Photoelectric Effect and Line Spectra (4E)

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MCAT Chemical and Physical Foundations of Biological Systems › Photoelectric Effect and Line Spectra (4E)

Questions 1 - 10
1

A researcher studies a one-electron atom that emits a line spectrum similar to hydrogen. When the nucleus is replaced with a different isotope (same atomic number, different mass), the bright emission lines are observed at essentially the same wavelengths within the instrument’s resolution. Which statement best accounts for this result using the principle of quantized energy levels?

Isotope substitution changes the work function, so emission lines should shift substantially but were missed due to low intensity

The unchanged wavelengths show that atomic emission is purely classical radiation from accelerating charges

Emission wavelengths depend on how many photons are emitted per second, which is unchanged by isotope substitution

Emission wavelengths are set primarily by electronic energy level differences, which depend on nuclear charge more than nuclear mass

Explanation

This question tests understanding of how atomic structure determines emission spectra. Emission line wavelengths are determined by the energy differences between electronic levels, which depend primarily on the nuclear charge (atomic number) that governs electron-nucleus attraction. When replacing the nucleus with a different isotope (same atomic number but different mass), the nuclear charge remains unchanged, so the electronic energy levels and their differences remain essentially the same. The correct answer A recognizes that electronic transitions depend on nuclear charge rather than nuclear mass. Option B incorrectly relates wavelength to photon emission rate rather than energy level differences. Option C wrongly suggests isotopes affect the work function, which is irrelevant to emission spectra. Option D incorrectly denies the quantum nature of atomic emission. The slight isotope shift that does exist is typically too small to detect with standard spectrometers.

2

A researcher observes that a hydrogen discharge tube emits a line at 656 nm. When the tube is cooled, the line remains at 656 nm but becomes dimmer. Which explanation is most consistent with the core principle of line spectra?

Cooling reduces the photon frequency, but wavelength stays constant because Planck’s constant decreases

Cooling changes the quantized energy levels, but the observed wavelength remains due to detector calibration

Cooling reduces the number of atoms reaching excited states, but the energy gaps (and thus wavelengths) remain fixed

Cooling makes emission more wave-like, so discrete lines should merge into a continuous spectrum

Explanation

This question tests understanding of atomic line spectra and how temperature affects emission intensity versus wavelength. Line spectra arise from electrons transitioning between discrete energy levels in atoms, with each transition producing a photon of specific wavelength determined by the energy difference between levels. When the hydrogen tube is cooled, fewer atoms have sufficient thermal energy to reach excited states through collisions, reducing the number of electrons available to make downward transitions that produce the 656 nm line. However, the energy levels themselves are intrinsic properties of hydrogen atoms and remain unchanged by temperature, so the wavelength of emitted photons stays constant at 656 nm. The correct answer recognizes that cooling affects the population of excited atoms (intensity) but not the quantized energy gaps (wavelength). Common distractors incorrectly suggest that temperature changes fundamental atomic properties or invoke incorrect physics like variable Planck's constant or wave-particle duality effects on spectral lines.

3

A hydrogen discharge tube is analyzed with a spectrometer. Three visible emission lines are recorded at approximately 656 nm, 486 nm, and 434 nm. (Constants: $c=3.00\times 10^8,\text{m/s}$, $h=6.63\times 10^{-34},\text{J·s}$.) Based on quantized electronic energy levels, which conclusion is most consistent with observing discrete wavelengths rather than a continuous spectrum?

Electrons in hydrogen can occupy only specific energy levels, so emitted photons have specific energies

Hydrogen atoms emit a continuous range of photon energies, but only three are detected in the visible

Hydrogen emits only at wavelengths where the spectrometer has maximum sensitivity

The emission wavelengths are determined by the tube’s temperature through blackbody radiation alone

Explanation

This question tests understanding of atomic line spectra and quantized energy levels. Line spectra demonstrate that electrons in atoms can only occupy specific, discrete energy levels, a fundamental principle of quantum mechanics. When electrons transition between these quantized levels, they emit photons with energies exactly equal to the energy difference between levels. Since energy levels are fixed for a given element, the emitted photon energies (and thus wavelengths via E = hc/λ) are also discrete and characteristic. The three observed wavelengths correspond to specific electronic transitions in hydrogen atoms. This contrasts with continuous spectra from hot solids, where thermal motion produces a broad range of energies. The discrete nature of the spectrum provides direct evidence for quantization in atomic systems, distinguishing it from classical predictions of continuous emission.

