a strong base neutralizes the solution and gives the solution a neutral pH of 7. This means that the concentration of hydrogen ions and hydroxide ions are equal to each other. If pH was greater than 7 (basic pH), then the hydroxide ion concentration would be higher and if pH was less than 7 (acidic pH) then hydrogen ion concentration would be higher.

Example Question #2 : Help With Acid Base Chemistry And P H

Solution A contains a weak acid and a weak base whereas solution B contains a weak acid and a strong base. What can you conclude about these two solutions?

I. Solution B will have a higher 

II. Solution B will have a higher pOH

III. Solution A will have a lower concentration of hydroxide ions

Possible Answers:

I and II

None of these

II and III

III only

Correct answer:

III only

Explanation:

Solution A has two weak reagents whereas solution B contains a strong base. This means that solution B will be more basic, will have a higher concentration of hydroxide ions, and a higher pH.  is a constant and is not altered by the relative reagents (it is always equal to ). Recall that pOH is defined as

This equation suggests that pOH decreases as the hydroxide ion concentration increases. Since it has the higher hydroxide ion concentration, solution B will have a lower pOH.

Example Question #93 : Gre Subject Test: Biochemistry, Cell, And Molecular Biology

What is the pH of a solution composed of  acetic acid and  acetate?

 for acetic acid is 

Possible Answers:

Correct answer:

Explanation:

Since this problem involves both the acid and the conjugate base of the acid, we can use the Henderson-Hasselbach equation in order to determine the pH of the solution:

Example Question #11 : Chemical Reactions

If a  solution of hydrofluoric acid is created, what fluoride ion concentration must be present in order to make the new pH of the solution equal to ?

 for hydrofluoric acid is 

Possible Answers:

Correct answer:

Explanation:

In order to determine what concentration of fluoride is needed, we can use the Henderson-Hasselbach equation:

All GRE Subject Test: Biochemistry, Cell, and Molecular Biology Resources

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