All AP Chemistry Resources
Example Questions
Example Question #341 : Ap Chemistry
In the given heating curve, when is the potential energy the highest?
The end of segment 2
The beginning of segment 4
The end of segment 4
The beginning of segment 2
The end of segment 4
The potential energy increases as the substance goes through phase changes. Therefore the potential energy is highest at the last possible instant of the most energy intensive phase change. In this case it is at the end of segment 4.
Example Question #11 : Phase Changes
The given heating curve represents a substance in phases solid, liquid, and gas. What is the melting point of the substance?
Because phase changes happen when the kinetic energy (temperature) remains constant melting will occur during a flat portion of the heating curve.
In this case it is the first flat portion because solid is the lowest energy phase represented in this diagram. Therefore the melting point is at .
Example Question #11 : Phase Changes
Suppose that a block of ice is exactly at its melting temperature, . If heat is added evenly to the block, which of the following does not occur?
The temperature remains constant until the ice melts
The intermolecular hydrogen bonds between water molecules are broken
The entropy of the system increases
The kinetic energy of the water molecules increases
The kinetic energy of the water molecules increases
This question is presenting us with a scenario in which heat is being added to a block of ice at its melting temperature. It's asking us to identify a false statement.
Recall that when anything goes through a phase change, the temperature remains the same until the phase change is complete. Furthermore, since temperature is a measure of the average kinetic energy of a system, this will not change either. Moreover, as energy is added to a system, the bonds between the components of that system will gradually weaken and then break as the entropy of that system increases.
Example Question #1 : Phase Diagrams
What is the definition of the triple point?
Definition of triple point: where solid, liquid, and gas exist in equilibrium
Example Question #2 : Phase Diagrams
What is represented by point D
Critical point
liquid phase
evaporation
Triple point
condensation
Critical point
the critical point is where the solid and gas cannot be distinguished
Example Question #1 : Phase Diagrams
A solution of water is at 0.006atm and 0.01 degrees Celsius. What phase(s) are present in the sample?
Solid and gas
Liquid and gas
Solid and liquid
Solid, liquid, and gas
Liquid only
Solid, liquid, and gas
The point detailed in the question is the triple point of water on the phase diagram. At the triple point all three phases of a chemical coexist; as such the correct answer is solid, liquid, and gas.
Example Question #11 : Phase Changes
Liquid water at room temperature is cooled to -75O C
Which of the following descriptions applies to the process outlined above?
I: A physical change occurred
II: A chemical change occurred
III: There was a change in entropy
I only
I,II, and III
II and III
I and III
II only
I and III
A physical change is a process where the physical properties of a substance are changed. Here water undergoes a phase change from the more disordered liquid state to the more ordered solid state, which is indeed a physical change. A chemical change describes when a substance undergoes a change in the identity of its constituent molecules. Here although the water has gone from the liquid phase to the solid phase it is still composed only of water molecules so a chemical change has not occured. Entropy describes the degree to which a system is ordered. Here we do have a change in entropy becasue the liquid water was more disordered than the solid water.
Example Question #1 : Types Of Phase Changes
A large number of molecules begin moving very fast, rarely bumping into one another, and taking up the entire space available to them. As the temperature drops and the kinetic energy of the particles decreases, the particles move more slowly and run into each other more often. They eventually form a lattice structure, only slightly moving. What is this process called?
Freezing
Decrease in temperature
Condensation, then freezing
Sublimination, then freezing
Vaporization, then condensation
Condensation, then freezing
This is a description of condensation from the gas phase to the liquid phase, then freezing from the liquid phase to the solid phase.
Example Question #2 : Types Of Phase Changes
A phase diagram is used to show the phase that a compound will be in depending upon the environmental temperature and pressure.
Carbon dioxide will sublimate from a solid to a gas at room temperature. What would be necessary in order to cause solid carbon dioxide to melt?
Decrease the temperature
Carbon dioxide cannot be melted
Increase the temperature
Decrease the pressure
Increase the pressure
Increase the pressure
At a pressure of one atmosphere, carbon dioxide can only exist in the solid phase or the gaseous phase. Solid carbon dioxide will sublimate at standard conditions.
Raising the temperature will simply make the carbon dioxide sublimate at a faster rate. In order to allow the solid carbon dioxide to melt into the liquid phase, the carbon dioxide must be subjected to a greater amount of pressure. This will shift equilibrium away from the gaseous state and toward the liquid state.
Example Question #12 : Phase Changes
A solution of water is at 0 degrees Celcius and 3atm. The pressure is constantly decreased until it was well below 0.000001atm. What will happen to the solution?
The liquid water will turn into water vapor
The liquid water will turn into ice, then into water vapor
The ice will turn straight into water vapor
The water starts off as a vapor, and will remain as a vapor
The ice will turn into liquid, then into water vapor
The liquid water will turn into ice, then into water vapor
Whenever you see a problem like this, immediately draw a mental point on the phase diagram to establish your starting conditions. In our case, the conditions fall in the range of the liquid phase of the water. This allows us to eliminate some of our answer options.
Next, determine what change is occuring and on which axis the change is occuring. We are decreasing pressure, so you are going to need to move down on the y-axis towards 0. Draw an imaginary line from the initial point to where the final point should be. In our case, the final pressure is extremely small. This point is not on the y-axis, but we can use our inference/inductive skills to determine that we will pass through the solid phase (ice) as we approach the gas phase (water vapor). Even if you didn't know the water would become vaporized, based on the graph you knew that the liquid phase had to be followed by the solid phase, and only one answer choice has that option.
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