4

In a photoelectric experiment, a clean sodium surface is illuminated with monochromatic light. The frequency is varied while intensity is held constant. Electrons are detected only when $f \ge 5.5\times 10^{14},\text{Hz}$. For $f=7.0\times 10^{14},\text{Hz}$, the stopping potential is $V_s=0.62,\text{V}$. (Constants: $h=6.63\times 10^{-34},\text{J·s}$, $e=1.60\times 10^{-19},\text{C}$.) Which outcome would be expected if the light intensity is increased (same $f=7.0\times 10^{14},\text{Hz}$)?

The stopping potential stays the same, but the emitted electron current increases

The stopping potential increases because each electron absorbs more energy per photon at higher intensity

The threshold frequency decreases because a brighter beam lowers the work function

Electron emission stops unless the frequency is increased further above threshold

Explanation

This question tests understanding of how light intensity affects the photoelectric effect when frequency is held constant. The photoelectric effect demonstrates that electron emission depends on individual photon energy (determined by frequency), not the total light intensity. When intensity increases at constant frequency, more photons strike the surface per unit time, but each photon still has the same energy. Since the stopping potential depends only on the maximum kinetic energy of emitted electrons (which equals photon energy minus work function), it remains unchanged. However, more photons mean more electrons are emitted, increasing the photocurrent. The common misconception is that higher intensity means more energy per electron, but in the quantum model, each electron absorbs exactly one photon regardless of intensity.

5

Monochromatic light of wavelength $\lambda$ illuminates a metal surface in a photoelectric cell. The wavelength is decreased (toward the ultraviolet) while intensity is held constant. (Constants: $c=3.00\times 10^8,\text{m/s}$, $h=6.63\times 10^{-34},\text{J·s}$.) Assuming the original light already caused emission, which change is expected?

The maximum kinetic energy of emitted electrons increases because photon energy increases as $\lambda$ decreases

The emitted electron current must decrease to zero because ultraviolet light cannot eject electrons

The maximum kinetic energy decreases because shorter wavelength means fewer photons hit the surface

The work function increases because wavelength determines a metal’s intrinsic binding energy

Explanation

This question tests understanding of how wavelength relates to photon energy in the photoelectric effect. The relationship E = hc/λ shows that photon energy is inversely proportional to wavelength - as wavelength decreases, photon energy increases. When wavelength shifts toward ultraviolet (shorter λ), frequency increases and photon energy rises. In the photoelectric effect, this increased photon energy translates directly to increased maximum kinetic energy of emitted electrons, following KEmax = hf - φ. Since the work function φ remains constant for the same metal, any increase in photon energy appears as increased electron kinetic energy. The stopping potential, which measures this maximum kinetic energy, therefore increases. Common misconceptions include thinking that wavelength affects the number of electrons or that ultraviolet light cannot cause emission.

6

In a photoelectric experiment, a student plots stopping potential $V_s$ versus light frequency $f$ for a given metal and obtains a straight line with positive slope. (Constants: $h=6.63\times 10^{-34},\text{J·s}$, $e=1.60\times 10^{-19},\text{C}$.) Which interpretation is most consistent with this linear relationship?

The slope corresponds to the work function $\phi$, which increases with frequency

The slope is caused by intensity variations, since frequency does not affect electron energy

The slope indicates photon momentum is quantized, so $V_s$ is independent of $f$

The slope corresponds to $h/e$, consistent with $eV_s = hf - \phi$

Explanation

This question tests understanding of the linear relationship between stopping potential and frequency in the photoelectric effect. The photoelectric equation eVs = hf - φ predicts that stopping potential varies linearly with frequency, with slope h/e. This relationship arises because each photon's energy (hf) is divided between overcoming the work function (φ) and providing kinetic energy to the electron (eVs). The positive slope indicates that higher frequency photons impart more kinetic energy to electrons after overcoming the constant work function. This linear relationship was crucial historical evidence for the photon model of light, as it directly contradicts classical wave predictions. The slope's value provides a method to measure Planck's constant, while the x-intercept gives the threshold frequency. Common misconceptions involve confusing the roles of frequency and intensity in determining electron energy.

7

A photoelectric cell shows a stopping potential of 0.30 V when illuminated with light of frequency $f$. When illuminated with light of frequency $f+\Delta f$, the stopping potential increases by 0.20 V. (Constants: $h=6.63\times 10^{-34},\text{J·s}$, $e=1.60\times 10^{-19},\text{C}$.) Which statement is most consistent with the underlying relationship between $V_s$ and $f$?

