AP Chemistry : Phase Changes

Study concepts, example questions & explanations for AP Chemistry

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Example Questions

Example Question #341 : Ap Chemistry

Heating curve

In the given heating curve, when is the potential energy the highest?

Possible Answers:

The end of segment 2

The beginning of segment 4

The end of segment 4

The beginning of segment 2

Correct answer:

The end of segment 4

Explanation:

The potential energy increases as the substance goes through phase changes. Therefore the potential energy is highest at the last possible instant of the most energy intensive phase change. In this case it is at the end of segment 4.

Example Question #11 : Phase Changes

Heating curve

The given heating curve represents a substance in phases solid, liquid, and gas. What is the melting point of the substance?

Possible Answers:

Correct answer:

Explanation:

Because phase changes happen when the kinetic energy (temperature) remains constant melting will occur during a flat portion of the heating curve.

In this case it is the first flat portion because solid is the lowest energy phase represented in this diagram. Therefore the melting point is at .

Example Question #11 : Phase Changes

Suppose that a block of ice is exactly at its melting temperature, . If heat is added evenly to the block, which of the following does not occur?

Possible Answers:

The temperature remains constant until the ice melts

The intermolecular hydrogen bonds between water molecules are broken

The entropy of the system increases

The kinetic energy of the water molecules increases

Correct answer:

The kinetic energy of the water molecules increases

Explanation:

This question is presenting us with a scenario in which heat is being added to a block of ice at its melting temperature. It's asking us to identify a false statement.

Recall that when anything goes through a phase change, the temperature remains the same until the phase change is complete. Furthermore, since temperature is a measure of the average kinetic energy of a system, this will not change either. Moreover, as energy is added to a system, the bonds between the components of that system will gradually weaken and then break as the entropy of that system increases.

Example Question #1 : Phase Diagrams

What is the definition of the triple point?

Possible Answers:
The condensation line of the phase diagram
None of these
The state where liquid and gas cannot be differentiated
The state where solid, liquid, and gas coexist in equilibrium
The point in which temperature change has no effect on the substance
Correct answer: The state where solid, liquid, and gas coexist in equilibrium
Explanation:

Definition of triple point: where solid, liquid, and gas exist in equilibrium

Example Question #2 : Phase Diagrams

What is represented by point D

Possible Answers:

Critical point

liquid phase

evaporation

Triple point

condensation

Correct answer:

Critical point

Explanation:

the critical point is where the solid and gas cannot be distinguished

Example Question #1 : Phase Diagrams

A solution of water is at 0.006atm and 0.01 degrees Celsius. What phase(s) are present in the sample?



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Possible Answers:

Solid and gas

Liquid and gas

Solid and liquid

Solid, liquid, and gas

Liquid only

Correct answer:

Solid, liquid, and gas

Explanation:

The point detailed in the question is the triple point of water on the phase diagram. At the triple point all three phases of a chemical coexist; as such the correct answer is solid, liquid, and gas. 

Example Question #11 : Phase Changes

Liquid water at room temperature is cooled to -75

Which of the following descriptions applies to the process outlined above?

I: A physical change occurred

II: A chemical change occurred

III: There was a change in entropy

Possible Answers:

I only

I,II, and III

II and III

I and III

II only

Correct answer:

I and III

Explanation:

A physical change is a process where the physical properties of a substance are changed.  Here water undergoes a phase change from the more disordered liquid state to the more ordered solid state, which is indeed a physical change.  A chemical change describes when a substance undergoes a change in the identity of its constituent molecules.  Here although the water has gone from the liquid phase to the solid phase it is still composed only of water molecules so a chemical change has not occured.  Entropy describes the degree to which a system is ordered.  Here we do have a change in entropy becasue the liquid water was more disordered than the solid water. 

Example Question #1 : Types Of Phase Changes

A large number of molecules begin moving very fast, rarely bumping into one another, and taking up the entire space available to them. As the temperature drops and the kinetic energy of the particles decreases, the particles move more slowly and run into each other more often. They eventually form a lattice structure, only slightly moving. What is this process called?

Possible Answers:

Freezing

Decrease in temperature

Condensation, then freezing

Sublimination, then freezing

Vaporization, then condensation

Correct answer:

Condensation, then freezing

Explanation:

This is a description of condensation from the gas phase to the liquid phase, then freezing from the liquid phase to the solid phase.

Example Question #2 : Types Of Phase Changes

A phase diagram is used to show the phase that a compound will be in depending upon the environmental temperature and pressure.

Carbon dioxide will sublimate from a solid to a gas at room temperature. What would be necessary in order to cause solid carbon dioxide to melt?

Possible Answers:

Decrease the temperature

Carbon dioxide cannot be melted

Increase the temperature

Decrease the pressure

Increase the pressure

Correct answer:

Increase the pressure

Explanation:

At a pressure of one atmosphere, carbon dioxide can only exist in the solid phase or the gaseous phase. Solid carbon dioxide will sublimate at standard conditions.

Raising the temperature will simply make the carbon dioxide sublimate at a faster rate. In order to allow the solid carbon dioxide to melt into the liquid phase, the carbon dioxide must be subjected to a greater amount of pressure. This will shift equilibrium away from the gaseous state and toward the liquid state.

Example Question #12 : Phase Changes

A solution of water is at 0 degrees Celcius and 3atm. The pressure is constantly decreased until it was well below 0.000001atm. What will happen to the solution? 



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Possible Answers:

The liquid water will turn into water vapor

The liquid water will turn into ice, then into water vapor

The ice will turn straight into water vapor

The water starts off as a vapor, and will remain as a vapor

The ice will turn into liquid, then into water vapor

Correct answer:

The liquid water will turn into ice, then into water vapor

Explanation:

Whenever you see a problem like this, immediately draw a mental point on the phase diagram to establish your starting conditions. In our case, the conditions fall in the range of the liquid phase of the water. This allows us to eliminate some of our answer options.

Next, determine what change is occuring and on which axis the change is occuring. We are decreasing pressure, so you are going to need to move down on the y-axis towards 0. Draw an imaginary line from the initial point to where the final point should be. In our case, the final pressure is extremely small. This point is not on the y-axis, but we can use our inference/inductive skills to determine that we will pass through the solid phase (ice) as we approach the gas phase (water vapor). Even if you didn't know the water would become vaporized, based on the graph you knew that the liquid phase had to be followed by the solid phase, and only one answer choice has that option. 

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