$V_s$ increases linearly with $f$ because $eV_s$ tracks the maximum kinetic energy $K_{\max}=hf-\phi$

$V_s$ increases quadratically with $f$ because photon energy scales as $f^2$

$V_s$ is independent of $f$ because work function is fixed for a given metal

$V_s$ depends only on intensity, so changing frequency cannot change $V_s$

Explanation

This question tests understanding of the linear relationship between stopping potential and frequency. The photoelectric equation eVs = hf - φ can be rearranged to show Vs = (h/e)f - φ/e, revealing a linear relationship with slope h/e. When frequency increases by Δf, the stopping potential increases by ΔVs = (h/e)Δf. The 0.20 V increase for a frequency increase of Δf confirms this linear relationship. This linearity is a fundamental prediction of the photon model and was historically important in validating quantum theory. The relationship shows that each unit increase in frequency produces the same increase in stopping potential, regardless of the starting frequency. This constant slope h/e provides a method to measure Planck's constant and demonstrates that photon energy depends linearly on frequency.

8

A spectrometer measures emission from a hydrogen discharge tube and detects sharp lines. The same instrument measures emission from a heated tungsten filament and detects a broad continuous spectrum. Which statement best explains the difference in spectra?

Both should be continuous, but the spectrometer resolves only a few wavelengths for hydrogen

A discharge tube primarily produces photons from discrete electronic transitions; a hot filament approximates blackbody radiation

Both should be line spectra, but tungsten lines overlap to appear continuous due to photon wave interference

A discharge tube produces continuous radiation because electrons accelerate; a filament produces lines because atoms are quantized

Explanation

This question tests understanding of the difference between line spectra and continuous spectra. A hydrogen discharge tube contains isolated atoms that undergo specific electronic transitions between quantized energy levels, producing photons at discrete wavelengths - hence sharp emission lines. In contrast, a heated tungsten filament acts as a dense solid where atoms are closely packed and strongly interact. This creates a near-continuum of available energy states, and thermal vibrations produce a broad range of photon energies approximating blackbody radiation. The fundamental difference is between isolated atoms with well-defined quantum states (line spectra) and condensed matter with overlapping energy bands (continuous spectra). This distinction is crucial for understanding different light sources and their applications in spectroscopy.

9

A metal is illuminated with two different monochromatic light sources. Source 1 has frequency $f_1$ and produces photoelectrons with stopping potential $V_{s1}$. Source 2 has frequency $f_2>f_1$ and produces stopping potential $V_{s2}$. Intensities are adjusted so that both sources produce the same photocurrent. Which relationship is expected if both frequencies exceed threshold? (Constants: $h$, $e$.)

$V_{s2}=V_{s1}$ because equal photocurrent implies equal electron kinetic energy

No stopping potential can be defined when photocurrents are equal

$V_{s2}>V_{s1}$ because maximum electron kinetic energy increases with photon frequency

$V_{s2}<V_{s1}$ because higher frequency implies fewer photons and thus lower electron energy

Explanation

This question tests understanding of how frequency affects stopping potential independent of photocurrent. The photoelectric effect establishes that stopping potential depends only on the maximum kinetic energy of emitted electrons, which is determined by photon frequency through Vs = (hf - φ)/e. Since f₂ > f₁, photons from source 2 have higher energy, resulting in electrons with greater maximum kinetic energy and thus requiring a larger stopping potential to stop them. The photocurrent (number of electrons per second) depends on the number of incident photons, which can be adjusted through intensity. Equal photocurrents simply mean equal numbers of electrons are emitted per second, but this doesn't affect the energy per electron. This demonstrates the independence of photon number (intensity) and photon energy (frequency) in the quantum model.

10

In a photoelectric experiment, the stopping potential is measured for several frequencies above threshold. The student mistakenly concludes that because light is a wave, increasing frequency should increase the number of emitted electrons per second at fixed intensity. Which statement best corrects this conclusion using the photoelectric model?

At fixed intensity, increasing frequency increases photon energy, so fewer photons per second may strike the surface

At fixed intensity, increasing frequency increases wave amplitude, so more electrons are emitted per photon

Frequency affects only the work function, so emission rate must remain constant

Electron emission rate depends only on stopping potential, which is unrelated to intensity

Explanation

This question tests understanding of the relationship between photon flux and frequency at constant intensity. In the photoelectric effect, light intensity equals the number of photons per second times the energy per photon (I = nE = nhf). At fixed intensity, increasing frequency means each photon carries more energy, so fewer photons per second must arrive to maintain the same total power. This results in fewer electron emissions per second (lower photocurrent) even though each emitted electron has higher kinetic energy. This counterintuitive result highlights the particle nature of light - we're dealing with discrete photons, not continuous waves. The student's error stems from classical wave thinking where frequency and amplitude are independent, but in the photon model, higher frequency at fixed intensity necessarily means fewer photons.

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